Characterization of composite carbon supported PtRu catalyst and its catalytic performance for methanol oxidation

A composite carbon prepared by blending Vulcan XC-72 carbon with multi-walled carbon nanotubes (MWCNTs) had been used as a support of PtRu alloy catalyst (PtRu/C + MWCNTs) for methanol oxidation reaction. The obtained electrocatalysts were characterized by transmission electron microscopy (TEM), X-r...

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Veröffentlicht in:Journal of alloys and compounds 2008-10, Vol.465 (1), p.296-304
Hauptverfasser: Liang, Ying, Li, Jun, Xu, Qing-Chi, Hu, Rong-Zong, Lin, Jing-Dong, Liao, Dai-Wei
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container_end_page 304
container_issue 1
container_start_page 296
container_title Journal of alloys and compounds
container_volume 465
creator Liang, Ying
Li, Jun
Xu, Qing-Chi
Hu, Rong-Zong
Lin, Jing-Dong
Liao, Dai-Wei
description A composite carbon prepared by blending Vulcan XC-72 carbon with multi-walled carbon nanotubes (MWCNTs) had been used as a support of PtRu alloy catalyst (PtRu/C + MWCNTs) for methanol oxidation reaction. The obtained electrocatalysts were characterized by transmission electron microscopy (TEM), X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS). The influence of the composite carbon support on the alloy content and PtRu surface state was discussed. The electrocatalytic property of the PtRu/C + MWCNTs catalyst was investigated by cyclic voltammetry (CV), chromoamperometry, CO stripping voltammetry and DMFC single cell test. The results demonstrated that, compared to the PtRu/C and PtRu/MWCNTs catalysts, the PtRu/C + MWCNTs catalyst exhibited superior electrocatalytic activity for methanol oxidation.
doi_str_mv 10.1016/j.jallcom.2007.10.075
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source ScienceDirect Journals (5 years ago - present)
subjects Catalysis
Catalyst support
Chemistry
Electrochemical properties
Electrochemistry
Exact sciences and technology
General and physical chemistry
Kinetics and mechanism of reactions
Methanol electrooxidation
PtRu alloy
Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry
title Characterization of composite carbon supported PtRu catalyst and its catalytic performance for methanol oxidation
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