Separation and preconcentration of trace amounts of aluminum ions in surface water samples using different analytical techniques
A separation/preconcentration of aluminum (III) (Al 3+) has been developed to overcome the problem of high matrix species, which may interfere with the determination of trace quantity of Al 3+ in natural water samples. The separation of Al 3+ in water samples was carried out from interfering cations...
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| Veröffentlicht in: | Talanta (Oxford) 2009-11, Vol.80 (1), p.158-162 |
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| creator | Khan, Sumaira Kazi, Tasneem G. Baig, Jameel A. Kolachi, Nida F. Afridi, Hassan I. Shah, Abdul Q. Kandhro, Ghulam A. Kumar, Sham |
| description | A separation/preconcentration of aluminum (III) (Al
3+) has been developed to overcome the problem of high matrix species, which may interfere with the determination of trace quantity of Al
3+ in natural water samples. The separation of Al
3+ in water samples was carried out from interfering cations by complexing them with 2-methyle 8-hyroxyquinoline (quinaldine) on activated silica. Whereas the separated trace amounts of Al
3+ was preconcentrated by cloud point extraction (CPE), as prior step to its determination by spectrofluorimetry (SPF) and flame atomic absorption spectrometry (FAAS). The Al
3+ react with 8-hydroxyquinoline (oxine) and then entrapped in non-ionic surfactant Triton X-114. The main factors affecting CPE efficiency, such as pH of sample solution, concentration of oxine and Triton X-114, equilibration temperature and time period for shaking were investigated in detail. The validity of separation/preconcentration of Al
3+ was checked by certified reference material of water (SRM-1643e). After optimization of the complexation and extraction conditions, a preconcentration factor of 20 was obtained for Al
3+ in 10
mL of natural water samples. The relative standard deviation for 6 replicates containing 100
μg
L
−1 of Al
3+ was 5.41 and 4.53% for SPF and FAAS, respectively. The proposed method has been applied for determination of trace amount of Al
3+ in natural water samples with satisfactory results. |
| doi_str_mv | 10.1016/j.talanta.2009.06.055 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_34940411</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><els_id>S0039914009004810</els_id><sourcerecordid>21063739</sourcerecordid><originalsourceid>FETCH-LOGICAL-c456t-7154dc57ae25c0d5800554fe92735a618705c2ef3e614ca36a3ae2a1c5fb349a3</originalsourceid><addsrcrecordid>eNqFkUFv1DAQhSMEokvhJ4B8gVvC2I6dzQmhCihSJQ7A2Zo6Y_AqcYLtgHrjp-NoI3rsydbomzcz71XVSw4NB67fnpqMI4aMjQDoG9ANKPWoOvBjJ2upOvm4OgDIvu55CxfVs5ROACAkyKfVBe-7oxCgD9Xfr7RgxOznwDAMbIlk52Ap5L04O1a-lhhO8xpy2go4rpMP68QKkJgPLK3RbcwfzBRZwmkZKbE1-fCDDd45ikWw6ON4l73FkWWyP4P_tVJ6Xj1xOCZ6sb-X1fePH75dXdc3Xz59vnp_U9tW6Vx3XLWDVR2SUBYGdYRybuuoF51UqMvVoKwgJ0nz1qLUKAuK3Cp3K9se5WX15qy7xHmbm83kk6WxeEjzmkyBWmg5fxAUHLTsZF9AdQZtnFOK5MwS_YTxznAwW0bmZPaMzJaRAW3K0qXv1T5gvZ1ouO_aQynA6x3AVMxyEYP16T8nhJK679vCvTtzVHz77SmaZD2V8AZfUsxmmP0Dq_wDPa60_w</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>21063739</pqid></control><display><type>article</type><title>Separation and preconcentration of trace amounts of aluminum ions in surface water samples using different analytical techniques</title><source>MEDLINE</source><source>ScienceDirect Journals (5 years ago - present)</source><creator>Khan, Sumaira ; Kazi, Tasneem G. ; Baig, Jameel A. ; Kolachi, Nida F. ; Afridi, Hassan I. ; Shah, Abdul Q. ; Kandhro, Ghulam A. ; Kumar, Sham</creator><creatorcontrib>Khan, Sumaira ; Kazi, Tasneem G. ; Baig, Jameel A. ; Kolachi, Nida F. ; Afridi, Hassan I. ; Shah, Abdul Q. ; Kandhro, Ghulam A. ; Kumar, Sham</creatorcontrib><description>A separation/preconcentration of aluminum (III) (Al
3+) has been developed to overcome the problem of high matrix species, which may interfere with the determination of trace quantity of Al
3+ in natural water samples. The separation of Al
3+ in water samples was carried out from interfering cations by complexing them with 2-methyle 8-hyroxyquinoline (quinaldine) on activated silica. Whereas the separated trace amounts of Al
3+ was preconcentrated by cloud point extraction (CPE), as prior step to its determination by spectrofluorimetry (SPF) and flame atomic absorption spectrometry (FAAS). The Al
