Performance of Pd-promoted Mo–V–Te–Nb–O catalysts in the partial oxidation of propane to acrylic acid
The activity of Pd-promoted Mo 1.0V 0.3Te 0.23Nb 0.23O x catalysts for the partial oxidation of propane was increased due to an increase in the number of sites for the adsorption of propane and for the oxidative dehydrogenation of propane to propylene. The selectivity for acrylic acid production was...
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| Veröffentlicht in: | Applied catalysis. A, General General, 2009-08, Vol.365 (1), p.79-87 |
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| container_title | Applied catalysis. A, General |
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| creator | Kum, Sang Seop Jo, Bu Young Moon, Sang Heup |
| description | The activity of Pd-promoted Mo
1.0V
0.3Te
0.23Nb
0.23O
x
catalysts for the partial oxidation of propane was increased due to an increase in the number of sites for the adsorption of propane and for the oxidative dehydrogenation of propane to propylene. The selectivity for acrylic acid production was increased due to the enhancement of the oxidative dehydrogenation step (RDS) and the suppression of the side-reaction steps.
The performance of a Mo
1.0V
0.3Te
0.23Nb
0.23O
x
catalyst in the partial oxidation of propane to obtain acrylic acid (AA) was improved when the catalyst was modified with an optimal amount of Pd oxide. The activity was increased due to an increase in the number of sites for the adsorption of propane and for the conversion of the adsorbed propane to propylene via oxidative dehydrogenation, which is the rate-determining step (RDS) in the process. An increase in the number of acidic sites was also responsible for the activity improvement. The selectivity for AA production was increased due to the enhancement of the RDS, accompanied by the suppression of the side-reaction steps. Added Pd oxide reduced the amount of propane, which was strongly adsorbed on the catalyst, such that propane was rapidly desorbed from the surface without being over-oxidized to CO
x
. The suppression of AA oxidation also contributed to the improved selectivity. Both activity and selectivity of the catalyst were eventually lowered when the Pd content was greater than 10
−2
wt% because the catalyst surface was covered with an excess amount of Pd oxide. |
| doi_str_mv | 10.1016/j.apcata.2009.05.056 |
| format | Article |
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1.0V
0.3Te
0.23Nb
0.23O
x
catalysts for the partial oxidation of propane was increased due to an increase in the number of sites for the adsorption of propane and for the oxidative dehydrogenation of propane to propylene. The selectivity for acrylic acid production was increased due to the enhancement of the oxidative dehydrogenation step (RDS) and the suppression of the side-reaction steps.
The performance of a Mo
1.0V
0.3Te
0.23Nb
0.23O
x
catalyst in the partial oxidation of propane to obtain acrylic acid (AA) was improved when the catalyst was modified with an optimal amount of Pd oxide. The activity was increased due to an increase in the number of sites for the adsorption of propane and for the conversion of the adsorbed propane to propylene via oxidative dehydrogenation, which is the rate-determining step (RDS) in the process. An increase in the number of acidic sites was also responsible for the activity improvement. The selectivity for AA production was increased due to the enhancement of the RDS, accompanied by the suppression of the side-reaction steps. Added Pd oxide reduced the amount of propane, which was strongly adsorbed on the catalyst, such that propane was rapidly desorbed from the surface without being over-oxidized to CO
x
. The suppression of AA oxidation also contributed to the improved selectivity. Both activity and selectivity of the catalyst were eventually lowered when the Pd content was greater than 10
−2
