Synthesis and characterization of fluorene-based low-band gap copolymers containing propylenedioxythiophene and benzothiadiazole derivatives for bulk heterojunction photovoltaic cell applications
The following noble series of soluble π-conjugated statistical copolymers was synthesized by palladium catalyzed Suzuki polymerization: poly[(9,9-dioctylfluorene)-alt-(4,7-bis(3',3'-dihepyl-3,4-propylenedioxythienyl)-2,1,3-benzothiadiazole)] (PFO-PTBT) derived from poly(9,9-dioctylfluorene...
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| Veröffentlicht in: | Journal of polymer science. Part A, Polymer chemistry Polymer chemistry, 2008-09, Vol.46 (18), p.6175-6184 |
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| container_title | Journal of polymer science. Part A, Polymer chemistry |
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| creator | Park, Jin Su Ryu, Tae In Song, Myungkwan Yoon, Kyung-Jin Lee, Myung Jin Shin, In Ae Lee, Gi-Dong Lee, Jae Wook Gal, Yeong-Soon Jin, Sung-Ho |
| description | The following noble series of soluble π-conjugated statistical copolymers was synthesized by palladium catalyzed Suzuki polymerization: poly[(9,9-dioctylfluorene)-alt-(4,7-bis(3',3'-dihepyl-3,4-propylenedioxythienyl)-2,1,3-benzothiadiazole)] (PFO-PTBT) derived from poly(9,9-dioctylfluorene) (PFO) and poly[(4,7-bis(3',3'-dihepyl-3,4-propylenedioxythienyl)-2,1,3-benzothiadiazole)] poly(heptyl₄-PTBT). The structure and properties of these polymers were characterized using ¹H-, ¹³C-NMR, UV-visible spectroscopy, elemental analysis, GPC, DSC, TGA, photoluminescence (PL), and cyclic voltammetry (CV). The statistical copolymers, PFO-PTBT (9:1, 8.4:1.6, 6.5:3.5), were soluble in common organic solvents and easily spin coated onto indium-tin oxide (ITO) coated glass substrates. The weight-average molecular weight (Mw) and polydispersity of the PFO-PTBT ranged from (1.0-4.2) x 10⁴ and 1.5-2.3, respectively. Bulk heterojunction photovoltaic cells with an ITO/PEDOT/PFO-PTBT:PCBM/LiF/Al configuration were fabricated, and the devices using PFOPTBT (6.5:3.5) showed the best performance compared with those using PFO-PTBT (9:1, 8.4:1.6). A maximum power conversion efficiency (PCE) of 0.50% (Voc = 0.66 V, FF = 0.29) was achieved with PFO-PTBT (6.5:3.5). |
| doi_str_mv | 10.1002/pola.22928 |
| format | Article |
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The structure and properties of these polymers were characterized using ¹H-, ¹³C-NMR, UV-visible spectroscopy, elemental analysis, GPC, DSC, TGA, photoluminescence (PL), and cyclic voltammetry (CV). The statistical copolymers, PFO-PTBT (9:1, 8.4:1.6, 6.5:3.5), were soluble in common organic solvents and easily spin coated onto indium-tin oxide (ITO) coated glass substrates. The weight-average molecular weight (Mw) and polydispersity of the PFO-PTBT ranged from (1.0-4.2) x 10⁴ and 1.5-2.3, respectively. Bulk heterojunction photovoltaic cells with an ITO/PEDOT/PFO-PTBT:PCBM/LiF/Al configuration were fabricated, and the devices using PFOPTBT (6.5:3.5) showed the best performance compared with those using PFO-PTBT (9:1, 8.4:1.6). A maximum power conversion efficiency (PCE) of 0.50% (Voc = 0.66 V, FF = 0.29) was achieved with PFO-PTBT (6.5:3.5).</description><identifier>ISSN: 0887-624X</identifier><identifier>EISSN: 1099-0518</identifier><identifier>DOI: 10.1002/pola.22928</identifier><identifier>CODEN: JPLCAT</identifier><language>eng</language><publisher>Hoboken: Wiley Subscription Services, Inc., A Wiley Company</publisher><subject>Applied sciences ; conjugated polymers ; copolymerization ; Energy ; Exact sciences and technology ; fullerenes ; Natural energy ; Organic polymers ; Photovoltaic conversion ; Physicochemistry of polymers ; Polymers with particular properties ; Preparation, kinetics, thermodynamics, mechanism and catalysts ; Solar cells. Photoelectrochemical cells ; Solar energy</subject><ispartof>Journal of polymer science. Part A, Polymer chemistry, 2008-09, Vol.46 (18), p.6175-6184</ispartof><rights>Copyright © 2008 Wiley Periodicals, Inc.