Effect of anhydrides on the mechanical, thermal and morphological properties of TPS/PE blends made by one-step extrusion
Thermoplastic starch/polyethylene blends containing maleic anhydride (MAH), succinic anhydride (SA) and phthalic anhydride (PA) were prepared by one-step extrusion, in a single-screw extruder, in the presence of dicumyl peroxide. The morphological, mechanical and thermal properties of the blends wer...
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Veröffentlicht in: | Polymers & polymer composites 2007-01, Vol.15 (3), p.249-253 |
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creator | YU, Jing-Lin PANG, Ji-Ping WANG, Shu-Jun YU, Jiu-Gao |
description | Thermoplastic starch/polyethylene blends containing maleic anhydride (MAH), succinic anhydride (SA) and phthalic anhydride (PA) were prepared by one-step extrusion, in a single-screw extruder, in the presence of dicumyl peroxide. The morphological, mechanical and thermal properties of the blends were characterized by scanning electron microscopy (SEM) and thermogravimetric analysis and also by measuring elongation at break (%) and tensile strength (MPa). Blends made with MAH had better properties than those with SA and PA. The SEM showed that they also had better interfacial adhesion. Because of the existence of carbon-carbon double bonds in MAH, it could graft to the polyethylene chains and act as a compatibilizer during the extrusion process. [PUBLICATION ABSTRACT] |
doi_str_mv | 10.1177/096739110701500309 |
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The morphological, mechanical and thermal properties of the blends were characterized by scanning electron microscopy (SEM) and thermogravimetric analysis and also by measuring elongation at break (%) and tensile strength (MPa). Blends made with MAH had better properties than those with SA and PA. The SEM showed that they also had better interfacial adhesion. Because of the existence of carbon-carbon double bonds in MAH, it could graft to the polyethylene chains and act as a compatibilizer during the extrusion process. 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[PUBLICATION ABSTRACT]</description><subject>Anhydrides</subject><subject>Applied sciences</subject><subject>Chemical modifications</subject><subject>Chemical reactions and properties</subject><subject>Exact sciences and technology</subject><subject>Extrusion</subject><subject>Extrusion process</subject><subject>Influence</subject><subject>Materials science</subject><subject>Mechanical properties</subject><subject>Organic polymers</subject><subject>Physicochemistry of polymers</subject><subject>Polymer blends</subject><subject>Thermal properties</subject><subject>Thermogravimetric analysis</subject><subject>Thermoplastic composites</subject><subject>Thermoplastics</subject><issn>0967-3911</issn><issn>1478-2391</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2007</creationdate><recordtype>article</recordtype><sourceid>8G5</sourceid><sourceid>BENPR</sourceid><sourceid>GUQSH</sourceid><sourceid>M2O</sourceid><recordid>eNqFkU9r3DAQxU1poNukX6AnUWhPdTL6Y8k6hrBpA4EGkpyNLI2yCrblSl7IfvvKbKDQHoIOQqPfG97Mq6rPFM4pVeoCtFRcUwoKaAPAQb-rNlSotmal_L7arEC9Eh-qjzk_AzAqZbOpXrbeo11I9MRMu4NLwWEmcSLLDsmIdmemYM3wfX2n0QyFcmSMad7FIT6tX2ROcca0hFXnycPd_cXdlvQDTi6T0Tgk_aE0xDovOBN8WdI-hzidVSfeDBk_vd6n1eP19uHqZ33768fN1eVtbQU0S825cKJ4dWCcRidbx6F3nHpJ-9YAK_NyK53TrEchQfcMmFOCCU9bCsLz0-rbsW-x-XuPeenGkC0Og5kw7nPHG6p0K9ibINNaMQor-OUf8Dnu01SG6KhWQrKGrdD5EXoyA3Zh8nFJxpbjcAy2rMOHUr-kLUgpeKOKgB0FNsWcE_puTmE06dBR6NaMu_8zLqKvr1ZMLlH4ZCYb8l9lq1rFW8H_AJY7pMc</recordid><startdate>20070101</startdate><enddate>20070101</enddate><creator>YU, Jing-Lin</creator><creator>PANG, Ji-Ping</creator><creator>WANG, Shu-Jun</creator><creator>YU, Jiu-Gao</creator><general>Rapra Technology</general><general>Sage Publications Ltd. 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The morphological, mechanical and thermal properties of the blends were characterized by scanning electron microscopy (SEM) and thermogravimetric analysis and also by measuring elongation at break (%) and tensile strength (MPa). Blends made with MAH had better properties than those with SA and PA. The SEM showed that they also had better interfacial adhesion. Because of the existence of carbon-carbon double bonds in MAH, it could graft to the polyethylene chains and act as a compatibilizer during the extrusion process. [PUBLICATION ABSTRACT]</abstract><cop>Shrewsbury</cop><pub>Rapra Technology</pub><doi>10.1177/096739110701500309</doi><tpages>5</tpages></addata></record> |
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source | Sage Journals GOLD Open Access 2024; Elektronische Zeitschriftenbibliothek - Frei zugängliche E-Journals |
subjects | Anhydrides Applied sciences Chemical modifications Chemical reactions and properties Exact sciences and technology Extrusion Extrusion process Influence Materials science Mechanical properties Organic polymers Physicochemistry of polymers Polymer blends Thermal properties Thermogravimetric analysis Thermoplastic composites Thermoplastics |
title | Effect of anhydrides on the mechanical, thermal and morphological properties of TPS/PE blends made by one-step extrusion |
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