Composition of the base glass used to realize the stained glass windows by Duccio di Buoninsegna (Siena Cathedral, 1288–1289 AD): A geochemical approach
A set of 35 samples from the rose window of the Siena Cathedral (Tuscany, Italy) has been studied using EMPA to define the chemical composition (17 major and minor elements) of the base glass. This paper focuses on colourless and natural-coloured glasses, i.e. glass produced without the intentional...
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Veröffentlicht in: | Materials characterization 2009-12, Vol.60 (12), p.1545-1554 |
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creator | Basso, E. Riccardi, M.P. Messiga, B. Mendera, M. Gimeno, D. Garcia-Valles, M. Fernandez-Turiel, J.L. Bazzocchi, F. Aulinas, M. Tarozzi, C. |
description | A set of 35 samples from the rose window of the Siena Cathedral (Tuscany, Italy) has been studied using EMPA to define the chemical composition (17 major and minor elements) of the base glass. This paper focuses on colourless and natural-coloured glasses, i.e. glass produced without the intentional addition of colouring agents. The presence of natural impurities of Fe and Mn, as well as the control of the furnace conditions plays an important role as well. Three compositional groups of natural-coloured glass have been identified taking into account the Al/Ti ratio and the K
2O and MgO concentrations. The most represented and homogeneous group contains the original glasses and defines the base glass composition. It is a soda–lime glass based on quartz (pure quartz sand or quartz-bearing pebbles/rocks) as vitrifying component and a Na-rich plant ash as flux. Restoration interventions explain the other two compositional groups. The compositional comparison of the original glass with coeval glass from Tuscany (Italy) has allowed us to postulate local production for them. |
doi_str_mv | 10.1016/j.matchar.2009.09.005 |
format | Article |
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2O and MgO concentrations. The most represented and homogeneous group contains the original glasses and defines the base glass composition. It is a soda–lime glass based on quartz (pure quartz sand or quartz-bearing pebbles/rocks) as vitrifying component and a Na-rich plant ash as flux. Restoration interventions explain the other two compositional groups. The compositional comparison of the original glass with coeval glass from Tuscany (Italy) has allowed us to postulate local production for them.</description><identifier>ISSN: 1044-5803</identifier><identifier>EISSN: 1873-4189</identifier><identifier>DOI: 10.1016/j.matchar.2009.09.005</identifier><language>eng</language><publisher>New York, NY: Elsevier Inc</publisher><subject>Cross-disciplinary physics: materials science; rheology ; EMPA ; Exact sciences and technology ; Glass composition ; Late 13th century ; Materials science ; Phase diagrams and microstructures developed by solidification and solid-solid phase transformations ; Physics ; Plant ash ; Solidification ; Stained glass windows</subject><ispartof>Materials characterization, 2009-12, Vol.60 (12), p.1545-1554</ispartof><rights>2009 Elsevier Inc.</rights><rights>2015 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c370t-52a7e61478aa7d7480ebf3d2815df799c29fa53182173d3ad5de14f5a80fd3a13</citedby><cites>FETCH-LOGICAL-c370t-52a7e61478aa7d7480ebf3d2815df799c29fa53182173d3ad5de14f5a80fd3a13</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://www.sciencedirect.com/science/article/pii/S1044580309002836$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,776,780,3537,27901,27902,65306</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=22203890$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Basso, E.</creatorcontrib><creatorcontrib>Riccardi, M.P.</creatorcontrib><creatorcontrib>Messiga, B.</creatorcontrib><creatorcontrib>Mendera, M.</creatorcontrib><creatorcontrib>Gimeno, D.</creatorcontrib><creatorcontrib>Garcia-Valles, M.</creatorcontrib><creatorcontrib>Fernandez-Turiel, J.L.</creatorcontrib><creatorcontrib>Bazzocchi, F.</creatorcontrib><creatorcontrib>Aulinas, M.</creatorcontrib><creatorcontrib>Tarozzi, C.</creatorcontrib><title>Composition of the base glass used to realize the stained glass windows by Duccio di Buoninsegna (Siena Cathedral, 1288–1289 AD): A geochemical approach</title><title>Materials characterization</title><description>A set of 35 samples from the rose window of the Siena Cathedral (Tuscany, Italy) has been studied using EMPA to define the chemical composition (17 major and minor elements) of the base glass. This paper focuses on colourless and natural-coloured glasses, i.e. glass produced without the intentional addition of colouring agents. The presence of natural impurities of Fe and Mn, as well as the control of the furnace conditions plays an important role as well. Three compositional groups of natural-coloured glass have been identified taking into account the Al/Ti ratio and the K