3+ react with 8-hydroxyquinoline (oxine) and then entrapped in non-ionic surfactant Triton X-114. The main factors affecting CPE efficiency, such as pH of sample solution, concentration of oxine and Triton X-114, equilibration temperature and time period for shaking were investigated in detail. The validity of separation/preconcentration of Al
3+ was checked by certified reference material of water (SRM-1643e). After optimization of the complexation and extraction conditions, a preconcentration factor of 20 was obtained for Al
3+ in 10
mL of natural water samples. The relative standard deviation for 6 replicates containing 100
μg
L
−1 of Al
3+ was 5.41 and 4.53% for SPF and FAAS, respectively. The proposed method has been applied for determination of trace amount of Al
3+ in natural water samples with satisfactory results.</description><identifier>ISSN: 0039-9140</identifier><identifier>EISSN: 1873-3573</identifier><identifier>DOI: 10.1016/j.talanta.2009.06.055</identifier><identifier>PMID: 19782206</identifier><identifier>CODEN: TLNTA2</identifier><language>eng</language><publisher>Amsterdam: Elsevier B.V</publisher><subject>8-Hydroxyquinoline ; Adsorption ; Aluminum ; Aluminum - analysis ; Aluminum - chemistry ; Aluminum - isolation & purification ; Analytical chemistry ; Cations ; Chemistry ; Cloud point extraction ; Clouds ; Environmental Monitoring - methods ; Exact sciences and technology ; Extraction ; Fresh Water - analysis ; Fresh Water - chemistry ; Hydrogen-Ion Concentration ; Oxyquinoline - chemistry ; Polyethylene Glycols - chemistry ; Quinaldines - chemistry ; Reproducibility of Results ; Separation ; Solid Phase Extraction ; Spectrometric and optical methods ; Spectrometry, Fluorescence - methods ; Spectrophotometry, Atomic - methods ; Superplastic forming ; Surface water ; Triton ; Triton X-114 ; Water Pollutants, Chemical - analysis ; Water Pollutants, Chemical - isolation & purification ; Water sample</subject><ispartof>Talanta (Oxford), 2009-11, Vol.80 (1), p.158-162</ispartof><rights>2009 Elsevier B.V.</rights><rights>2015 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c456t-7154dc57ae25c0d5800554fe92735a618705c2ef3e614ca36a3ae2a1c5fb349a3</citedby></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.talanta.2009.06.055$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,780,784,3550,27924,27925,45995</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=22536994$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/19782206$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Khan, Sumaira</creatorcontrib><creatorcontrib>Kazi, Tasneem G.</creatorcontrib><creatorcontrib>Baig, Jameel A.</creatorcontrib><creatorcontrib>Kolachi, Nida F.</creatorcontrib><creatorcontrib>Afridi, Hassan I.</creatorcontrib><creatorcontrib>Shah, Abdul Q.</creatorcontrib><creatorcontrib>Kandhro, Ghulam A.</creatorcontrib><creatorcontrib>Kumar, Sham</creatorcontrib><title>Separation and preconcentration of trace amounts of aluminum ions in surface water samples using different analytical techniques</title><title>Talanta (Oxford)</title><addtitle>Talanta</addtitle><description>A separation/preconcentration of aluminum (III) (Al
3+) has been developed to overcome the problem of high matrix species, which may interfere with the determination of trace quantity of Al
3+ in natural water samples. The separation of Al
3+ in water samples was carried out from interfering cations by complexing them with 2-methyle 8-hyroxyquinoline (quinaldine) on activated silica. Whereas the separated trace amounts of Al
3+ was preconcentrated by cloud point extraction (CPE), as prior step to its determination by spectrofluorimetry (SPF) and flame atomic absorption spectrometry (FAAS). The Al
3+ react with 8-hydroxyquinoline (oxine) and then entrapped in non-ionic surfactant Triton X-114. The main factors affecting CPE efficiency, such as pH of sample solution, concentration of oxine and Triton X-114, equilibration temperature and time period for shaking were investigated in detail. The validity of separation/preconcentration of Al
3+ was checked by certified reference material of water (SRM-1643e). After optimization of the complexation and extraction conditions, a preconcentration factor of 20 was obtained for Al
3+ in 10
mL of natural water samples. The relative standard deviation for 6 replicates containing 100
μg
L
−1 of Al
3+ was 5.41 and 4.53% for SPF and FAAS, respectively. The proposed method has been applied for determination of trace amount of Al
