Polymer-modified halloysite composite nanotubes
A natural clay halloysite, which is a kind of aluminosilicate with a predominantly nanosized hollow tubular structure, was modified by polymers achieving polymer‐halloysite composite nanotubes. Polymer chains can grow from both interior and exterior surfaces of the halloysite nanotubes by atom trans...
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Veröffentlicht in: | Journal of applied polymer science 2008-12, Vol.110 (6), p.3638-3646 |
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creator | Li, Cuiping Liu, Jiguang Qu, Xiaozhong Guo, Baochun Yang, Zhenzhong |
description | A natural clay halloysite, which is a kind of aluminosilicate with a predominantly nanosized hollow tubular structure, was modified by polymers achieving polymer‐halloysite composite nanotubes. Polymer chains can grow from both interior and exterior surfaces of the halloysite nanotubes by atom transfer radial polymerization (ATRP). Eventually, the composite nanotubes were evolved to a core‐shell coaxial structure after the interior cavity was fully covered by the polymer. After dissolution of the halloysite template, polymeric nanotubes and nanowires were derived. The composition could be controlled from polymer to carbon after being treated at high temperature. The idea can be extended to a cast halloysite fabric resulting nonwoven composites, which had some interesting wettability. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008 |
doi_str_mv | 10.1002/app.28879 |
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Polymer chains can grow from both interior and exterior surfaces of the halloysite nanotubes by atom transfer radial polymerization (ATRP). Eventually, the composite nanotubes were evolved to a core‐shell coaxial structure after the interior cavity was fully covered by the polymer. After dissolution of the halloysite template, polymeric nanotubes and nanowires were derived. The composition could be controlled from polymer to carbon after being treated at high temperature. The idea can be extended to a cast halloysite fabric resulting nonwoven composites, which had some interesting wettability. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008</description><identifier>ISSN: 0021-8995</identifier><identifier>EISSN: 1097-4628</identifier><identifier>DOI: 10.1002/app.28879</identifier><identifier>CODEN: JAPNAB</identifier><language>eng</language><publisher>Hoboken: Wiley Subscription Services, Inc., A Wiley Company</publisher><subject>Applied sciences ; ATRP ; composite nanotube ; Exact sciences and technology ; Fibers and threads ; Forms of application and semi-finished materials ; halloysite ; nonwoven fabric ; Organic polymers ; Physicochemistry of polymers ; Polymer industry, paints, wood ; Polymerization ; Preparation, kinetics, thermodynamics, mechanism and catalysts ; Technology of polymers</subject><ispartof>Journal of applied polymer science, 2008-12, Vol.110 (6), p.3638-3646</ispartof><rights>Copyright © 2008 Wiley Periodicals, Inc.</rights><rights>2015 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c4349-357dbcf381b9f95c7168e9b97a9a435cdfb7b79ff07a9095f51c8b62697f38c53</citedby><cites>FETCH-LOGICAL-c4349-357dbcf381b9f95c7168e9b97a9a435cdfb7b79ff07a9095f51c8b62697f38c53</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fapp.28879$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fapp.28879$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,776,780,1411,27903,27904,45553,45554</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=20869491$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Li, Cuiping</creatorcontrib><creatorcontrib>Liu, Jiguang</creatorcontrib><creatorcontrib>Qu, Xiaozhong</creatorcontrib><creatorcontrib>Guo, Baochun</creatorcontrib><creatorcontrib>Yang, Zhenzhong</creatorcontrib><title>Polymer-modified halloysite composite nanotubes</title><title>Journal of applied polymer science</title><addtitle>J. Appl. Polym. Sci</addtitle><description>A natural clay halloysite, which is a kind of aluminosilicate with a predominantly nanosized hollow tubular structure, was modified by polymers achieving polymer‐halloysite composite nanotubes. Polymer chains can grow from both interior and exterior surfaces of the halloysite nanotubes by atom transfer radial polymerization (ATRP). Eventually, the composite nanotubes were evolved to a core‐shell coaxial structure after the interior cavity was fully covered by the polymer. After dissolution of the halloysite template, polymeric nanotubes and nanowires were derived. The composition could be controlled from polymer to carbon after being treated at high temperature. The idea can be extended to a cast halloysite fabric resulting nonwoven composites, which had some interesting wettability. