Electrophoretic deposition of chitosan

The electrophoretic deposition (EPD) of chitosan on metallic substrates was investigated. The electrophoretic mobility of the natural biopolymer in aqueous solution as a function of pH was studied. Because the protonation/deporotonation of chitosan is pH-dependent, the electrophoretic mobility and d...

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Veröffentlicht in:Materials letters 2009-10, Vol.63 (26), p.2253-2256
Hauptverfasser: Simchi, A., Pishbin, F., Boccaccini, A.R.
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Pishbin, F.
Boccaccini, A.R.
description The electrophoretic deposition (EPD) of chitosan on metallic substrates was investigated. The electrophoretic mobility of the natural biopolymer in aqueous solution as a function of pH was studied. Because the protonation/deporotonation of chitosan is pH-dependent, the electrophoretic mobility and deposition rate is shown to increase with increasing pH from 2.9 to 4.1. The film growth rate is estimated to vary in the range 0.02–0.08 µm/s depending on the pH value. At high growth rates (> 0.05 µm/s), a porous film is obtained due to hydrogen entrapment. The EPD method developed here is applicable for the surface modification of metal implants by chitosan to develop novel bioactive coatings.
doi_str_mv 10.1016/j.matlet.2009.07.046
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subjects Biomaterials
Charge mobility
Chitosan
Deposition
Kinetics
title Electrophoretic deposition of chitosan
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