Surface enhanced Raman scattering study of l-lysine
Different SERS spectra of lysine (Lys) in Ag colloidal surface were obtained. No identical SERS spectra of Lys were observed after a stabilization period, suggesting that a unique conformation and orientation on the metal surface of lysine do not exist at neutral pH. In general, Lys molecules intera...
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Veröffentlicht in: | Vibrational spectroscopy 2009-05, Vol.50 (1), p.131-135 |
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creator | Aliaga, A.E. Osorio-Roman, I. Garrido, C. Leyton, P. Cárcamo, J. Clavijo, E. Gómez-Jeria, J.S. F., G. Díaz Campos-Vallette, M.M. |
description | Different SERS spectra of lysine (Lys) in Ag colloidal surface were obtained. No identical SERS spectra of Lys were observed after a stabilization period, suggesting that a unique conformation and orientation on the metal surface of lysine do not exist at neutral pH. In general, Lys molecules interact with the surface through both the carboxylate and amino groups; the aliphatic moiety is close to the surface. The interpretation of the experimental results is supported by theoretical analysis of the molecule on the silver surface. |
doi_str_mv | 10.1016/j.vibspec.2008.09.018 |
format | Article |
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Díaz</creatorcontrib><creatorcontrib>Campos-Vallette, M.M.</creatorcontrib><title>Surface enhanced Raman scattering study of l-lysine</title><title>Vibrational spectroscopy</title><description>Different SERS spectra of lysine (Lys) in Ag colloidal surface were obtained. No identical SERS spectra of Lys were observed after a stabilization period, suggesting that a unique conformation and orientation on the metal surface of lysine do not exist at neutral pH. In general, Lys molecules interact with the surface through both the carboxylate and amino groups; the aliphatic moiety is close to the surface. The interpretation of the experimental results is supported by theoretical analysis of the molecule on the silver surface.</description><subject>Lysine</subject><subject>Metal surface</subject><subject>Raman spectroscopy</subject><subject>SERS</subject><issn>0924-2031</issn><issn>1873-3697</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2009</creationdate><recordtype>article</recordtype><recordid>eNqFkEtLxDAUhYMoOI7-BKErd603TdJOVyKDLxgQfKxDkt5ohk475rbC_HszzOxdnc13DpyPsWsOBQde3a6L32Bpi64oARYFNAXwxQmb8UUtclE19SmbQVPKvATBz9kF0RoAKsXFjIn3KXrjMMP-2_QO2-zNbEyfkTPjiDH0XxmNU7vLBp91ebej0OMlO_OmI7w65px9Pj58LJ_z1evTy_J-lTshYcwtCCNqW9qGeyVUbWQrQSrObW1TIghblkKi8cI66cG16J20qVx5p5QSc3Zz2N3G4WdCGvUmkMOuMz0OE-kENqDqKoHqALo4EEX0ehvDxsSd5qD3ivRaHxXpvSINjU6KUu_u0MP04jdg1OQC7i2EiG7U7RD-WfgD0mdx4w</recordid><startdate>20090526</startdate><enddate>20090526</enddate><creator>Aliaga, A.E.</creator><creator>Osorio-Roman, I.</creator><creator>Garrido, C.</creator><creator>Leyton, P.</creator><creator>Cárcamo, J.</creator><creator>Clavijo, E.</creator><creator>Gómez-Jeria, J.S.</creator><creator>F., G. 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Díaz</creatorcontrib><creatorcontrib>Campos-Vallette, M.M.</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Vibrational spectroscopy</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Aliaga, A.E.</au><au>Osorio-Roman, I.</au><au>Garrido, C.</au><au>Leyton, P.</au><au>Cárcamo, J.</au><au>Clavijo, E.</au><au>Gómez-Jeria, J.S.</au><au>F., G. Díaz</au><au>Campos-Vallette, M.M.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Surface enhanced Raman scattering study of l-lysine</atitle><jtitle>Vibrational spectroscopy</jtitle><date>2009-05-26</date><risdate>2009</risdate><volume>50</volume><issue>1</issue><spage>131</spage><epage>135</epage><pages>131-135</pages><issn>0924-2031</issn><eissn>1873-3697</eissn><abstract>Different SERS spectra of lysine (Lys) in Ag colloidal surface were obtained. No identical SERS spectra of Lys were observed after a stabilization period, suggesting that a unique conformation and orientation on the metal surface of lysine do not exist at neutral pH. In general, Lys molecules interact with the surface through both the carboxylate and amino groups; the aliphatic moiety is close to the surface. 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subjects | Lysine Metal surface Raman spectroscopy SERS |
title | Surface enhanced Raman scattering study of l-lysine |
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