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008</description><subject>Applied sciences</subject><subject>ATRP</subject><subject>composite nanotube</subject><subject>Exact sciences and technology</subject><subject>Fibers and threads</subject><subject>Forms of application and semi-finished materials</subject><subject>halloysite</subject><subject>nonwoven fabric</subject><subject>Organic polymers</subject><subject>Physicochemistry of polymers</subject><subject>Polymer industry, paints, wood</subject><subject>Polymerization</subject><subject>Preparation, kinetics, thermodynamics, mechanism and catalysts</subject><subject>Technology of polymers</subject><issn>0021-8995</issn><issn>1097-4628</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2008</creationdate><recordtype>article</recordtype><recordid>eNp1kLFOwzAURS0EEqUw8AddQGJIa8dxbI9VoQVUQUBFjJbj2CKQ1MFOBfl7TFO6Mb2n9849wwXgHMExgjCeyKYZx4xRfgAGCHIaJWnMDsEg_FDEOCfH4MT7dwgRIjAdgElmq67WLqptUZpSF6M3WVW282WrR8rWjd1ua7m27SbX_hQcGVl5fbabQ_Ayv1nNbqPl4-JuNl1GKsEJjzChRa4MZijnhhNFUco0zzmVXCaYqMLkNKfcGBgukBNDkGJ5GqechpAieAgue2_j7OdG-1bUpVe6quRa240XmCSUJRgH8KoHlbPeO21E48pauk4gKH4rEaESsa0ksBc7qfRKVsbJtSr9PhBDlvKEo8BNeu6rrHT3v1BMs-zPHPWJ0rf6e5-Q7kOkFFMiXh8W4ilbXT_fz4MF_wD5i37H</recordid><startdate>20081215</startdate><enddate>20081215</enddate><creator>Li, Cuiping</creator><creator>Liu, Jiguang</creator><creator>Qu, Xiaozhong</creator><creator>Guo, Baochun</creator><creator>Yang, Zhenzhong</creator><general>Wiley Subscription Services, Inc., A Wiley Company</general><general>Wiley</general><scope>BSCLL</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7QF</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20081215</creationdate><title>Polymer-modified halloysite composite nanotubes</title><author>Li, Cuiping ; Liu, Jiguang ; Qu, Xiaozhong ; Guo, Baochun ; Yang, Zhenzhong</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c4349-357dbcf381b9f95c7168e9b97a9a435cdfb7b79ff07a9095f51c8b62697f38c53</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2008</creationdate><topic>Applied sciences</topic><topic>ATRP</topic><topic>composite nanotube</topic><topic>Exact sciences and technology</topic><topic>Fibers and threads</topic><topic>Forms of application and semi-finished materials</topic><topic>halloysite</topic><topic>nonwoven fabric</topic><topic>Organic polymers</topic><topic>Physicochemistry of polymers</topic><topic>Polymer industry, paints, wood</topic><topic>Polymerization</topic><topic>Preparation, kinetics, thermodynamics, mechanism and catalysts</topic><topic>Technology of polymers</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Li, Cuiping</creatorcontrib><creatorcontrib>Liu, Jiguang</creatorcontrib><creatorcontrib>Qu, Xiaozhong</creatorcontrib><creatorcontrib>Guo, Baochun</creatorcontrib><creatorcontrib>Yang, Zhenzhong</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Aluminium Industry Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Journal of applied polymer science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Li, Cuiping</au><au>Liu, Jiguang</au><au>Qu, Xiaozhong</au><au>Guo, Baochun</au><au>Yang, Zhenzhong</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Polymer-modified halloysite composite nanotubes</atitle><jtitle>Journal of applied polymer science</jtitle><addtitle>J. Appl. Polym. Sci</addtitle><date>2008-12-15</date><risdate>2008</risdate><volume>110</volume><issue>6</issue><spage>3638</spage><epage>3646</epage><pages>3638-3646</pages><issn>0021-8995</issn><eissn>1097-4628</eissn><coden>JAPNAB</coden><abstract>A natural clay halloysite, which is a kind of aluminosilicate with a predominantly nanosized hollow tubular structure, was modified by polymers achieving polymer‐halloysite composite nanotubes. Polymer chains can grow from both interior and exterior surfaces of the halloysite nanotubes by atom transfer radial polymerization (ATRP). Eventually, the composite nanotubes were evolved to a core‐shell coaxial structure after the interior cavity was fully covered by the polymer. After dissolution of the halloysite template, polymeric nanotubes and nanowires were derived. The composition could be controlled from polymer to carbon after being treated at high temperature. The idea can be extended to a cast halloysite fabric resulting nonwoven composites, which had some interesting wettability. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008</abstract><cop>Hoboken</cop><pub>Wiley Subscription Services, Inc., A Wiley Company</pub><doi>10.1002/app.28879</doi><tpages>9</tpages></addata></record> |
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subjects | Applied sciences ATRP composite nanotube Exact sciences and technology Fibers and threads Forms of application and semi-finished materials halloysite nonwoven fabric Organic polymers Physicochemistry of polymers Polymer industry, paints, wood Polymerization Preparation, kinetics, thermodynamics, mechanism and catalysts Technology of polymers |
title | Polymer-modified halloysite composite nanotubes |
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