Ising-like model study of size dependence relaxation in spin crossover complexes

In this paper we present a theoretical study of size effects during relaxation in spin transition solids. The systems are described using an Ising-like model consisting of molecules having two energy levels and fictitious spin values of +1, (HS) and −1 (LS). We compare relaxation in various 2D or 3D...

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Veröffentlicht in:Journal of magnetism and magnetic materials 2009-12, Vol.321 (24), p.4132-4138
Hauptverfasser: Dobrinescu, Alexandra, Enachescu, Cristian, Stancu, Alexandru
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creator Dobrinescu, Alexandra
Enachescu, Cristian
Stancu, Alexandru
description In this paper we present a theoretical study of size effects during relaxation in spin transition solids. The systems are described using an Ising-like model consisting of molecules having two energy levels and fictitious spin values of +1, (HS) and −1 (LS). We compare relaxation in various 2D or 3D systems (rectangular, hexagonal or cubic) and we realise an exhaustive analysis of the parameters that influence the relaxation in small size samples. The differences between homogenous and inhomogeneous systems reflected on the shapes of relaxation curves are discussed and analysed.
doi_str_mv 10.1016/j.jmmm.2009.08.017
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subjects Condensed matter: electronic structure, electrical, magnetic, and optical properties
Exact sciences and technology
Ising-like system
Magnetic properties and materials
Magnetically ordered materials: other intrinsic properties
Physics
Size effect
Spin crossover
Spin crossover complex
title Ising-like model study of size dependence relaxation in spin crossover complexes
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