The effect of magnetic field on the catalytic graphitization of phenolic resin in the presence of Fe–Ni
The effect of an externally applied magnetic field on the Fe–Ni catalyzed graphitization of phenolic resin was investigated. The Fe and Ni doped phenolic resin was first carbonized at 800 °C and then graphitized at different temperatures (800–1200 °C). Both the carbonization and graphitization were...
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Veröffentlicht in: | Carbon (New York) 2009-11, Vol.47 (14), p.3233-3237 |
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creator | Xu, Shihai Zhang, Fengying Kang, Qing Liu, Shaohuan Cai, Qingyun |
description | The effect of an externally applied magnetic field on the Fe–Ni catalyzed graphitization of phenolic resin was investigated. The Fe and Ni doped phenolic resin was first carbonized at 800
°C and then graphitized at different temperatures (800–1200
°C). Both the carbonization and graphitization were carried out in a magnetic field and the crystal structure was characterized by X-ray diffraction and transmission electron microscopy. The externally applied magnetic field was found to promote the graphitization and to improve the orientation of the hexagonal carbon layers. In the presence of Fe–Ni, a high degree of graphitization could be achieved by applying a magnetic field. This resulted in a
d
002 of 0.3355
nm and full-width at half maximum (FWHM) value of 0.103° after a 1200
°C heat treatment. In comparison, the absence of a magnetic field resulted in a
d
002 of 0.3358
nm and FWHM of 0.305°. |
doi_str_mv | 10.1016/j.carbon.2009.07.036 |
format | Article |
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°C and then graphitized at different temperatures (800–1200
°C). Both the carbonization and graphitization were carried out in a magnetic field and the crystal structure was characterized by X-ray diffraction and transmission electron microscopy. The externally applied magnetic field was found to promote the graphitization and to improve the orientation of the hexagonal carbon layers. In the presence of Fe–Ni, a high degree of graphitization could be achieved by applying a magnetic field. This resulted in a
d
002 of 0.3355
nm and full-width at half maximum (FWHM) value of 0.103° after a 1200
°C heat treatment. In comparison, the absence of a magnetic field resulted in a
d
002 of 0.3358
nm and FWHM of 0.305°.</description><identifier>ISSN: 0008-6223</identifier><identifier>EISSN: 1873-3891</identifier><identifier>DOI: 10.1016/j.carbon.2009.07.036</identifier><identifier>CODEN: CRBNAH</identifier><language>eng</language><publisher>Kidlington: Elsevier Ltd</publisher><subject>Catalysis ; Chemistry ; Cross-disciplinary physics: materials science; rheology ; Exact sciences and technology ; Fullerenes and related materials; diamonds, graphite ; General and physical chemistry ; Materials science ; Physics ; Specific materials ; Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry</subject><ispartof>Carbon (New York), 2009-11, Vol.47 (14), p.3233-3237</ispartof><rights>2009</rights><rights>2009 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c433t-943b8b0460101ad3adc21c6d33930f564759ac172402a96636cafe3ef211f1603</citedby><cites>FETCH-LOGICAL-c433t-943b8b0460101ad3adc21c6d33930f564759ac172402a96636cafe3ef211f1603</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://www.sciencedirect.com/science/article/pii/S0008622309004618$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,776,780,3536,27903,27904,65309</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=21965307$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Xu, Shihai</creatorcontrib><creatorcontrib>Zhang, Fengying</creatorcontrib><creatorcontrib>Kang, Qing</creatorcontrib><creatorcontrib>Liu, Shaohuan</creatorcontrib><creatorcontrib>Cai, Qingyun</creatorcontrib><title>The effect of magnetic field on the catalytic graphitization of phenolic resin in the presence of Fe–Ni</title><title>Carbon (New York)</title><description>The effect of an externally applied magnetic field on the Fe–Ni catalyzed graphitization of phenolic resin was investigated. The Fe and Ni doped phenolic resin was first carbonized at 800
°C and then graphitized at different temperatures (800–1200
°C). Both the carbonization and graphitization were carried out in a magnetic field and the crystal structure was characterized by X-ray diffraction and transmission electron microscopy. The externally applied magnetic field was found to promote the graphitization and to improve the orientation of the hexagonal carbon layers. In the presence of Fe–Ni, a high degree of graphitization could be achieved by applying a magnetic field. This resulted in a
d
002 of 0.3355
nm and full-width at half maximum (FWHM) value of 0.103° after a 1200
