Phase behavior of blends containing amorphous poly(resorcinol phthalate-block-carbonate) and semicrystalline polyesters

Phase behavior of blends containing amorphous poly(resorcinol phthalate-block-carbonate) and semicrystalline polyesters

The phase behavior of poly(resorcinol phthalate-block-carbonate) (RPC) with engineering polyesters was investigated by using differential scanning calorimeter (DSC) and dynamic mechanical analysis. RPC was found to form miscible blends with poly(ethylene terephthalate) (PET), poly(butylene terephtha...

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Veröffentlicht in:Journal of applied polymer science 2008-12, Vol.110 (5), p.2623-2633
Hauptverfasser: Kim, Sung Dug, Chakravarti, Shreyas, Tian, Jun
Format: Artikel
Sprache:eng
Schlagworte:
Applied sciences
copolymer of resorcinol and carbonate
Exact sciences and technology
melting-point depression
Organic polymers
Physicochemistry of polymers
polyesters
Properties and characterization
Thermal and thermodynamic properties
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container_title Journal of applied polymer science
container_volume 110
creator Kim, Sung Dug
Chakravarti, Shreyas
Tian, Jun
description The phase behavior of poly(resorcinol phthalate-block-carbonate) (RPC) with engineering polyesters was investigated by using differential scanning calorimeter (DSC) and dynamic mechanical analysis. RPC was found to form miscible blends with poly(ethylene terephthalate) (PET), poly(butylene terephthalate) (PBT), and poly(cyclohexylmethylene terephthalate) (PCT), but was partially miscible with poly(1,4-cyclohexanedimethylene-1,4-cyclohexanedicarboxylate) (PCCD) in the melt state and below the melting temperature (Tm). The degree of melting-point depression indicates that the RPC is most miscible with PCT followed by PET and then PBT. Furthermore, with the help of empirical DSC data and the Nishi-Wang equation, the interaction parameters between RPC and PET, PBT, and PCT were quantified to be -0.36, -0.33, and -0.54, respectively.
doi_str_mv 10.1002/app.28473
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RPC was found to form miscible blends with poly(ethylene terephthalate) (PET), poly(butylene terephthalate) (PBT), and poly(cyclohexylmethylene terephthalate) (PCT), but was partially miscible with poly(1,4-cyclohexanedimethylene-1,4-cyclohexanedicarboxylate) (PCCD) in the melt state and below the melting temperature (Tm). The degree of melting-point depression indicates that the RPC is most miscible with PCT followed by PET and then PBT. 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Appl. Polym. Sci</addtitle><description>The phase behavior of poly(resorcinol phthalate-block-carbonate) (RPC) with engineering polyesters was investigated by using differential scanning calorimeter (DSC) and dynamic mechanical analysis. RPC was found to form miscible blends with poly(ethylene terephthalate) (PET), poly(butylene terephthalate) (PBT), and poly(cyclohexylmethylene terephthalate) (PCT), but was partially miscible with poly(1,4-cyclohexanedimethylene-1,4-cyclohexanedicarboxylate) (PCCD) in the melt state and below the melting temperature (Tm). The degree of melting-point depression indicates that the RPC is most miscible with PCT followed by PET and then PBT. 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Appl. Polym. Sci</addtitle><date>2008-12-05</date><risdate>2008</risdate><volume>110</volume><issue>5</issue><spage>2623</spage><epage>2633</epage><pages>2623-2633</pages><issn>0021-8995</issn><eissn>1097-4628</eissn><coden>JAPNAB</coden><abstract>The phase behavior of poly(resorcinol phthalate-block-carbonate) (RPC) with engineering polyesters was investigated by using differential scanning calorimeter (DSC) and dynamic mechanical analysis. RPC was found to form miscible blends with poly(ethylene terephthalate) (PET), poly(butylene terephthalate) (PBT), and poly(cyclohexylmethylene terephthalate) (PCT), but was partially miscible with poly(1,4-cyclohexanedimethylene-1,4-cyclohexanedicarboxylate) (PCCD) in the melt state and below the melting temperature (Tm). The degree of melting-point depression indicates that the RPC is most miscible with PCT followed by PET and then PBT. Furthermore, with the help of empirical DSC data and the Nishi-Wang equation, the interaction parameters between RPC and PET, PBT, and PCT were quantified to be -0.36, -0.33, and -0.54, respectively.</abstract><cop>Hoboken</cop><pub>Wiley Subscription Services, Inc., A Wiley Company</pub><doi>10.1002/app.28473</doi><tpages>11</tpages></addata></record>
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subjects Applied sciences
copolymer of resorcinol and carbonate
Exact sciences and technology
melting-point depression
Organic polymers
Physicochemistry of polymers
polyesters
Properties and characterization
Thermal and thermodynamic properties
title Phase behavior of blends containing amorphous poly(resorcinol phthalate-block-carbonate) and semicrystalline polyesters
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