The effect of magnetic field on the catalytic graphitization of phenolic resin in the presence of Fe–Ni

The effect of an externally applied magnetic field on the Fe–Ni catalyzed graphitization of phenolic resin was investigated. The Fe and Ni doped phenolic resin was first carbonized at 800 °C and then graphitized at different temperatures (800–1200 °C). Both the carbonization and graphitization were...

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Veröffentlicht in:Carbon (New York) 2009-11, Vol.47 (14), p.3233-3237
Hauptverfasser: Xu, Shihai, Zhang, Fengying, Kang, Qing, Liu, Shaohuan, Cai, Qingyun
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container_end_page 3237
container_issue 14
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container_title Carbon (New York)
container_volume 47
creator Xu, Shihai
Zhang, Fengying
Kang, Qing
Liu, Shaohuan
Cai, Qingyun
description The effect of an externally applied magnetic field on the Fe–Ni catalyzed graphitization of phenolic resin was investigated. The Fe and Ni doped phenolic resin was first carbonized at 800 °C and then graphitized at different temperatures (800–1200 °C). Both the carbonization and graphitization were carried out in a magnetic field and the crystal structure was characterized by X-ray diffraction and transmission electron microscopy. The externally applied magnetic field was found to promote the graphitization and to improve the orientation of the hexagonal carbon layers. In the presence of Fe–Ni, a high degree of graphitization could be achieved by applying a magnetic field. This resulted in a d 002 of 0.3355 nm and full-width at half maximum (FWHM) value of 0.103° after a 1200 °C heat treatment. In comparison, the absence of a magnetic field resulted in a d 002 of 0.3358 nm and FWHM of 0.305°.
doi_str_mv 10.1016/j.carbon.2009.07.036
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subjects Catalysis
Chemistry
Cross-disciplinary physics: materials science
rheology
Exact sciences and technology
Fullerenes and related materials
diamonds, graphite
General and physical chemistry
Materials science
Physics
Specific materials
Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry
title The effect of magnetic field on the catalytic graphitization of phenolic resin in the presence of Fe–Ni
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