Synthesis of a graft polymer PVAc- g-[P(AN- r-BVE)- b-PCHO] in “one-step” by radical/cationic transformation polymerization and coupling reaction
This article reports a new “one-step” synthesis of graft polymers based on the radical/cationic transformation polymerization. Using the synthetic method proposed, a graft polymer (PVAc- g-[P(AN- r-BVE)- b-PCHO]) consisting of a partly hydrolyzed poly(vinyl acetate) (PVAc-OH) backbone and block poly...
Gespeichert in:
| Veröffentlicht in: | Polymer (Guilford) 2009-07, Vol.50 (15), p.3582-3586 |
|---|---|
| Hauptverfasser: | , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 3586 |
|---|---|
| container_issue | 15 |
| container_start_page | 3582 |
| container_title | Polymer (Guilford) |
| container_volume | 50 |
| creator | Lai, Renfu Guo, Haiqing Kamachi, Mikuharu |
| description | This article reports a new “one-step” synthesis of graft polymers based on the radical/cationic transformation polymerization. Using the synthetic method proposed, a graft polymer (PVAc-
g-[P(AN-
r-BVE)-
b-PCHO]) consisting of a partly hydrolyzed poly(vinyl acetate) (PVAc-OH) backbone and block polymer grafts of acrylonitrile/
n-butyl vinyl ether random copolymer (P(AN-
r-BVE)) and poly(cyclohexene oxide) (PCHO) was synthesized
in situ by radical/cationic transformation polymerization of a mixture of AN/BVE/CHO in the presence of PVAc-OH. The graft polymer, PVAc-
g-[P(AN-
r-BVE)-
b-PCHO], was fully characterized by
1H NMR, IR, gel permeation chromatography and differential scanning calorimetry. The graft polymer, PVAc-
g-[P(AN-
r-BVE)-
b-PCHO], was hydrolyzed with NaOH to form a poly(vinyl alcohol)-based amphiphilic graft polymer, PVA-
g-[P(AN-
r-BVE)-
b-PCHO]. The aggregation behavior of the amphiphilic graft polymer was investigated briefly by atomic force microscopy and dynamic light scattering measurements.
[Display omitted] |
| doi_str_mv | 10.1016/j.polymer.2009.06.002 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_34700070</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><els_id>S0032386109004765</els_id><sourcerecordid>34700070</sourcerecordid><originalsourceid>FETCH-LOGICAL-c370t-48109ff55de76e8d27d6ea1601997df1937024a8d6616a39efd41638112f5deb3</originalsourceid><addsrcrecordid>eNqFkc9uEzEQxq0KJELLIyD5AoKDt7Z34909oRD1D1JFI0F7qSrLscfB0cbe2ptK6akvwQ1erk9ShwSunCyPft83M98g9JbRglEmjpdFH7rNCmLBKW0LKgpK-QEasaYuCecte4FGlJaclI1gr9DrlJY0E2NejdDPbxs__IDkEg4WK7yIyg5474dn1xNN8ILczD5MvhIcyefrk48Ez8lsen55i53HT4-_ggeSBuifHn_j-QZHZZxW3bFWgwveaTxE5ZMNcfWn8NfbPey-yhusw7rvnF_gCEpvq0fopVVdgjf79xBdnZ58n56Ti8uzL9PJBdFlTQdSNYy21o7HBmoBjeG1EaCYoKxta2NZmyleqcYIwYQqW7CmYqJsGOM2a-blIXq_8-1juFtDGuTKJQ1dpzyEdZJlVeekaprB8Q7UMaQUwco-upWKG8mo3B5BLuV-Mbk9gqRC5oiz7t2-gUo5FJuj0C79E3NWt1UeNnOfdhzkbe9ddknagddgXAQ9SBPcfzo9A28Moh4</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>34700070</pqid></control><display><type>article</type><title>Synthesis of a graft polymer PVAc- g-[P(AN- r-BVE)- b-PCHO] in “one-step” by radical/cationic transformation polymerization and coupling reaction</title><source>Elsevier ScienceDirect Journals Complete</source><creator>Lai, Renfu ; Guo, Haiqing ; Kamachi, Mikuharu</creator><creatorcontrib>Lai, Renfu ; Guo, Haiqing ; Kamachi, Mikuharu</creatorcontrib><description>This article reports a new “one-step” synthesis of graft polymers based on the radical/cationic transformation polymerization. Using the synthetic method proposed, a graft polymer (PVAc-
g-[P(AN-
r-BVE)-
b-PCHO]) consisting of a partly hydrolyzed poly(vinyl acetate) (PVAc-OH) backbone and block polymer grafts of acrylonitrile/
n-butyl vinyl ether random copolymer (P(AN-
r-BVE)) and poly(cyclohexene oxide) (PCHO) was synthesized
in situ by radical/cationic transformation polymerization of a mixture of AN/BVE/CHO in the presence of PVAc-OH. The graft polymer, PVAc-
g-[P(AN-
r-BVE)-
b-PCHO], was fully characterized by
1H NMR, IR, gel permeation chromatography and differential scanning calorimetry. The graft polymer, PVAc-
g-[P(AN-
r-BVE)-
b-PCHO], was hydrolyzed with NaOH to form a poly(vinyl alcohol)-based amphiphilic graft polymer, PVA-
g-[P(AN-
r-BVE)-
b-PCHO]. The aggregation behavior of the amphiphilic graft polymer was investigated briefly by atomic force microscopy and dynamic light scattering measurements.
