Highly efficient polymer blends from a polyfluorene derivative and PVK for LEDs

The photophysical and electroluminescent properties of blends of a polyfluorene derivative of the PPV type, poly[(9,9-dihexyl-9H-fluorene-2,7-diyl)-1,2-ethenediyl-1,4-phenylene-1,2-ethenediyl] (labeled as LaPPS16) and poly(vinylcarbazole) – PVK are presented and discussed in terms of the operating l...

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Veröffentlicht in:Polymer (Guilford) 2009-11, Vol.50 (25), p.6057-6064
Hauptverfasser: Nowacki, Bruno, Iamazaki, Eduardo, Cirpan, Ali, Karasz, Frank, Atvars, Teresa D.Z., Akcelrud, Leni
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container_end_page 6064
container_issue 25
container_start_page 6057
container_title Polymer (Guilford)
container_volume 50
creator Nowacki, Bruno
Iamazaki, Eduardo
Cirpan, Ali
Karasz, Frank
Atvars, Teresa D.Z.
Akcelrud, Leni
description The photophysical and electroluminescent properties of blends of a polyfluorene derivative of the PPV type, poly[(9,9-dihexyl-9H-fluorene-2,7-diyl)-1,2-ethenediyl-1,4-phenylene-1,2-ethenediyl] (labeled as LaPPS16) and poly(vinylcarbazole) – PVK are presented and discussed in terms of the operating light emission mechanisms. Static and dynamic fluorescence measurements and morphology data showed a powerful exciton migration from the host (PVK) to the guest (LaPPS16) resulting in emission coming from solely LaPPS16, even when in concentrations small as 1%. Electroluminescence was greatly enhanced with the blending; increases of 18 times in efficiency and 20 times in luminance were achieved in the blend containing 20% LaPPS16, with 3 V applied voltage. [Display omitted]
doi_str_mv 10.1016/j.polymer.2009.09.056
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subjects Applied sciences
Electrical, magnetic and optical properties
Electroluminescence
Electronics
Exact sciences and technology
Optoelectronic devices
Organic polymers
Photoluminescence
Physicochemistry of polymers
Polymer blends
Properties and characterization
Semiconductor electronics. Microelectronics. Optoelectronics. Solid state devices
title Highly efficient polymer blends from a polyfluorene derivative and PVK for LEDs
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