3+ in natural water samples with satisfactory results.</description><subject>8-Hydroxyquinoline</subject><subject>Adsorption</subject><subject>Aluminum</subject><subject>Aluminum - analysis</subject><subject>Aluminum - chemistry</subject><subject>Aluminum - isolation & purification</subject><subject>Analytical chemistry</subject><subject>Cations</subject><subject>Chemistry</subject><subject>Cloud point extraction</subject><subject>Clouds</subject><subject>Environmental Monitoring - methods</subject><subject>Exact sciences and technology</subject><subject>Extraction</subject><subject>Fresh Water - analysis</subject><subject>Fresh Water - chemistry</subject><subject>Hydrogen-Ion Concentration</subject><subject>Oxyquinoline - chemistry</subject><subject>Polyethylene Glycols - chemistry</subject><subject>Quinaldines - chemistry</subject><subject>Reproducibility of Results</subject><subject>Separation</subject><subject>Solid Phase Extraction</subject><subject>Spectrometric and optical methods</subject><subject>Spectrometry, Fluorescence - methods</subject><subject>Spectrophotometry, Atomic - methods</subject><subject>Superplastic forming</subject><subject>Surface water</subject><subject>Triton</subject><subject>Triton X-114</subject><subject>Water Pollutants, Chemical - analysis</subject><subject>Water Pollutants, Chemical - isolation & purification</subject><subject>Water sample</subject><issn>0039-9140</issn><issn>1873-3573</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2009</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNqFkUFv1DAQhSMEokvhJ4B8gVvC2I6dzQmhCihSJQ7A2Zo6Y_AqcYLtgHrjp-NoI3rsydbomzcz71XVSw4NB67fnpqMI4aMjQDoG9ANKPWoOvBjJ2upOvm4OgDIvu55CxfVs5ROACAkyKfVBe-7oxCgD9Xfr7RgxOznwDAMbIlk52Ap5L04O1a-lhhO8xpy2go4rpMP68QKkJgPLK3RbcwfzBRZwmkZKbE1-fCDDd45ikWw6ON4l73FkWWyP4P_tVJ6Xj1xOCZ6sb-X1fePH75dXdc3Xz59vnp_U9tW6Vx3XLWDVR2SUBYGdYRybuuoF51UqMvVoKwgJ0nz1qLUKAuK3Cp3K9se5WX15qy7xHmbm83kk6WxeEjzmkyBWmg5fxAUHLTsZF9AdQZtnFOK5MwS_YTxznAwW0bmZPaMzJaRAW3K0qXv1T5gvZ1ouO_aQynA6x3AVMxyEYP16T8nhJK679vCvTtzVHz77SmaZD2V8AZfUsxmmP0Dq_wDPa60_w</recordid><startdate>20091115</startdate><enddate>20091115</enddate><creator>Khan, Sumaira</creator><creator>Kazi, Tasneem G.</creator><creator>Baig, Jameel A.</creator><creator>Kolachi, Nida F.</creator><creator>Afridi, Hassan I.</creator><creator>Shah, Abdul Q.</creator><creator>Kandhro, Ghulam A.</creator><creator>Kumar, Sham</creator><general>Elsevier B.V</general><general>Elsevier</general><scope>IQODW</scope><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7QF</scope><scope>7QQ</scope><scope>7SR</scope><scope>7SU</scope><scope>8FD</scope><scope>C1K</scope><scope>FR3</scope><scope>JG9</scope></search><sort><creationdate>20091115</creationdate><title>Separation and preconcentration of trace amounts of aluminum ions in surface water samples using different analytical techniques</title><author>Khan, Sumaira ; Kazi, Tasneem G. ; Baig, Jameel A. ; Kolachi, Nida F. ; Afridi, Hassan I. ; Shah, Abdul Q. ; Kandhro, Ghulam A. ; Kumar, Sham</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c456t-7154dc57ae25c0d5800554fe92735a618705c2ef3e614ca36a3ae2a1c5fb349a3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2009</creationdate><topic>8-Hydroxyquinoline</topic><topic>Adsorption</topic><topic>Aluminum</topic><topic>Aluminum - analysis</topic><topic>Aluminum - chemistry</topic><topic>Aluminum - isolation & purification</topic><topic>Analytical chemistry</topic><topic>Cations</topic><topic>Chemistry</topic><topic>Cloud point extraction</topic><topic>Clouds</topic><topic>Environmental Monitoring - methods</topic><topic>Exact sciences and technology</topic><topic>Extraction</topic><topic>Fresh Water - analysis</topic><topic>Fresh Water - chemistry</topic><topic>Hydrogen-Ion Concentration</topic><topic>Oxyquinoline - chemistry</topic><topic>Polyethylene Glycols - chemistry</topic><topic>Quinaldines - chemistry</topic><topic>Reproducibility of Results</topic><topic>Separation</topic><topic>Solid Phase Extraction</topic><topic>Spectrometric and optical methods</topic><topic>Spectrometry, Fluorescence - methods</topic><topic>Spectrophotometry, Atomic - methods</topic><topic>Superplastic forming</topic><topic>Surface water</topic><topic>Triton</topic><topic>Triton X-114</topic><topic>Water Pollutants, Chemical - analysis</topic><topic>Water Pollutants, Chemical - isolation & purification</topic><topic>Water sample</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Khan, Sumaira</creatorcontrib><creatorcontrib>Kazi, Tasneem G.