[Display omitted]</description><identifier>ISSN: 0032-3861</identifier><identifier>EISSN: 1873-2291</identifier><identifier>DOI: 10.1016/j.polymer.2009.06.002</identifier><identifier>CODEN: POLMAG</identifier><language>eng</language><publisher>Kidlington: Elsevier Ltd</publisher><subject>Applied sciences ; Exact sciences and technology ; Graft polymer ; One-step ; Organic polymers ; Physicochemistry of polymers ; Polymers with particular properties ; Preparation, kinetics, thermodynamics, mechanism and catalysts ; Transformation polymerization</subject><ispartof>Polymer (Guilford), 2009-07, Vol.50 (15), p.3582-3586</ispartof><rights>2009 Elsevier Ltd</rights><rights>2009 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c370t-48109ff55de76e8d27d6ea1601997df1937024a8d6616a39efd41638112f5deb3</citedby><cites>FETCH-LOGICAL-c370t-48109ff55de76e8d27d6ea1601997df1937024a8d6616a39efd41638112f5deb3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://www.sciencedirect.com/science/article/pii/S0032386109004765$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,776,780,3537,27901,27902,65306</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=21794199$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Lai, Renfu</creatorcontrib><creatorcontrib>Guo, Haiqing</creatorcontrib><creatorcontrib>Kamachi, Mikuharu</creatorcontrib><title>Synthesis of a graft polymer PVAc- g-[P(AN- r-BVE)- b-PCHO] in “one-step” by radical/cationic transformation polymerization and coupling reaction</title><title>Polymer (Guilford)</title><description>This article reports a new “one-step” synthesis of graft polymers based on the radical/cationic transformation polymerization. Using the synthetic method proposed, a graft polymer (PVAc-
g-[P(AN-
r-BVE)-
b-PCHO]) consisting of a partly hydrolyzed poly(vinyl acetate) (PVAc-OH) backbone and block polymer grafts of acrylonitrile/
n-butyl vinyl ether random copolymer (P(AN-
r-BVE)) and poly(cyclohexene oxide) (PCHO) was synthesized
in situ by radical/cationic transformation polymerization of a mixture of AN/BVE/CHO in the presence of PVAc-OH. The graft polymer, PVAc-
g-[P(AN-
r-BVE)-
b-PCHO], was fully characterized by
1H NMR, IR, gel permeation chromatography and differential scanning calorimetry. The graft polymer, PVAc-
g-[P(AN-
r-BVE)-
b-PCHO], was hydrolyzed with NaOH to form a poly(vinyl alcohol)-based amphiphilic graft polymer, PVA-
g-[P(AN-
r-BVE)-
b-PCHO]. The aggregation behavior of the amphiphilic graft polymer was investigated briefly by atomic force microscopy and dynamic light scattering measurements.
[Display omitted]</description><subject>Applied sciences</subject><subject>Exact sciences and technology</subject><subject>Graft polymer</subject><subject>One-step</subject><subject>Organic polymers</subject><subject>Physicochemistry of polymers</subject><subject>Polymers with particular properties</subject><subject>Preparation, kinetics, thermodynamics, mechanism and catalysts</subject><subject>Transformation polymerization</subject><issn>0032-3861</issn><issn>1873-2291</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2009</creationdate><recordtype>article</recordtype><recordid>eNqFkc9uEzEQxq0KJELLIyD5AoKDt7Z34909oRD1D1JFI0F7qSrLscfB0cbe2ptK6akvwQ1erk9ShwSunCyPft83M98g9JbRglEmjpdFH7rNCmLBKW0LKgpK-QEasaYuCecte4FGlJaclI1gr9DrlJY0E2NejdDPbxs__IDkEg4WK7yIyg5474dn1xNN8ILczD5MvhIcyefrk48Ez8lsen55i53HT4-_ggeSBuifHn_j-QZHZZxW3bFWgwveaTxE5ZMNcfWn8NfbPey-yhusw7rvnF_gCEpvq0fopVVdgjf79xBdnZ58n56Ti8uzL9PJBdFlTQdSNYy21o7HBmoBjeG1EaCYoKxta2NZmyleqcYIwYQqW7CmYqJsGOM2a-blIXq_8-1juFtDGuTKJQ1dpzyEdZJlVeekaprB8Q7UMaQUwco-upWKG8mo3B5BLuV-Mbk9gqRC5oiz7t2-gUo5FJuj0C79E3NWt1UeNnOfdhzkbe9ddknagddgXAQ9SBPcfzo9A28Moh4</recordid><startdate>20090717</startdate><enddate>20090717</enddate><creator>Lai, Renfu</creator><creator>Guo, Haiqing</creator><creator>Kamachi, Mikuharu</creator><general>Elsevier Ltd</general><general>Elsevier</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>F28</scope><scope>FR3</scope><scope>JG9</scope></search><sort><creationdate>20090717</creationdate><title>Synthesis of a graft polymer PVAc- g-[P(AN- r-BVE)- b-PCHO] in “one-step” by radical/cationic transformation polymerization and