wt% because the catalyst surface was covered with an excess amount of Pd oxide.</description><identifier>ISSN: 0926-860X</identifier><identifier>EISSN: 1873-3875</identifier><identifier>DOI: 10.1016/j.apcata.2009.05.056</identifier><language>eng</language><publisher>Kidlington: Elsevier B.V</publisher><subject>Acrylic acid ; Catalysis ; Chemistry ; Exact sciences and technology ; General and physical chemistry ; Oxidation ; Oxidative dehydrogenation ; Pd oxide ; Propane ; Surface physical chemistry ; Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry</subject><ispartof>Applied catalysis. A, General, 2009-08, Vol.365 (1), p.79-87</ispartof><rights>2009 Elsevier B.V.</rights><rights>2009 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c404t-2cd05c00eb6070e20c2834e9df239cc624b6036771064f5c644d178282f874ee3</citedby><cites>FETCH-LOGICAL-c404t-2cd05c00eb6070e20c2834e9df239cc624b6036771064f5c644d178282f874ee3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://www.sciencedirect.com/science/article/pii/S0926860X09004128$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,776,780,3537,27901,27902,65306</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=21782101$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Kum, Sang Seop</creatorcontrib><creatorcontrib>Jo, Bu Young</creatorcontrib><creatorcontrib>Moon, Sang Heup</creatorcontrib><title>Performance of Pd-promoted Mo–V–Te–Nb–O catalysts in the partial oxidation of propane to acrylic acid</title><title>Applied catalysis. A, General</title><description>The activity of Pd-promoted Mo
1.0V
0.3Te
0.23Nb
0.23O
x
catalysts for the partial oxidation of propane was increased due to an increase in the number of sites for the adsorption of propane and for the oxidative dehydrogenation of propane to propylene. The selectivity for acrylic acid production was increased due to the enhancement of the oxidative dehydrogenation step (RDS) and the suppression of the side-reaction steps.
The performance of a Mo
1.0V
0.3Te
0.23Nb
0.23O
x
catalyst in the partial oxidation of propane to obtain acrylic acid (AA) was improved when the catalyst was modified with an optimal amount of Pd oxide. The activity was increased due to an increase in the number of sites for the adsorption of propane and for the conversion of the adsorbed propane to propylene via oxidative dehydrogenation, which is the rate-determining step (RDS) in the process. An increase in the number of acidic sites was also responsible for the activity improvement. The selectivity for AA production was increased due to the enhancement of the RDS, accompanied by the suppression of the side-reaction steps. Added Pd oxide reduced the amount of propane, which was strongly adsorbed on the catalyst, such that propane was rapidly desorbed from the surface without being over-oxidized to CO
x
. The suppression of AA oxidation also contributed to the improved selectivity. Both activity and selectivity of the catalyst were eventually lowered when the Pd content was greater than 10
−2
wt% because the catalyst surface was covered with an excess amount of Pd oxide.</description><subject>Acrylic acid</subject><subject>Catalysis</subject><subject>Chemistry</subject><subject>Exact sciences and technology</subject><subject>General and physical chemistry</subject><subject>Oxidation</subject><subject>Oxidative dehydrogenation</subject><subject>Pd oxide</subject><subject>Propane</subject><subject>Surface physical chemistry</subject><subject>Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry</subject><issn>0926-860X</issn><issn>1873-3875</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2009</creationdate><recordtype>article</recordtype><recordid>eNp9UE1P3DAQtaoidQv9Bz340t6yTBzHSS6VKlQ-JGA5AOrNMvZE9SpZp7ZB7I3_wD_sL2GiXfWINJ45-L03bx5jX0tYllCq4_XSTNZksxQA3RJqKvWBLcq2qYqqbeqPbAGdUEWr4Pcn9jmlNQAI2dULNt5g7EMczcYiDz2_ccUUwxgyOn4V_r283tO7RWrXD9RWfN4zbFNO3G94_oN8MjF7M_Dw7J3JPmxmGdKYzAZ5DtzYuB28pendETvozZDwy34esrvTX7cn58Xl6uzi5OdlYSXIXAjroLYA-KCgARRgRVtJ7Fwvqs5aJSR9VKppSlCyr62S0pVNK1rRt41ErA7Z950u-fj7iCnr0SeLw0CewmPSlVRKlbIioNwBbQwpRez1FP1o4laXoOds9VrvstVzthpqKkW0b3t9k6wZ-kjx-fSfK2YzxCbcjx0O6dgnj1En65Gidj6izdoF__6iN0NDlMU</recordid><startdate>20090815</startdate><enddate>20090815</enddate><creator>Kum, Sang