Effect of nanoparticles on the anticorrosion and mechanical properties of epoxy coating

Homogeneous epoxy coatings containing nanoparticles of SiO 2, Zn, Fe 2O 3 and halloysite clay were successfully synthesized on steel substrates by room-temperature curing of a fully mixed epoxy slurry diluted by acetone. The surface morphology and mechanical properties of these coatings were charact...

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Veröffentlicht in:Surface & coatings technology 2009-10, Vol.204 (3), p.237-245
Hauptverfasser: Shi, Xianming, Nguyen, Tuan Anh, Suo, Zhiyong, Liu, Yajun, Avci, Recep
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container_end_page 245
container_issue 3
container_start_page 237
container_title Surface & coatings technology
container_volume 204
creator Shi, Xianming
Nguyen, Tuan Anh
Suo, Zhiyong
Liu, Yajun
Avci, Recep
description Homogeneous epoxy coatings containing nanoparticles of SiO 2, Zn, Fe 2O 3 and halloysite clay were successfully synthesized on steel substrates by room-temperature curing of a fully mixed epoxy slurry diluted by acetone. The surface morphology and mechanical properties of these coatings were characterized by scanning electron microscopy and atomic force microscopy, respectively. The effect of incorporating various nanoparticles on the corrosion resistance of epoxy-coated steel was investigated by potentiodynamic polarization and electrochemical impedance spectroscopy. The electrochemical monitoring of the coated steel over 28 days of immersion in both 0.3 wt.% and 3 wt.% NaCl solutions suggested the beneficial role of nanoparticles in significantly improving the corrosion resistance of the coated steel, with the Fe 2O 3 and halloysite clay nanoparticles being the best. The SiO 2 nanoparticles were found to significantly improve the microstructure of the coating matrix and thus enhanced both the anticorrosive performance and Young's modulus of the epoxy coating. In addition to enhancing the coating barrier performance, at least another mechanism was at work to account for the role of the nanoparticles in improving the anticorrosive performance of these epoxy coatings.
doi_str_mv 10.1016/j.surfcoat.2009.06.048
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source Elsevier ScienceDirect Journals
subjects AFM
Applied sciences
Corrosion
Corrosion environments
Corrosion resistance
Cross-disciplinary physics: materials science
rheology
EIS
Epoxy coating
Exact sciences and technology
Materials science
Mechanical properties and methods of testing. Rheology. Fracture mechanics. Tribology
Metals. Metallurgy
Nanoindentation
Nanoparticle
Nonmetallic coatings
Physics
Production techniques
SEM
Surface treatment
Surface treatments
title Effect of nanoparticles on the anticorrosion and mechanical properties of epoxy coating
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