Predominant dissociation of the CO(D2Π)n(d/s)σ Rydberg states into atomic excited Rydberg fragments with the same effective principal quantum number

Predominant dissociation of the CO(D2Π)n(d/s)σ Rydberg states into atomic excited Rydberg fragments with the same effective principal quantum number

Dissociation of the CO molecule excited in the photon energy range between 20 eV and 25 eV is investigated by photon-induced fluorescence spectroscopy (PIFS) detecting dispersed fluorescence from C I* 2s22p1n(d/s) fragments in the spectral range of 115-135 nm. First experimental indications were fou...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Journal of physics. B, Atomic, molecular, and optical physics Atomic, molecular, and optical physics, 2009-08, Vol.42 (16), p.165103-165103 (10)
Hauptverfasser: Ehresmann, A, Demekhin, Ph V, Kielich, W, Haar, I, Schlüter, M A, Sukhorukov, V L, Schmoranzer, H
Format: Artikel
Sprache:eng
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
container_end_page 165103 (10)
container_issue 16
container_start_page 165103
container_title Journal of physics. B, Atomic, molecular, and optical physics
container_volume 42
creator Ehresmann, A
Demekhin, Ph V
Kielich, W
Haar, I
Schlüter, M A
Sukhorukov, V L
Schmoranzer, H
description Dissociation of the CO molecule excited in the photon energy range between 20 eV and 25 eV is investigated by photon-induced fluorescence spectroscopy (PIFS) detecting dispersed fluorescence from C I* 2s22p1n(d/s) fragments in the spectral range of 115-135 nm. First experimental indications were found for a predominant dissociation of the CO*(D2Pi)n(d/s)sigma Rydberg states into the Rydberg states of the neutral C I atom conserving the effective principal quantum number n* = n - delta of the Rydberg electron. Such a process has as yet been verified only for the dissociating molecular Rydberg series (c4Sigma-u)n(d/s)sigmag3Sigma-u in O*2 (H Liebel et al 2000 Phys. Lett. 267 267). The selective dissociation of the molecular Rydberg states into atomic ones is interpreted by theoretical potential energy curves of the CO+ ion and molecular orbitals of Rydberg electrons computed within the single-centre approach.
doi_str_mv 10.1088/0953-4075/42/16/165103
format Article
fullrecord <record><control><sourceid>proquest_pasca</sourceid><recordid>TN_cdi_proquest_miscellaneous_34906268</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>34906268</sourcerecordid><originalsourceid>FETCH-LOGICAL-c396t-c526ceb720db2560ddd841bf114cf55efaebeb9adc1392504fcc535c9f63bfc63</originalsourceid><addsrcrecordid>eNqFkc1u1DAUhS0EEkPhFZA3oHaRjq8du8kSDX-VKhVVsLYc-7o1SuI0doCueQfWPFH7SniYajYgVbLkhb9zfO65hLwEdgysadaslaKq2Ylc13wNqhwJTDwiKxAKKlVL-Zis9tBT8iylr4wBNJytyK9PM7o4hNGMmbqQUrTB5BBHGj3NV0g354dv-e3vo_HQrdPR3U96ceM6nC9pyiZjomHMkZpcLCzFHzZkdHvEz-ZywDEn-j3kq792yQxI0Xu0OXxDOs1htGEyPb1eSoJloOMyFO1z8sSbPuGL-_uAfHn_7vPmY3V2_uF08-assqJVubKSK4vdCWeu41Ix51xTQ-cBauulRG-ww641zoJouWS1t1YKaVuvROetEgfk9c53muP1ginrISSLfW9GjEvSom6Z4qopoNqBdo4pzeh1iT6Y-UYD09s16G3DetuwrrkGpXdrKMJX9z-YZE1fKikDp72aQ8tACShcteNCnPav__fUk_OFh3_5B7L8AXn5qKY</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>34906268</pqid></control><display><type>article</type><title>Predominant dissociation of the CO(D2Π)n(d/s)σ Rydberg states into atomic excited Rydberg fragments with the same effective principal quantum number</title><source>Institute of Physics Journals</source><creator>Ehresmann, A ; Demekhin, Ph V ; Kielich, W ; Haar, I ; Schlüter, M A ; Sukhorukov, V L ; Schmoranzer, H</creator><creatorcontrib>Ehresmann, A ; Demekhin, Ph V ; Kielich, W ; Haar, I ; Schlüter, M A ; Sukhorukov, V L ; Schmoranzer, H</creatorcontrib><description>Dissociation of the CO molecule excited in the photon energy range between 20 eV and 25 eV is investigated by photon-induced fluorescence spectroscopy (PIFS) detecting dispersed fluorescence from C I* 2s22p1n(d/s) fragments in the spectral range of 115-135 nm. First experimental indications were found for a predominant dissociation of the CO*(D2Pi)n(d/s)sigma Rydberg states into the Rydberg states of the neutral C I atom conserving the effective principal quantum number n* = n - delta of the Rydberg electron. Such a process has as yet been verified only for the dissociating molecular Rydberg series (c4Sigma-u)n(d/s)sigmag3Sigma-u in O*2 (H Liebel et al 2000 Phys. Lett. 267 267). The selective dissociation of the molecular Rydberg states into atomic ones is interpreted by theoretical potential energy curves of the CO+ ion and molecular orbitals of Rydberg electrons computed within the single-centre approach.