Confocal Raman spectroscopic mapping studies on a single CuO nanowire
In this study we are able, using a copper grid substrate, to successfully grow separate nanowires with a high level of crystallinity, for a length of up to 10 μm. They were synthesized under various temperatures. We compare and contrast three types of geometries (micron-, nano-scale, and tip-like si...
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Veröffentlicht in: | Applied surface science 2008-09, Vol.254 (23), p.7539-7543 |
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creator | Chou, M.H. Liu, S.B. Huang, C.Y. Wu, S.Y. Cheng, C.-L. |
description | In this study we are able, using a copper grid substrate, to successfully grow separate nanowires with a high level of crystallinity, for a length of up to 10
μm. They were synthesized under various temperatures. We compare and contrast three types of geometries (micron-, nano-scale, and tip-like single CuO nanowires), to identify their potential for monitoring the size effects of quantum confinements. The confocal Raman spectrometry results confirm the expected outcome, that reducing of the diameter of a cylindrical cross-section of a single nanowire results in Raman frequency downshifts. The results can be explained by the bond polarizability model. The applicability of investigating the size effects of the quantum confinement of the tip-like geometry of a single nanowire without any preparation for different sizes of nanoparticles is possible because the detection is relatively straightforward and the reproduced Raman signals can be observed. |
doi_str_mv | 10.1016/j.apsusc.2007.12.065 |
format | Article |
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μm. They were synthesized under various temperatures. We compare and contrast three types of geometries (micron-, nano-scale, and tip-like single CuO nanowires), to identify their potential for monitoring the size effects of quantum confinements. The confocal Raman spectrometry results confirm the expected outcome, that reducing of the diameter of a cylindrical cross-section of a single nanowire results in Raman frequency downshifts. The results can be explained by the bond polarizability model. The applicability of investigating the size effects of the quantum confinement of the tip-like geometry of a single nanowire without any preparation for different sizes of nanoparticles is possible because the detection is relatively straightforward and the reproduced Raman signals can be observed.</description><identifier>ISSN: 0169-4332</identifier><identifier>EISSN: 1873-5584</identifier><identifier>DOI: 10.1016/j.apsusc.2007.12.065</identifier><language>eng</language><publisher>Amsterdam: Elsevier B.V</publisher><subject>Biological and medical sciences ; Condensed matter: electronic structure, electrical, magnetic, and optical properties ; Confocal Raman spectroscopy ; Cross-disciplinary physics: materials science; rheology ; Cupric oxide ; Exact sciences and technology ; Fundamental and applied biological sciences. Psychology ; General aspects, investigation technics, apparatus ; Infrared and Raman spectra ; Infrared and raman spectra and scattering ; Materials science ; Nanocrystalline materials ; Nanoscale materials and structures: fabrication and characterization ; Nanowire ; Optical properties and condensed-matter spectroscopy and other interactions of matter with particles and radiation ; Physics ; Tissues, organs and organisms biophysics</subject><ispartof>Applied surface science, 2008-09, Vol.254 (23), p.7539-7543</ispartof><rights>2008 Elsevier B.V.</rights><rights>2009 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c367t-63e1abffb50d6a323e63dd7cd31619f1f75e073cfba2b8d4939406a3753482e03</citedby><cites>FETCH-LOGICAL-c367t-63e1abffb50d6a323e63dd7cd31619f1f75e073cfba2b8d4939406a3753482e03</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.apsusc.2007.12.065$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>310,311,315,781,785,790,791,3551,23935,23936,25145,27929,27930,46000</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=20797571$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Chou, M.H.</creatorcontrib><creatorcontrib>Liu, S.B.</creatorcontrib><creatorcontrib>Huang, C.Y.</creatorcontrib><creatorcontrib>Wu, S.Y.</creatorcontrib><creatorcontrib>Cheng, C.-L.</creatorcontrib><title>Confocal Raman spectroscopic mapping studies on a single CuO nanowire</title><title>Applied surface science</title><description>In this study we are able, using a copper grid substrate, to successfully grow separate nanowires with a high level of crystallinity, for a length of up to 10
μm. They were synthesized under various temperatures. We compare and contrast three types of geometries (micron-, nano-scale, and tip-like single CuO nanowires), to identify their potential for monitoring the size effects of quantum confinements. The confocal Raman spectrometry results confirm the expected outcome, that reducing of the diameter of a cylindrical cross-section of a single nanowire results in Raman frequency downshifts. The results can be explained by the bond polarizability model. The applicability of investigating the size effects of the quantum confinement of the tip-like geometry of a single nanowire without any preparation for different sizes of nanoparticles is possible because the detection is relatively straightforward and the reproduced Raman signals can be observed.