Seop</creator><creator>Jo, Bu Young</creator><creator>Moon, Sang Heup</creator><general>Elsevier B.V</general><general>Elsevier</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope></search><sort><creationdate>20090815</creationdate><title>Performance of Pd-promoted Mo–V–Te–Nb–O catalysts in the partial oxidation of propane to acrylic acid</title><author>Kum, Sang Seop ; Jo, Bu Young ; Moon, Sang Heup</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c404t-2cd05c00eb6070e20c2834e9df239cc624b6036771064f5c644d178282f874ee3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2009</creationdate><topic>Acrylic acid</topic><topic>Catalysis</topic><topic>Chemistry</topic><topic>Exact sciences and technology</topic><topic>General and physical chemistry</topic><topic>Oxidation</topic><topic>Oxidative dehydrogenation</topic><topic>Pd oxide</topic><topic>Propane</topic><topic>Surface physical chemistry</topic><topic>Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Kum, Sang Seop</creatorcontrib><creatorcontrib>Jo, Bu Young</creatorcontrib><creatorcontrib>Moon, Sang Heup</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Applied catalysis. A, General</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Kum, Sang Seop</au><au>Jo, Bu Young</au><au>Moon, Sang Heup</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Performance of Pd-promoted Mo–V–Te–Nb–O catalysts in the partial oxidation of propane to acrylic acid</atitle><jtitle>Applied catalysis. A, General</jtitle><date>2009-08-15</date><risdate>2009</risdate><volume>365</volume><issue>1</issue><spage>79</spage><epage>87</epage><pages>79-87</pages><issn>0926-860X</issn><eissn>1873-3875</eissn><abstract>The activity of Pd-promoted Mo
1.0V
0.3Te
0.23Nb
0.23O
x
catalysts for the partial oxidation of propane was increased due to an increase in the number of sites for the adsorption of propane and for the oxidative dehydrogenation of propane to propylene. The selectivity for acrylic acid production was increased due to the enhancement of the oxidative dehydrogenation step (RDS) and the suppression of the side-reaction steps.
The performance of a Mo
1.0V
0.3Te
0.23Nb
0.23O
x
catalyst in the partial oxidation of propane to obtain acrylic acid (AA) was improved when the catalyst was modified with an optimal amount of Pd oxide. The activity was increased due to an increase in the number of sites for the adsorption of propane and for the conversion of the adsorbed propane to propylene via oxidative dehydrogenation, which is the rate-determining step (RDS) in the process. An increase in the number of acidic sites was also responsible for the activity improvement. The selectivity for AA production was increased due to the enhancement of the RDS, accompanied by the suppression of the side-reaction steps. Added Pd oxide reduced the amount of propane, which was strongly adsorbed on the catalyst, such that propane was rapidly desorbed from the surface without being over-oxidized to CO
x
. The suppression of AA oxidation also contributed to the improved selectivity. Both activity and selectivity of the catalyst were eventually lowered when the Pd content was greater than 10
−2
wt% because the catalyst surface was covered with an excess amount of Pd oxide.</abstract><cop>Kidlington</cop><pub>Elsevier B.V</pub><doi>10.1016/j.apcata.2009.05.056</doi><tpages>9</tpages></addata></record> |
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| ispartof | Applied catalysis. A, General, 2009-08, Vol.365 (1), p.79-87 |
| issn | 0926-860X 1873-3875 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_34666143 |
| source | Elsevier ScienceDirect Journals Complete |
| subjects | Acrylic acid Catalysis Chemistry Exact sciences and technology General and physical chemistry Oxidation Oxidative dehydrogenation Pd oxide Propane Surface physical chemistry Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry |
| title | Performance of Pd-promoted Mo–V–Te–Nb–O catalysts in the partial oxidation of propane to acrylic acid |
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