</description><identifier>ISSN: 0953-4075</identifier><identifier>EISSN: 1361-6455</identifier><identifier>DOI: 10.1088/0953-4075/42/16/165103</identifier><identifier>CODEN: JPAPEH</identifier><language>eng</language><publisher>Bristol: IOP Publishing</publisher><ispartof>Journal of physics. B, Atomic, molecular, and optical physics, 2009-08, Vol.42 (16), p.165103-165103 (10)</ispartof><rights>2009 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c396t-c526ceb720db2560ddd841bf114cf55efaebeb9adc1392504fcc535c9f63bfc63</citedby><cites>FETCH-LOGICAL-c396t-c526ceb720db2560ddd841bf114cf55efaebeb9adc1392504fcc535c9f63bfc63</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://iopscience.iop.org/article/10.1088/0953-4075/42/16/165103/pdf$$EPDF$$P50$$Giop$$H</linktopdf><link.rule.ids>314,780,784,27924,27925,53830,53910</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&amp;idt=21901631$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Ehresmann, A</creatorcontrib><creatorcontrib>Demekhin, Ph V</creatorcontrib><creatorcontrib>Kielich, W</creatorcontrib><creatorcontrib>Haar, I</creatorcontrib><creatorcontrib>Schlüter, M A</creatorcontrib><creatorcontrib>Sukhorukov, V L</creatorcontrib><creatorcontrib>Schmoranzer, H</creatorcontrib><title>Predominant dissociation of the CO(D2Π)n(d/s)σ Rydberg states into atomic excited Rydberg fragments with the same effective principal quantum number</title><title>Journal of physics. B, Atomic, molecular, and optical physics</title><description>Dissociation of the CO molecule excited in the photon energy range between 20 eV and 25 eV is investigated by photon-induced fluorescence spectroscopy (PIFS) detecting dispersed fluorescence from C I* 2s22p1n(d/s) fragments in the spectral range of 115-135 nm. First experimental indications were found for a predominant dissociation of the CO*(D2Pi)n(d/s)sigma Rydberg states into the Rydberg states of the neutral C I atom conserving the effective principal quantum number n* = n - delta of the Rydberg electron. Such a process has as yet been verified only for the dissociating molecular Rydberg series (c4Sigma-u)n(d/s)sigmag3Sigma-u in O*2 (H Liebel et al 2000 Phys. Lett. 267 267). The selective dissociation of the molecular Rydberg states into atomic ones is interpreted by theoretical potential energy curves of the CO+ ion and molecular orbitals of Rydberg electrons computed within the single-centre approach.</description><issn>0953-4075</issn><issn>1361-6455</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2009</creationdate><recordtype>article</recordtype><recordid>eNqFkc1u1DAUhS0EEkPhFZA3oHaRjq8du8kSDX-VKhVVsLYc-7o1SuI0doCueQfWPFH7SniYajYgVbLkhb9zfO65hLwEdgysadaslaKq2Ylc13wNqhwJTDwiKxAKKlVL-Zis9tBT8iylr4wBNJytyK9PM7o4hNGMmbqQUrTB5BBHGj3NV0g354dv-e3vo_HQrdPR3U96ceM6nC9pyiZjomHMkZpcLCzFHzZkdHvEz-ZywDEn-j3kq792yQxI0Xu0OXxDOs1htGEyPb1eSoJloOMyFO1z8sSbPuGL-_uAfHn_7vPmY3V2_uF08-assqJVubKSK4vdCWeu41Ix51xTQ-cBauulRG-ww641zoJouWS1t1YKaVuvROetEgfk9c53muP1ginrISSLfW9GjEvSom6Z4qopoNqBdo4pzeh1iT6Y-UYD09s16G3DetuwrrkGpXdrKMJX9z-YZE1fKikDp72aQ8tACShcteNCnPav__fUk_OFh3_5B7L8AXn5qKY</recordid><startdate>20090828</startdate><enddate>20090828</enddate><creator>Ehresmann, A</creator><creator>Demekhin, Ph V</creator><creator>Kielich, W</creator><creator>Haar, I</creator><creator>Schlüter, M A</creator><creator>Sukhorukov, V L</creator><creator>Schmoranzer, H</creator><general>IOP Publishing</general><general>Institute of Physics</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7U5</scope><scope>8FD</scope><scope>L7M</scope></search><sort><creationdate>20090828</creationdate><title>Predominant