Raman spectroscopic determination of boroxol and borate ring contents in lead borate glasses

Raman spectroscopic determination of boroxol and borate ring contents in lead borate glasses

Glasses in the system xPbO·(100 – x)B2O3 (0 ≤ x ≤ 30 mol.%) were studied by Raman spectroscopy. The conversion of boroxol rings into borate rings containing one or two BO4 groups due to the transformation of threefold to fourfold coordinated boron with increasing content of lead oxide was determined...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Journal of Raman spectroscopy 1993-07, Vol.24 (7), p.407-410
Hauptverfasser: Witke, K., Hübert, Th, Reich, P., Splett, Ch
Format: Artikel
Sprache:eng
Schlagworte:
Condensed matter: structure, mechanical and thermal properties
Disordered solids
Exact sciences and technology
Physics
Structure of solids and liquids
crystallography
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
container_end_page 410
container_issue 7
container_start_page 407
container_title Journal of Raman spectroscopy
container_volume 24
creator Witke, K.
Hübert, Th
Reich, P.
Splett, Ch
description Glasses in the system xPbO·(100 – x)B2O3 (0 ≤ x ≤ 30 mol.%) were studied by Raman spectroscopy. The conversion of boroxol rings into borate rings containing one or two BO4 groups due to the transformation of threefold to fourfold coordinated boron with increasing content of lead oxide was determined from the intensities of the Raman peaks at 805 and 770 cm−1. Quantitative measurements were carried out on highly finished spherical samples to allow different reflection losses of the samples to be taken into account.
doi_str_mv 10.1002/jrs.1250240704
format Article
fullrecord <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_35041369</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>35041369</sourcerecordid><originalsourceid>FETCH-LOGICAL-c3874-c555bc4c41d1d6d1a52e2cb4a59502a22827009481013f1783ded1321d986d083</originalsourceid><addsrcrecordid>eNqFUMtuFDEQtCKQsgSunH2IuM3Sfsx45hiFEEABpPCIhCJZvbYncjJrL-6JSP4eRxstyolTt9RV1VXF2GsBSwEg314XWgrZgtRgQO-xhYDBNLpt22dsAcqYBnTf7bMXRNcAMAydWLDLc1xj4rQJbi6ZXN5Ex32YQ1nHhHPMieeRr3LJd3nimPzDjnPgJaYr7nKaQ5qJx8SngLvj1YREgV6y5yNOFF49zgP24_3J9-MPzdnX04_HR2eNU73RjasWV047LbzwnRfYyiDdSmM71DQoZS9N9at7AUKNwvTKBy-UFH7oOw-9OmBvtrqbkn_fBprtOpIL04Qp5FuyqgUtVDdU4HILdDUrlTDaTYlrLPdWgH0o0dYS7b8SK-HwURnJ4TQWTC7SjqUHqO9lhQ1b2J84hfv_iNpP59-evGi23EhzuNtxsdzYzijT2osvp7bTv_TF5_6d_an-Arw0kaY</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>35041369</pqid></control><display><type>article</type><title>Raman spectroscopic determination of boroxol and borate ring contents in lead borate glasses</title><source>Wiley Online Library Journals Frontfile Complete</source><creator>Witke, K. ; Hübert, Th ; Reich, P. ; Splett, Ch</creator><creatorcontrib>Witke, K. ; Hübert, Th ; Reich, P. ; Splett, Ch</creatorcontrib><description>Glasses in the system xPbO·(100 – x)B2O3 (0 ≤ x ≤ 30 mol.%) were studied by Raman spectroscopy. The conversion of boroxol rings into borate rings containing one or two BO4 groups due to the transformation of threefold to fourfold coordinated boron with increasing content of lead oxide was determined from the intensities of the Raman peaks at 805 and 770 cm−1. Quantitative measurements were carried out on highly finished spherical samples to allow different reflection losses of the samples to be taken into account.</description><identifier>ISSN: 0377-0486</identifier><identifier>EISSN: 1097-4555</identifier><identifier>DOI: 10.1002/jrs.1250240704</identifier><identifier>CODEN: JRSPAF</identifier><language>eng</language><publisher>Chichester, UK: John Wiley &amp; Sons, Ltd</publisher><subject>Condensed matter: structure, mechanical and thermal properties ; Disordered solids ; Exact sciences and technology ; Physics ; Structure of solids and liquids; crystallography</subject><ispartof>Journal of Raman spectroscopy, 1993-07, Vol.24 (7), p.407-410</ispartof><rights>Copyright © 1993 John Wiley &amp; Sons, Ltd.</rights><rights>1993 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c3874-c555bc4c41d1d6d1a52e2cb4a59502a22827009481013f1783ded1321d986d083</citedby><cites>FETCH-LOGICAL-c3874-c555bc4c41d1d6d1a52e2cb4a59502a22827009481013f1783ded1321d986d083</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fjrs.1250240704$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fjrs.1250240704$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,777,781,1412,27905,27906,45555,45556</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&amp;idt=4900832$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Witke, K.</creatorcontrib><creatorcontrib>Hübert, Th</creatorcontrib><creatorcontrib>Reich, P.</creatorcontrib><creatorcontrib>Splett, Ch</creatorcontrib><title>Raman spectroscopic determination of boroxol and borate ring contents in lead borate glasses</title><title>Journal of Raman spectroscopy</title><addtitle>J. Raman Spectrosc</addtitle><description>Glasses in the system xPbO·(100 – x)B2O3 (0 ≤ x ≤ 30 mol.