Development of novel processable electron accepting conjugated polymers containing fluoranthene units in the main chain
Considerable interest exists in the development of novel n-type conjugated polymers, since many currently available polymer systems have insufficient electron mobility and/or electron affinity. In this work, a universal synthesis route is presented towards a new class of n-type conjugated polymers,...
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| Veröffentlicht in: | Polymer (Guilford) 2009-10, Vol.50 (21), p.5007-5015 |
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| creator | Palmaerts, Arne Lutsen, Laurence Cleij, Thomas J. Vanderzande, Dirk Pivrikas, Almantas Neugebauer, Helmut Sariciftci, Niyazi Serdar |
| description | Considerable interest exists in the development of novel n-type conjugated polymers, since many currently available polymer systems have insufficient electron mobility and/or electron affinity. In this work, a universal synthesis route is presented towards a new class of n-type conjugated polymers, i.e. poly(p-fluoranthene vinylene) (PFV) and its derivatives. This route is illustrated with three examples, i.e. unsubstituted PFV and functionalized hexyl-PFV and dodecyl-PFV. All polymers have been synthesized via the dithiocarbamate precursor route. Solubility was introduced by incorporation of alkyl side chains, which leads to a significantly enhanced purity and processability as compared to unsubstituted PFV. Under the applied electrochemical conditions PFV-type polymers demonstrate typical n-type behavior. Additional CELIV mobility measurements on dodecyl-PFV reveal an excellent electron mobility, μe=1.4×10−4cm2/Vs. Hence, poly(p-fluoranthene vinylene) and its derivatives are promising n-type materials for organic optoelectronic applications.
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| doi_str_mv | 10.1016/j.polymer.2009.08.031 |
| format | Article |
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[Display omitted]</description><subject>Applied sciences</subject><subject>Conjugated polymers</subject><subject>Exact sciences and technology</subject><subject>Organic electronics</subject><subject>Organic polymers</subject><subject>Physicochemistry of polymers</subject><subject>Polymers with particular properties</subject><subject>PPV-type polymers</subject><subject>Preparation, kinetics, thermodynamics, mechanism and catalysts</subject><issn>0032-3861</issn><issn>1873-2291</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2009</creationdate><recordtype>article</recordtype><recordid>eNqFkE9v3CAQxVHVSN0m-QiVuLQ3OwMY_zlVVZq2kSL10pwRi4eEFQYXcKp8-7LaVa-9ADP8Zp7eI-QDg5YB628O7Rr964Kp5QBTC2MLgr0hOzYOouF8Ym_JDkDwRow9e0fe53wAAC55tyN_vuIL-rguGAqNloZYS7qmaDBnvfdI0aMpKQaqjcG1uPBETQyH7UkXnOlZOR97Rbtw_LZ-i0mH8owB6RZcydQFWku6VIKa53pekQurfcbr831JHr_d_br90Tz8_H5_--WhMWKA0oxy3qPt6nsve4HMMIlGC9CzENMwT311J0cpWWettNhxlELPUg4Mx_3QM3FJPp32Vku_N8xFLS4b9F4HjFtWohvl1MNUQXkCTYo5J7RqTW7R6VUxUMeY1UGdzapjzApGVWOucx_PAjob7W01blz-N8w5MODAK_f5xGF1--LqlmwcBoOzSzVgNUf3H6W_Gz-Y_g</recordid><startdate>20091009</startdate><enddate>20091009</enddate><creator>Palmaerts, Arne</creator><creator>Lutsen, Laurence</creator><creator>Cleij, Thomas J.</creator><creator>Vanderzande, Dirk</creator><creator>Pivrikas, Almantas</creator><creator>Neugebauer, Helmut</creator><creator>Sariciftci, Niyazi Serdar</creator><general>Elsevier Ltd</general><general>Elsevier</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>F28</scope><scope>FR3</scope><scope>JG9</scope></search><sort><creationdate>20091009</creationdate><title>Development of novel processable electron accepting conjugated polymers containing fluoranthene units in the main chain</title><author>Palmaerts, Arne ; Lutsen, Laurence ; Cleij, Thomas J. ; Vanderzande, Dirk ; Pivrikas, Almantas ; Neugebauer, Helmut ; Sariciftci, Niyazi Serdar</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c370t-85dbef4370b563e1c15eca30ad3397d96291585514ff5fe42e53ad5571e8b7613</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2009</creationdate><topic>Applied sciences</topic><topic>Conjugated polymers</topic><topic>Exact sciences and technology</topic><topic>Organic electronics</topic><topic>Organic polymers</topic><topic>Physicochemistry of polymers</topic><topic>Polymers with particular properties</topic><topic>PPV-type polymers</topic><topic>Preparation, kinetics, thermodynamics, mechanism and catalysts</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Palmaerts, Arne</creatorcontrib><creatorcontrib>Lutsen, Laurence</creatorcontrib><creatorcontrib>Cleij, Thomas J.</creatorcontrib><creatorcontrib>Vanderzande, Dirk</creatorcontrib><creatorcontrib>Pivrikas, Almantas</creatorcontrib><creatorcontrib>Neugebauer, Helmut</creatorcontrib><creatorcontrib>Sariciftci, Niyazi Serdar</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>ANTE: Abstracts in New Technology & Engineering</collection><collection>Engineering Research Database</collection><collection>Materials Research Database</collection><jtitle>Polymer (Guilford)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Palmaerts, Arne</au><au>Lutsen, Laurence</au><au>Cleij, Thomas J.</au><au>Vanderzande, Dirk</au><au>Pivrikas, Almantas</au><au>Neugebauer, Helmut</au><au>Sariciftci, Niyazi Serdar</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Development of novel processable electron accepting conjugated polymers containing fluoranthene units in the main chain</atitle><jtitle>Polymer (Guilford)</jtitle><date>2009-10-09</date><risdate>2009</risdate><volume>50</volume><issue>21</issue><spage>5007</spage><epage>5015</epage><pages>5007-5015</pages><issn>0032-3861</issn><eissn>1873-2291</eissn><coden>POLMAG</coden><abstract>Considerable interest exists in the development of novel n-type conjugated polymers, since many currently available polymer systems have insufficient electron mobility and/or electron affinity. In this work, a universal synthesis route is presented towards a new class of n-type conjugated polymers, i.e. poly(p-fluoranthene vinylene) (PFV) and its derivatives. This route is illustrated with three examples, i.e. unsubstituted PFV and functionalized hexyl-PFV and dodecyl-PFV. All polymers have been synthesized via the dithiocarbamate precursor route. Solubility was introduced by incorporation of alkyl side chains, which leads to a significantly enhanced purity and processability as compared to unsubstituted PFV. Under the applied electrochemical conditions PFV-type polymers demonstrate typical n-type behavior. Additional CELIV mobility measurements on dodecyl-PFV reveal an excellent electron mobility, μe=1.4×10−4cm2/Vs. Hence, poly(p-fluoranthene vinylene) and its derivatives are promising n-type materials for organic optoelectronic applications.
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| subjects | Applied sciences Conjugated polymers Exact sciences and technology Organic electronics Organic polymers Physicochemistry of polymers Polymers with particular properties PPV-type polymers Preparation, kinetics, thermodynamics, mechanism and catalysts |
| title | Development of novel processable electron accepting conjugated polymers containing fluoranthene units in the main chain |
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