dissociation of the CO(D2Π)n(d/s)σ Rydberg states into atomic excited Rydberg fragments with the same effective principal quantum number</title><author>Ehresmann, A ; Demekhin, Ph V ; Kielich, W ; Haar, I ; Schlüter, M A ; Sukhorukov, V L ; Schmoranzer, H</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c396t-c526ceb720db2560ddd841bf114cf55efaebeb9adc1392504fcc535c9f63bfc63</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2009</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Ehresmann, A</creatorcontrib><creatorcontrib>Demekhin, Ph V</creatorcontrib><creatorcontrib>Kielich, W</creatorcontrib><creatorcontrib>Haar, I</creatorcontrib><creatorcontrib>Schlüter, M A</creatorcontrib><creatorcontrib>Sukhorukov, V L</creatorcontrib><creatorcontrib>Schmoranzer, H</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Technology Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Journal of physics. B, Atomic, molecular, and optical physics</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Ehresmann, A</au><au>Demekhin, Ph V</au><au>Kielich, W</au><au>Haar, I</au><au>Schlüter, M A</au><au>Sukhorukov, V L</au><au>Schmoranzer, H</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Predominant dissociation of the CO(D2Π)n(d/s)σ Rydberg states into atomic excited Rydberg fragments with the same effective principal quantum number</atitle><jtitle>Journal of physics. B, Atomic, molecular, and optical physics</jtitle><date>2009-08-28</date><risdate>2009</risdate><volume>42</volume><issue>16</issue><spage>165103</spage><epage>165103 (10)</epage><pages>165103-165103 (10)</pages><issn>0953-4075</issn><eissn>1361-6455</eissn><coden>JPAPEH</coden><abstract>Dissociation of the CO molecule excited in the photon energy range between 20 eV and 25 eV is investigated by photon-induced fluorescence spectroscopy (PIFS) detecting dispersed fluorescence from C I* 2s22p1n(d/s) fragments in the spectral range of 115-135 nm. First experimental indications were found for a predominant dissociation of the CO*(D2Pi)n(d/s)sigma Rydberg states into the Rydberg states of the neutral C I atom conserving the effective principal quantum number n* = n - delta of the Rydberg electron. Such a process has as yet been verified only for the dissociating molecular Rydberg series (c4Sigma-u)n(d/s)sigmag3Sigma-u in O*2 (H Liebel et al 2000 Phys. Lett. 267 267). The selective dissociation of the molecular Rydberg states into atomic ones is interpreted by theoretical potential energy curves of the CO+ ion and molecular orbitals of Rydberg electrons computed within the single-centre approach.</abstract><cop>Bristol</cop><pub>IOP Publishing</pub><doi>10.1088/0953-4075/42/16/165103</doi></addata></record>
fulltext fulltext
identifier ISSN: 0953-4075
ispartof Journal of physics. B, Atomic, molecular, and optical physics, 2009-08, Vol.42 (16), p.165103-165103 (10)
issn 0953-4075
1361-6455
language eng
recordid cdi_proquest_miscellaneous_34906268
source Institute of Physics Journals
title Predominant dissociation of the CO(D2Π)n(d/s)σ Rydberg states into atomic excited Rydberg fragments with the same effective principal quantum number
url https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-24T03%3A31%3A55IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_pasca&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Predominant%20dissociation%20of%20the%20CO(D2%CE%A0)n(d/s)%CF%83%20Rydberg%20states%20into%20atomic%20excited%20Rydberg%20fragments%20with%20the%20same%20effective%20principal%20quantum%20number&rft.jtitle=Journal%20of%20physics.%20B,%20Atomic,%20molecular,%20and%20optical%20physics&rft.au=Ehresmann,%20A&rft.date=2009-08-28&rft.volume=42&rft.issue=16&rft.spage=165103&rft.epage=165103%20(10)&rft.pages=165103-165103%20(10)&rft.issn=0953-4075&rft.eissn=1361-6455&rft.coden=JPAPEH&rft_id=info:doi/10.1088/0953-4075/42/16/165103&rft_dat=%3Cproquest_pasca%3E34906268%3C/proquest_pasca%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=34906268&rft_id=info:pmid/&rfr_iscdi=true