Composition of the base glass used to realize the stained glass windows by Duccio di Buoninsegna (Siena Cathedral, 1288–1289 AD): A geochemical approach

A set of 35 samples from the rose window of the Siena Cathedral (Tuscany, Italy) has been studied using EMPA to define the chemical composition (17 major and minor elements) of the base glass. This paper focuses on colourless and natural-coloured glasses, i.e. glass produced without the intentional...

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Veröffentlicht in:Materials characterization 2009-12, Vol.60 (12), p.1545-1554
Hauptverfasser: Basso, E., Riccardi, M.P., Messiga, B., Mendera, M., Gimeno, D., Garcia-Valles, M., Fernandez-Turiel, J.L., Bazzocchi, F., Aulinas, M., Tarozzi, C.
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container_end_page 1554
container_issue 12
container_start_page 1545
container_title Materials characterization
container_volume 60
creator Basso, E.
Riccardi, M.P.
Messiga, B.
Mendera, M.
Gimeno, D.
Garcia-Valles, M.
Fernandez-Turiel, J.L.
Bazzocchi, F.
Aulinas, M.
Tarozzi, C.
description A set of 35 samples from the rose window of the Siena Cathedral (Tuscany, Italy) has been studied using EMPA to define the chemical composition (17 major and minor elements) of the base glass. This paper focuses on colourless and natural-coloured glasses, i.e. glass produced without the intentional addition of colouring agents. The presence of natural impurities of Fe and Mn, as well as the control of the furnace conditions plays an important role as well. Three compositional groups of natural-coloured glass have been identified taking into account the Al/Ti ratio and the K 2O and MgO concentrations. The most represented and homogeneous group contains the original glasses and defines the base glass composition. It is a soda–lime glass based on quartz (pure quartz sand or quartz-bearing pebbles/rocks) as vitrifying component and a Na-rich plant ash as flux. Restoration interventions explain the other two compositional groups. The compositional comparison of the original glass with coeval glass from Tuscany (Italy) has allowed us to postulate local production for them.
doi_str_mv 10.1016/j.matchar.2009.09.005
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source ScienceDirect Journals (5 years ago - present)
subjects Cross-disciplinary physics: materials science
rheology
EMPA
Exact sciences and technology
Glass composition
Late 13th century
Materials science
Phase diagrams and microstructures developed by solidification and solid-solid phase transformations
Physics
Plant ash
Solidification
Stained glass windows
title Composition of the base glass used to realize the stained glass windows by Duccio di Buoninsegna (Siena Cathedral, 1288–1289 AD): A geochemical approach
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