2O and MgO concentrations. The most represented and homogeneous group contains the original glasses and defines the base glass composition. It is a soda–lime glass based on quartz (pure quartz sand or quartz-bearing pebbles/rocks) as vitrifying component and a Na-rich plant ash as flux. Restoration interventions explain the other two compositional groups. The compositional comparison of the original glass with coeval glass from Tuscany (Italy) has allowed us to postulate local production for them.</description><subject>Cross-disciplinary physics: materials science; rheology</subject><subject>EMPA</subject><subject>Exact sciences and technology</subject><subject>Glass composition</subject><subject>Late 13th century</subject><subject>Materials science</subject><subject>Phase diagrams and microstructures developed by solidification and solid-solid phase transformations</subject><subject>Physics</subject><subject>Plant ash</subject><subject>Solidification</subject><subject>Stained glass windows</subject><issn>1044-5803</issn><issn>1873-4189</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2009</creationdate><recordtype>article</recordtype><recordid>eNqFUcuOEzEQHCGQWBY-AckXEEg7wY95eLisQpaXtBIH4Gx17HbiaGYc3DOslhP_sDc-jy_BIRFXpJbKj6out6songq-EFw0r3aLASa7hbSQnHeLQ_H6XnEmdKvKSujufl7zqiprzdXD4hHRjnPeaNGeFb9WcdhHClOII4ueTVtkayBkmx6I2Ezo2BRZQujDD_x7TROEMR8fGTdhdPGG2PqWXc3WhshcYG_mOIaRcDMCe_E5YIYVZK1L0F8wIbX-_fMuQ8eWVy9fsyXbYLRbHIKFnsF-nyLY7ePigYee8MkJz4uv795-WX0orz-9_7haXpdWtXwqawktNqJqNUDr2kpzXHvlpBa1823XWdl5qJXQUrTKKXC1Q1H5GjT3eSvUefH82DfbfpuRJjMEstj3MGKcyaiqa_JTm0ysj0SbIlFCb_YpDJBujeDmkITZmVMS5pCEORSvs-7ZyQAoD-gTjDbQP7GUkivd8cy7PPIwT_s9YDJk899ZdCGhnYyL4T9OfwBn16JF</recordid><startdate>20091201</startdate><enddate>20091201</enddate><creator>Basso, E.</creator><creator>Riccardi, M.P.</creator><creator>Messiga, B.</creator><creator>Mendera, M.</creator><creator>Gimeno, D.</creator><creator>Garcia-Valles, M.</creator><creator>Fernandez-Turiel, J.L.</creator><creator>Bazzocchi, F.</creator><creator>Aulinas, M.</creator><creator>Tarozzi, C.</creator><general>Elsevier Inc</general><general>Elsevier</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20091201</creationdate><title>Composition of the base glass used to realize the stained glass windows by Duccio di Buoninsegna (Siena Cathedral, 1288–1289 AD): A geochemical approach</title><author>Basso, E. ; Riccardi, M.P. ; Messiga, B. ; Mendera, M. ; Gimeno, D. ; Garcia-Valles, M. ; Fernandez-Turiel, J.L. ; Bazzocchi, F. ; Aulinas, M. ; Tarozzi, C.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c370t-52a7e61478aa7d7480ebf3d2815df799c29fa53182173d3ad5de14f5a80fd3a13</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2009</creationdate><topic>Cross-disciplinary physics: materials science; rheology</topic><topic>EMPA</topic><topic>Exact sciences and technology</topic><topic>Glass composition</topic><topic>Late 13th century</topic><topic>Materials science</topic><topic>Phase diagrams and microstructures developed by solidification and solid-solid phase transformations</topic><topic>Physics</topic><topic>Plant ash</topic><topic>Solidification</topic><topic>Stained glass windows</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Basso, E.</creatorcontrib><creatorcontrib>Riccardi, M.P.</creatorcontrib><creatorcontrib>Messiga, B.</creatorcontrib><creatorcontrib>Mendera, M.</creatorcontrib><creatorcontrib>Gimeno, D.</creatorcontrib><creatorcontrib>Garcia-Valles, M.</creatorcontrib><creatorcontrib>Fernandez-Turiel, J.L.</creatorcontrib><creatorcontrib>Bazzocchi, F.</creatorcontrib><creatorcontrib>Aulinas, M.</creatorcontrib><creatorcontrib>Tarozzi, C.</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Materials characterization</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Basso, E.</au><au>Riccardi, M.P.</au><au>Messiga, B.</au><au>Mendera, M.</au><au>Gimeno, D.</au><au>Garcia-Valles, M.</au><au>Fernandez-Turiel, J.L.</au><au>Bazzocchi, F.</au><au>Aulinas, M.</au><au>Tarozzi, C.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Composition of the base glass used to realize the stained glass windows by Duccio di Buoninsegna (Siena Cathedral, 1288–1289 AD): A geochemical approach</atitle><jtitle>Materials characterization</jtitle><date>2009-12-01</date><risdate>2009</risdate><volume>60</volume><issue>12</issue><spage>1545</spage><epage>1554</epage><pages>1545-1554</pages><issn>1044-5803</issn><eissn>1873-4189</eissn><abstract>A set of 35 samples from the rose window of the Siena Cathedral (Tuscany, Italy) has been studied using EMPA to define the chemical composition (17 major and minor elements) of the base glass. 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2O and MgO concentrations. The most represented and homogeneous group contains the original glasses and defines the base glass composition. It is a soda–lime glass based on quartz (pure quartz sand or quartz-bearing pebbles/rocks) as vitrifying component and a Na-rich plant ash as flux. Restoration interventions explain the other two compositional groups. The compositional comparison of the original glass with coeval glass from Tuscany (Italy) has allowed us to postulate local production for them.</abstract><cop>New York, NY</cop><pub>Elsevier Inc</pub><doi>10.1016/j.matchar.2009.09.005</doi><tpages>10</tpages></addata></record> |
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subjects | Cross-disciplinary physics: materials science rheology EMPA Exact sciences and technology Glass composition Late 13th century Materials science Phase diagrams and microstructures developed by solidification and solid-solid phase transformations Physics Plant ash Solidification Stained glass windows |
title | Composition of the base glass used to realize the stained glass windows by Duccio di Buoninsegna (Siena Cathedral, 1288–1289 AD): A geochemical approach |
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