Diazo Reagents in Copper(I)‐Catalyzed Olefination of Aldehydes

The olefination of aldehydes to synthesize unsaturated ketones, esters, amides and phosphonates using diazo reagents and triphenylphosphine in the presence of copper(I) iodide as catalyst, is described. Good to excellent E:Z selectivities as well as yields were obtained for a large variety of alipha...

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Veröffentlicht in:	Advanced synthesis & catalysis 2008-10, Vol.350 (14‐15), p.2352-2358
Hauptverfasser:	Lebel, Hélène, Davi, Michaël
Format:	Artikel
Sprache:	eng
Schlagworte:	alkenes conjugated esters CC bond formation phosphorus ylides Wittig reaction
Online-Zugang:	Volltext
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