</description><subject>Biological and medical sciences</subject><subject>Condensed matter: electronic structure, electrical, magnetic, and optical properties</subject><subject>Confocal Raman spectroscopy</subject><subject>Cross-disciplinary physics: materials science; rheology</subject><subject>Cupric oxide</subject><subject>Exact sciences and technology</subject><subject>Fundamental and applied biological sciences. Psychology</subject><subject>General aspects, investigation technics, apparatus</subject><subject>Infrared and Raman spectra</subject><subject>Infrared and raman spectra and scattering</subject><subject>Materials science</subject><subject>Nanocrystalline materials</subject><subject>Nanoscale materials and structures: fabrication and characterization</subject><subject>Nanowire</subject><subject>Optical properties and condensed-matter spectroscopy and other interactions of matter with particles and radiation</subject><subject>Physics</subject><subject>Tissues, organs and organisms biophysics</subject><issn>0169-4332</issn><issn>1873-5584</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2008</creationdate><recordtype>article</recordtype><recordid>eNp9kE1LxDAQhoMouK7-Aw-56K01H22zvQhS1g9YWBA9h2w6kSzdpHZaxX9vll08ehqYeWaG9yHkmrOcM17dbXPT44Q2F4ypnIucVeUJmfGFkllZLopTMktYnRVSinNygbhljIs0nZFlE4OL1nT01exMoNiDHYeINvbe0p3pex8-KI5T6wFpDNRQTJ0OaDOtaTAhfvsBLsmZMx3C1bHOyfvj8q15zlbrp5fmYZVZWakxqyRws3FuU7K2MlJIqGTbKttKXvHacadKYEpatzFis2iLWtYFS6AqZbEQwOSc3B7u9kP8nABHvfNooetMgDihloXiVSHLBBYH0KYsOIDT_eB3ZvjRnOm9M73VB2d670xzoZOztHZzvG8wOXGDCdbj365gqlal4om7P3CQwn55GDRaD8FCm2TYUbfR___oF4fAhAQ</recordid><startdate>20080930</startdate><enddate>20080930</enddate><creator>Chou, M.H.</creator><creator>Liu, S.B.</creator><creator>Huang, C.Y.</creator><creator>Wu, S.Y.</creator><creator>Cheng, C.-L.</creator><general>Elsevier B.V</general><general>Elsevier</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>H8G</scope><scope>JG9</scope></search><sort><creationdate>20080930</creationdate><title>Confocal Raman spectroscopic mapping studies on a single CuO nanowire</title><author>Chou, M.H. ; Liu, S.B. ; Huang, C.Y. ; Wu, S.Y. ; Cheng, C.-L.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c367t-63e1abffb50d6a323e63dd7cd31619f1f75e073cfba2b8d4939406a3753482e03</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2008</creationdate><topic>Biological and medical sciences</topic><topic>Condensed matter: electronic structure, electrical, magnetic, and optical properties</topic><topic>Confocal Raman spectroscopy</topic><topic>Cross-disciplinary physics: materials science; rheology</topic><topic>Cupric oxide</topic><topic>Exact sciences and technology</topic><topic>Fundamental and applied biological sciences. Psychology</topic><topic>General aspects, investigation technics, apparatus</topic><topic>Infrared and Raman spectra</topic><topic>Infrared and raman spectra and scattering</topic><topic>Materials science</topic><topic>Nanocrystalline materials</topic><topic>Nanoscale materials and structures: fabrication and characterization</topic><topic>Nanowire</topic><topic>Optical properties and condensed-matter spectroscopy and other interactions of matter with particles and radiation</topic><topic>Physics</topic><topic>Tissues, organs and organisms biophysics</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Chou, M.H.</creatorcontrib><creatorcontrib>Liu, S.B.</creatorcontrib><creatorcontrib>Huang, C.Y.</creatorcontrib><creatorcontrib>Wu, S.Y.</creatorcontrib><creatorcontrib>Cheng, C.-L.</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Copper Technical Reference Library</collection><collection>Materials Research Database</collection><jtitle>Applied surface science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Chou, M.H.</au><au>Liu, S.B.</au><au>Huang, C.Y.</au><au>Wu, S.Y.</au><au>Cheng, C.-L.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Confocal Raman spectroscopic mapping studies on a single CuO nanowire</atitle><jtitle>Applied surface science</jtitle><date>2008-09-30</date><risdate>2008</risdate><volume>254</volume><issue>23</issue><spage>7539</spage><epage>7543</epage><pages>7539-7543</pages><issn>0169-4332</issn><eissn>1873-5584</eissn><abstract>In this study we are able, using a copper grid substrate, to successfully grow separate nanowires with a high level of crystallinity, for a length of up to 10
μm. They were synthesized under various temperatures. We compare and contrast three types of geometries (micron-, nano-scale, and tip-like single CuO nanowires), to identify their potential for monitoring the size effects of quantum confinements. The confocal Raman spectrometry results confirm the expected outcome, that reducing of the diameter of a cylindrical cross-section of a single nanowire results in Raman frequency downshifts. The results can be explained by the bond polarizability model. The applicability of investigating the size effects of the quantum confinement of the tip-like geometry of a single nanowire without any preparation for different sizes of nanoparticles is possible because the detection is relatively straightforward and the reproduced Raman signals can be observed.</abstract><cop>Amsterdam</cop><pub>Elsevier B.V</pub><doi>10.1016/j.apsusc.2007.12.065</doi><tpages>5</tpages></addata></record> |
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subjects | Biological and medical sciences Condensed matter: electronic structure, electrical, magnetic, and optical properties Confocal Raman spectroscopy Cross-disciplinary physics: materials science rheology Cupric oxide Exact sciences and technology Fundamental and applied biological sciences. Psychology General aspects, investigation technics, apparatus Infrared and Raman spectra Infrared and raman spectra and scattering Materials science Nanocrystalline materials Nanoscale materials and structures: fabrication and characterization Nanowire Optical properties and condensed-matter spectroscopy and other interactions of matter with particles and radiation Physics Tissues, organs and organisms biophysics |
title | Confocal Raman spectroscopic mapping studies on a single CuO nanowire |
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