%) were studied by Raman spectroscopy. The conversion of boroxol rings into borate rings containing one or two BO4 groups due to the transformation of threefold to fourfold coordinated boron with increasing content of lead oxide was determined from the intensities of the Raman peaks at 805 and 770 cm−1. Quantitative measurements were carried out on highly finished spherical samples to allow different reflection losses of the samples to be taken into account.</description><subject>Condensed matter: structure, mechanical and thermal properties</subject><subject>Disordered solids</subject><subject>Exact sciences and technology</subject><subject>Physics</subject><subject>Structure of solids and liquids; crystallography</subject><issn>0377-0486</issn><issn>1097-4555</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1993</creationdate><recordtype>article</recordtype><recordid>eNqFUMtuFDEQtCKQsgSunH2IuM3Sfsx45hiFEEABpPCIhCJZvbYncjJrL-6JSP4eRxstyolTt9RV1VXF2GsBSwEg314XWgrZgtRgQO-xhYDBNLpt22dsAcqYBnTf7bMXRNcAMAydWLDLc1xj4rQJbi6ZXN5Ex32YQ1nHhHPMieeRr3LJd3nimPzDjnPgJaYr7nKaQ5qJx8SngLvj1YREgV6y5yNOFF49zgP24_3J9-MPzdnX04_HR2eNU73RjasWV047LbzwnRfYyiDdSmM71DQoZS9N9at7AUKNwvTKBy-UFH7oOw-9OmBvtrqbkn_fBprtOpIL04Qp5FuyqgUtVDdU4HILdDUrlTDaTYlrLPdWgH0o0dYS7b8SK-HwURnJ4TQWTC7SjqUHqO9lhQ1b2J84hfv_iNpP59-evGi23EhzuNtxsdzYzijT2osvp7bTv_TF5_6d_an-Arw0kaY</recordid><startdate>199307</startdate><enddate>199307</enddate><creator>Witke, K.</creator><creator>Hübert, Th</creator><creator>Reich, P.</creator><creator>Splett, Ch</creator><general>John Wiley &amp; Sons, Ltd</general><general>Wiley</general><scope>BSCLL</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope></search><sort><creationdate>199307</creationdate><title>Raman spectroscopic determination of boroxol and borate ring contents in lead borate glasses</title><author>Witke, K. ; Hübert, Th ; Reich, P. ; Splett, Ch</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3874-c555bc4c41d1d6d1a52e2cb4a59502a22827009481013f1783ded1321d986d083</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1993</creationdate><topic>Condensed matter: structure, mechanical and thermal properties</topic><topic>Disordered solids</topic><topic>Exact sciences and technology</topic><topic>Physics</topic><topic>Structure of solids and liquids; crystallography</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Witke, K.</creatorcontrib><creatorcontrib>Hübert, Th</creatorcontrib><creatorcontrib>Reich, P.</creatorcontrib><creatorcontrib>Splett, Ch</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Journal of Raman spectroscopy</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Witke, K.</au><au>Hübert, Th</au><au>Reich, P.</au><au>Splett, Ch</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Raman spectroscopic determination of boroxol and borate ring contents in lead borate glasses</atitle><jtitle>Journal of Raman spectroscopy</jtitle><addtitle>J. Raman Spectrosc</addtitle><date>1993-07</date><risdate>1993</risdate><volume>24</volume><issue>7</issue><spage>407</spage><epage>410</epage><pages>407-410</pages><issn>0377-0486</issn><eissn>1097-4555</eissn><coden>JRSPAF</coden><abstract>Glasses in the system xPbO·(100 – x)B2O3 (0 ≤ x ≤ 30 mol.%) were studied by Raman spectroscopy. The conversion of boroxol rings into borate rings containing one or two BO4 groups due to the transformation of threefold to fourfold coordinated boron with increasing content of lead oxide was determined from the intensities of the Raman peaks at 805 and 770 cm−1. Quantitative measurements were carried out on highly finished spherical samples to allow different reflection losses of the samples to be taken into account.</abstract><cop>Chichester, UK</cop><pub>John Wiley &amp; Sons, Ltd</pub><doi>10.1002/jrs.1250240704</doi><tpages>4</tpages></addata></record>
fulltext fulltext
identifier ISSN: 0377-0486
ispartof Journal of Raman spectroscopy, 1993-07, Vol.24 (7), p.407-410
issn 0377-0486
1097-4555
language eng
recordid cdi_proquest_miscellaneous_35041369
source Wiley Online Library Journals Frontfile Complete
subjects Condensed matter: structure, mechanical and thermal properties
Disordered solids
Exact sciences and technology
Physics
Structure of solids and liquids
crystallography
title Raman spectroscopic determination of boroxol and borate ring contents in lead borate glasses
url https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-19T13%3A32%3A55IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Raman%20spectroscopic%20determination%20of%20boroxol%20and%20borate%20ring%20contents%20in%20lead%20borate%20glasses&rft.jtitle=Journal%20of%20Raman%20spectroscopy&rft.au=Witke,%20K.&rft.date=1993-07&rft.volume=24&rft.issue=7&rft.spage=407&rft.epage=410&rft.pages=407-410&rft.issn=0377-0486&rft.eissn=1097-4555&rft.coden=JRSPAF&rft_id=info:doi/10.1002/jrs.1250240704&rft_dat=%3Cproquest_cross%3E35041369%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=35041369&rft_id=info:pmid/&rfr_iscdi=true