°C heat treatment. In comparison, the absence of a magnetic field resulted in a
d
002 of 0.3358
nm and FWHM of 0.305°.</description><subject>Catalysis</subject><subject>Chemistry</subject><subject>Cross-disciplinary physics: materials science; rheology</subject><subject>Exact sciences and technology</subject><subject>Fullerenes and related materials; diamonds, graphite</subject><subject>General and physical chemistry</subject><subject>Materials science</subject><subject>Physics</subject><subject>Specific materials</subject><subject>Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry</subject><issn>0008-6223</issn><issn>1873-3891</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2009</creationdate><recordtype>article</recordtype><recordid>eNp9kM1KxTAQhYMoeP15Axfd6K510qRpuxFE_APRja7D3HTizaW3rUkVdOU7-IY-iSkVl66GmXPODPMxdsQh48DV6Toz6Jd9l-UAdQZlBkJtsQWvSpGKqubbbAEAVaryXOyyvRDWsZUVlwvmHleUkLVkxqS3yQafOxqdSayjtkn6LhmjbnDE9n0aP3scVm50Hzi6KMbEsKKub6PkKbgucXNiiB11hibHFX1_ft27A7ZjsQ10-Fv32dPV5ePFTXr3cH17cX6XGinEmNZSLKslSAXxNWwENibnRjVC1AJsoWRZ1Gh4mUvIsVZKKIOWBNmcc8sViH12Mu8dfP_ySmHUGxcMtS121L8GLWQtC1VMRjkbje9D8GT14N0G_bvmoCeueq1nrnriqqHUkWuMHf_ux2CwtR4748JfNue1KgSU0Xc2-yg---bI62DcxKRxPtLWTe_-P_QDHd2Qhw</recordid><startdate>20091101</startdate><enddate>20091101</enddate><creator>Xu, Shihai</creator><creator>Zhang, Fengying</creator><creator>Kang, Qing</creator><creator>Liu, Shaohuan</creator><creator>Cai, Qingyun</creator><general>Elsevier Ltd</general><general>Elsevier</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20091101</creationdate><title>The effect of magnetic field on the catalytic graphitization of phenolic resin in the presence of Fe–Ni</title><author>Xu, Shihai ; Zhang, Fengying ; Kang, Qing ; Liu, Shaohuan ; Cai, Qingyun</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c433t-943b8b0460101ad3adc21c6d33930f564759ac172402a96636cafe3ef211f1603</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2009</creationdate><topic>Catalysis</topic><topic>Chemistry</topic><topic>Cross-disciplinary physics: materials science; rheology</topic><topic>Exact sciences and technology</topic><topic>Fullerenes and related materials; diamonds, graphite</topic><topic>General and physical chemistry</topic><topic>Materials science</topic><topic>Physics</topic><topic>Specific materials</topic><topic>Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Xu, Shihai</creatorcontrib><creatorcontrib>Zhang, Fengying</creatorcontrib><creatorcontrib>Kang, Qing</creatorcontrib><creatorcontrib>Liu, Shaohuan</creatorcontrib><creatorcontrib>Cai, Qingyun</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Carbon (New York)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Xu, Shihai</au><au>Zhang, Fengying</au><au>Kang, Qing</au><au>Liu, Shaohuan</au><au>Cai, Qingyun</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>The effect of magnetic field on the catalytic graphitization of phenolic resin in the presence of Fe–Ni</atitle><jtitle>Carbon (New York)</jtitle><date>2009-11-01</date><risdate>2009</risdate><volume>47</volume><issue>14</issue><spage>3233</spage><epage>3237</epage><pages>3233-3237</pages><issn>0008-6223</issn><eissn>1873-3891</eissn><coden>CRBNAH</coden><abstract>The effect of an externally applied magnetic field on the Fe–Ni catalyzed graphitization of phenolic resin was investigated. The Fe and Ni doped phenolic resin was first carbonized at 800
°C and then graphitized at different temperatures (800–1200
°C). Both the carbonization and graphitization were carried out in a magnetic field and the crystal structure was characterized by X-ray diffraction and transmission electron microscopy. The externally applied magnetic field was found to promote the graphitization and to improve the orientation of the hexagonal carbon layers. In the presence of Fe–Ni, a high degree of graphitization could be achieved by applying a magnetic field. This resulted in a
d
002 of 0.3355
nm and full-width at half maximum (FWHM) value of 0.103° after a 1200
°C heat treatment. In comparison, the absence of a magnetic field resulted in a
d
002 of 0.3358
nm and FWHM of 0.305°.</abstract><cop>Kidlington</cop><pub>Elsevier Ltd</pub><doi>10.1016/j.carbon.2009.07.036</doi><tpages>5</tpages></addata></record> |
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language | eng |
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source | Elsevier ScienceDirect Journals |
subjects | Catalysis Chemistry Cross-disciplinary physics: materials science rheology Exact sciences and technology Fullerenes and related materials diamonds, graphite General and physical chemistry Materials science Physics Specific materials Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry |
title | The effect of magnetic field on the catalytic graphitization of phenolic resin in the presence of Fe–Ni |
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