Removal of Cd(II), Pb(II), Cu(II) and Ni(II) from water using modified pine bark

This paper describes the removal of Cd(II), Pb(II), Cu(II), and Ni(II) ions from aqueous solutions using chemically modified pine barks ( Pinus nigra). In this article, effects of chemical modification methods on the adsorption capacity have been investigated. Changes of the surface properties were...

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Veröffentlicht in:Desalination 2009-12, Vol.249 (2), p.519-527
Hauptverfasser: Argun, Mehmet Emin, Dursun, Sukru, Karatas, Mustafa
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Karatas, Mustafa
description This paper describes the removal of Cd(II), Pb(II), Cu(II), and Ni(II) ions from aqueous solutions using chemically modified pine barks ( Pinus nigra). In this article, effects of chemical modification methods on the adsorption capacity have been investigated. Changes of the surface properties were examined by the FTIR, SEM and zeta potential analyses. HCl, NaOH, Fenton reactive, polymerization, acetone, ethanol, chloroform, tetra ethylene glycol, diethyl ether and glycol were used for modification processes. Maximum adsorption capacities were obtained by modification with NaOH (13–20 mg/g), Fenton (12–17 mg/g) and polymerization (12–16.5 mg/g). These modification processes also decreased Chemical Oxygen Demand of water from 1820 mg/L for raw pine barks to 35 mg/L for NaOH modified barks. Adsorption capacities of adsorbents increased from 2 mg/g to 20 mg/g as a result of modification that accordingly increase adsorbent surface activity.
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subjects Adsorbents
Adsorption
Applied sciences
Bark
Chemical engineering
Ethyl alcohol
Exact sciences and technology
Modification
Oxygen demand
Pine
Pollution
Polymerization
Surface chemistry
Toxic metal
Toxicity
title Removal of Cd(II), Pb(II), Cu(II) and Ni(II) from water using modified pine bark
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