coupling reaction</title><author>Lai, Renfu ; Guo, Haiqing ; Kamachi, Mikuharu</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c370t-48109ff55de76e8d27d6ea1601997df1937024a8d6616a39efd41638112f5deb3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2009</creationdate><topic>Applied sciences</topic><topic>Exact sciences and technology</topic><topic>Graft polymer</topic><topic>One-step</topic><topic>Organic polymers</topic><topic>Physicochemistry of polymers</topic><topic>Polymers with particular properties</topic><topic>Preparation, kinetics, thermodynamics, mechanism and catalysts</topic><topic>Transformation polymerization</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Lai, Renfu</creatorcontrib><creatorcontrib>Guo, Haiqing</creatorcontrib><creatorcontrib>Kamachi, Mikuharu</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>ANTE: Abstracts in New Technology & Engineering</collection><collection>Engineering Research Database</collection><collection>Materials Research Database</collection><jtitle>Polymer (Guilford)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Lai, Renfu</au><au>Guo, Haiqing</au><au>Kamachi, Mikuharu</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis of a graft polymer PVAc- g-[P(AN- r-BVE)- b-PCHO] in “one-step” by radical/cationic transformation polymerization and coupling reaction</atitle><jtitle>Polymer (Guilford)</jtitle><date>2009-07-17</date><risdate>2009</risdate><volume>50</volume><issue>15</issue><spage>3582</spage><epage>3586</epage><pages>3582-3586</pages><issn>0032-3861</issn><eissn>1873-2291</eissn><coden>POLMAG</coden><abstract>This article reports a new “one-step” synthesis of graft polymers based on the radical/cationic transformation polymerization. Using the synthetic method proposed, a graft polymer (PVAc-
g-[P(AN-
r-BVE)-
b-PCHO]) consisting of a partly hydrolyzed poly(vinyl acetate) (PVAc-OH) backbone and block polymer grafts of acrylonitrile/
n-butyl vinyl ether random copolymer (P(AN-
r-BVE)) and poly(cyclohexene oxide) (PCHO) was synthesized
in situ by radical/cationic transformation polymerization of a mixture of AN/BVE/CHO in the presence of PVAc-OH. The graft polymer, PVAc-
g-[P(AN-
r-BVE)-
b-PCHO], was fully characterized by
1H NMR, IR, gel permeation chromatography and differential scanning calorimetry. The graft polymer, PVAc-
g-[P(AN-
r-BVE)-
b-PCHO], was hydrolyzed with NaOH to form a poly(vinyl alcohol)-based amphiphilic graft polymer, PVA-
g-[P(AN-
r-BVE)-
b-PCHO]. The aggregation behavior of the amphiphilic graft polymer was investigated briefly by atomic force microscopy and dynamic light scattering measurements.
[Display omitted]</abstract><cop>Kidlington</cop><pub>Elsevier Ltd</pub><doi>10.1016/j.polymer.2009.06.002</doi><tpages>5</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0032-3861 |
| ispartof | Polymer (Guilford), 2009-07, Vol.50 (15), p.3582-3586 |
| issn | 0032-3861 1873-2291 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_34700070 |
| source | Elsevier ScienceDirect Journals Complete |
| subjects | Applied sciences Exact sciences and technology Graft polymer One-step Organic polymers Physicochemistry of polymers Polymers with particular properties Preparation, kinetics, thermodynamics, mechanism and catalysts Transformation polymerization |
| title | Synthesis of a graft polymer PVAc- g-[P(AN- r-BVE)- b-PCHO] in “one-step” by radical/cationic transformation polymerization and coupling reaction |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-29T08%3A09%3A18IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Synthesis%20of%20a%20graft%20polymer%20PVAc-%20g-%5BP(AN-%20r-BVE)-%20b-PCHO%5D%20in%20%E2%80%9Cone-step%E2%80%9D%20by%20radical/cationic%20transformation%20polymerization%20and%20coupling%20reaction&rft.jtitle=Polymer%20(Guilford)&rft.au=Lai,%20Renfu&rft.date=2009-07-17&rft.volume=50&rft.issue=15&rft.spage=3582&rft.epage=3586&rft.pages=3582-3586&rft.issn=0032-3861&rft.eissn=1873-2291&rft.coden=POLMAG&rft_id=info:doi/10.1016/j.polymer.2009.06.002&rft_dat=%3Cproquest_cross%3E34700070%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=34700070&rft_id=info:pmid/&rft_els_id=S0032386109004765&rfr_iscdi=true |