</creatorcontrib><creatorcontrib>Baig, Jameel A.</creatorcontrib><creatorcontrib>Kolachi, Nida F.</creatorcontrib><creatorcontrib>Afridi, Hassan I.</creatorcontrib><creatorcontrib>Shah, Abdul Q.</creatorcontrib><creatorcontrib>Kandhro, Ghulam A.</creatorcontrib><creatorcontrib>Kumar, Sham</creatorcontrib><collection>Pascal-Francis</collection><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>Aluminium Industry Abstracts</collection><collection>Ceramic Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>Environmental Engineering Abstracts</collection><collection>Technology Research Database</collection><collection>Environmental Sciences and Pollution Management</collection><collection>Engineering Research Database</collection><collection>Materials Research Database</collection><jtitle>Talanta (Oxford)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Khan, Sumaira</au><au>Kazi, Tasneem G.</au><au>Baig, Jameel A.</au><au>Kolachi, Nida F.</au><au>Afridi, Hassan I.</au><au>Shah, Abdul Q.</au><au>Kandhro, Ghulam A.</au><au>Kumar, Sham</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Separation and preconcentration of trace amounts of aluminum ions in surface water samples using different analytical techniques</atitle><jtitle>Talanta (Oxford)</jtitle><addtitle>Talanta</addtitle><date>2009-11-15</date><risdate>2009</risdate><volume>80</volume><issue>1</issue><spage>158</spage><epage>162</epage><pages>158-162</pages><issn>0039-9140</issn><eissn>1873-3573</eissn><coden>TLNTA2</coden><abstract>A separation/preconcentration of aluminum (III) (Al
3+) has been developed to overcome the problem of high matrix species, which may interfere with the determination of trace quantity of Al
3+ in natural water samples. The separation of Al
3+ in water samples was carried out from interfering cations by complexing them with 2-methyle 8-hyroxyquinoline (quinaldine) on activated silica. Whereas the separated trace amounts of Al
3+ was preconcentrated by cloud point extraction (CPE), as prior step to its determination by spectrofluorimetry (SPF) and flame atomic absorption spectrometry (FAAS). The Al
3+ react with 8-hydroxyquinoline (oxine) and then entrapped in non-ionic surfactant Triton X-114. The main factors affecting CPE efficiency, such as pH of sample solution, concentration of oxine and Triton X-114, equilibration temperature and time period for shaking were investigated in detail. The validity of separation/preconcentration of Al
3+ was checked by certified reference material of water (SRM-1643e). After optimization of the complexation and extraction conditions, a preconcentration factor of 20 was obtained for Al
3+ in 10
mL of natural water samples. The relative standard deviation for 6 replicates containing 100
μg
L
−1 of Al
3+ was 5.41 and 4.53% for SPF and FAAS, respectively. The proposed method has been applied for determination of trace amount of Al
3+ in natural water samples with satisfactory results.</abstract><cop>Amsterdam</cop><pub>Elsevier B.V</pub><pmid>19782206</pmid><doi>10.1016/j.talanta.2009.06.055</doi><tpages>5</tpages></addata></record> |
| fulltext | fulltext |
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| ispartof | Talanta (Oxford), 2009-11, Vol.80 (1), p.158-162 |
| issn | 0039-9140 1873-3573 |
| language | eng |
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| source | MEDLINE; ScienceDirect Journals (5 years ago - present) |
| subjects | 8-Hydroxyquinoline Adsorption Aluminum Aluminum - analysis Aluminum - chemistry Aluminum - isolation & purification Analytical chemistry Cations Chemistry Cloud point extraction Clouds Environmental Monitoring - methods Exact sciences and technology Extraction Fresh Water - analysis Fresh Water - chemistry Hydrogen-Ion Concentration Oxyquinoline - chemistry Polyethylene Glycols - chemistry Quinaldines - chemistry Reproducibility of Results Separation Solid Phase Extraction Spectrometric and optical methods Spectrometry, Fluorescence - methods Spectrophotometry, Atomic - methods Superplastic forming Surface water Triton Triton X-114 Water Pollutants, Chemical - analysis Water Pollutants, Chemical - isolation & purification Water sample |
| title | Separation and preconcentration of trace amounts of aluminum ions in surface water samples using different analytical techniques |
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