Surface enhanced Raman scattering study of l-lysine

Different SERS spectra of lysine (Lys) in Ag colloidal surface were obtained. No identical SERS spectra of Lys were observed after a stabilization period, suggesting that a unique conformation and orientation on the metal surface of lysine do not exist at neutral pH. In general, Lys molecules intera...

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Veröffentlicht in:Vibrational spectroscopy 2009-05, Vol.50 (1), p.131-135
Hauptverfasser: Aliaga, A.E., Osorio-Roman, I., Garrido, C., Leyton, P., Cárcamo, J., Clavijo, E., Gómez-Jeria, J.S., F., G. Díaz, Campos-Vallette, M.M.
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container_end_page 135
container_issue 1
container_start_page 131
container_title Vibrational spectroscopy
container_volume 50
creator Aliaga, A.E.
Osorio-Roman, I.
Garrido, C.
Leyton, P.
Cárcamo, J.
Clavijo, E.
Gómez-Jeria, J.S.
F., G. Díaz
Campos-Vallette, M.M.
description Different SERS spectra of lysine (Lys) in Ag colloidal surface were obtained. No identical SERS spectra of Lys were observed after a stabilization period, suggesting that a unique conformation and orientation on the metal surface of lysine do not exist at neutral pH. In general, Lys molecules interact with the surface through both the carboxylate and amino groups; the aliphatic moiety is close to the surface. The interpretation of the experimental results is supported by theoretical analysis of the molecule on the silver surface.
doi_str_mv 10.1016/j.vibspec.2008.09.018
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subjects Lysine
Metal surface
Raman spectroscopy
SERS
title Surface enhanced Raman scattering study of l-lysine
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