Temperature effect on charge density of silicon nitride films deposited in SiH4–NH3–N2 plasma

Improved surface passivation of silicon nitride films requires a high positive charge density. A neural network model of SiN charge density was used to investigate temperature effects on charge density. For a systematic modeling, the deposition process was characterized by means of a face-centered B...

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Veröffentlicht in:Surface & coatings technology 2008-08, Vol.202 (22-23), p.5539-5542
Hauptverfasser: Kim, Byungwhan, Kwon, Sang Hee
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container_title Surface & coatings technology
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Kwon, Sang Hee
description Improved surface passivation of silicon nitride films requires a high positive charge density. A neural network model of SiN charge density was used to investigate temperature effects on charge density. For a systematic modeling, the deposition process was characterized by means of a face-centered Box Wilson experiment. Prediction performance of neural network model was optimized by using genetic algorithm. Interestingly, charge density was varied little with the substrate temperature regardless of SiH4 flow rates. Charge density variation was not sensitive to [Si–H] variation. A pronounced temperature effect at higher NH3 flow rate or lower radio frequency (rf) power was attributed to a relatively large [N–H]. For NH3 or rf power variation, charge density was strongly correlated to [N–H]/[Si–H].
doi_str_mv 10.1016/j.surfcoat.2008.06.030
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A neural network model of SiN charge density was used to investigate temperature effects on charge density. For a systematic modeling, the deposition process was characterized by means of a face-centered Box Wilson experiment. Prediction performance of neural network model was optimized by using genetic algorithm. Interestingly, charge density was varied little with the substrate temperature regardless of SiH4 flow rates. Charge density variation was not sensitive to [Si–H] variation. A pronounced temperature effect at higher NH3 flow rate or lower radio frequency (rf) power was attributed to a relatively large [N–H]. 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subjects Charge density
Cross-disciplinary physics: materials science
rheology
Exact sciences and technology
Generalized regression neural network
Materials science
Physics
Plasma enhanced chemical vapor deposition
SiH4
Silicon nitride film
Surface treatments
Temperature
title Temperature effect on charge density of silicon nitride films deposited in SiH4–NH3–N2 plasma
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