</rights><rights>2008 INIST-CNRS</rights><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c3968-3e28cdde0eba40e70a949f9d053d3879d93115ac4458e6d2f9c699cbe2e2deab3</citedby><cites>FETCH-LOGICAL-c3968-3e28cdde0eba40e70a949f9d053d3879d93115ac4458e6d2f9c699cbe2e2deab3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fpola.22928$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fpola.22928$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,776,780,1411,27903,27904,45553,45554</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=20603069$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Park, Jin Su</creatorcontrib><creatorcontrib>Ryu, Tae In</creatorcontrib><creatorcontrib>Song, Myungkwan</creatorcontrib><creatorcontrib>Yoon, Kyung-Jin</creatorcontrib><creatorcontrib>Lee, Myung Jin</creatorcontrib><creatorcontrib>Shin, In Ae</creatorcontrib><creatorcontrib>Lee, Gi-Dong</creatorcontrib><creatorcontrib>Lee, Jae Wook</creatorcontrib><creatorcontrib>Gal, Yeong-Soon</creatorcontrib><creatorcontrib>Jin, Sung-Ho</creatorcontrib><title>Synthesis and characterization of fluorene-based low-band gap copolymers containing propylenedioxythiophene and benzothiadiazole derivatives for bulk heterojunction photovoltaic cell applications</title><title>Journal of polymer science. Part A, Polymer chemistry</title><addtitle>J. Polym. Sci. A Polym. Chem</addtitle><description>The following noble series of soluble π-conjugated statistical copolymers was synthesized by palladium catalyzed Suzuki polymerization: poly[(9,9-dioctylfluorene)-alt-(4,7-bis(3',3'-dihepyl-3,4-propylenedioxythienyl)-2,1,3-benzothiadiazole)] (PFO-PTBT) derived from poly(9,9-dioctylfluorene) (PFO) and poly[(4,7-bis(3',3'-dihepyl-3,4-propylenedioxythienyl)-2,1,3-benzothiadiazole)] poly(heptyl₄-PTBT). The structure and properties of these polymers were characterized using ¹H-, ¹³C-NMR, UV-visible spectroscopy, elemental analysis, GPC, DSC, TGA, photoluminescence (PL), and cyclic voltammetry (CV). The statistical copolymers, PFO-PTBT (9:1, 8.4:1.6, 6.5:3.5), were soluble in common organic solvents and easily spin coated onto indium-tin oxide (ITO) coated glass substrates. The weight-average molecular weight (Mw) and polydispersity of the PFO-PTBT ranged from (1.0-4.2) x 10⁴ and 1.5-2.3, respectively. Bulk heterojunction photovoltaic cells with an ITO/PEDOT/PFO-PTBT:PCBM/LiF/Al configuration were fabricated, and the devices using PFOPTBT (6.5:3.5) showed the best performance compared with those using PFO-PTBT (9:1, 8.4:1.6). A maximum power conversion efficiency (PCE) of 0.50% (Voc = 0.66 V, FF = 0.29) was achieved with PFO-PTBT (6.5:3.5).</description><subject>Applied sciences</subject><subject>conjugated polymers</subject><subject>copolymerization</subject><subject>Energy</subject><subject>Exact sciences and technology</subject><subject>fullerenes</subject><subject>Natural energy</subject><subject>Organic polymers</subject><subject>Photovoltaic conversion</subject><subject>Physicochemistry of polymers</subject><subject>Polymers with particular properties</subject><subject>Preparation, kinetics, thermodynamics, mechanism and catalysts</subject><subject>Solar cells. Photoelectrochemical cells</subject><subject>Solar energy</subject><issn>0887-624X</issn><issn>1099-0518</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2008</creationdate><recordtype>article</recordtype><recordid>eNp9ks1u1DAUhSMEEkNhwwvgDSyQUhznz15WFVMQI4pUCuysG_tm4tYTBzszbeb1eDE8k9IlK1_b3z3nWNdJ8jqjpxml7MPgLJwyJhh_kiwyKkRKy4w_TRaU8zqtWPHrefIihBtK413JF8mfq6kfOwwmEOg1UR14UCN6s4fRuJ64lrR26zz2mDYQUBPr7mIV2TUMRLnoOG3Qh1j2I5je9GsyeDdMNrZo4-6nsTNu6OLu6NBgv3fxCLSBvbNIdDTbRbMdBtI6T5qtvSUdxgzuZturY4qhc6PbORsNFFFoLYFhsEYdM4aXybMWbMBXD-tJcr38-P38U7q6vPh8frZKVS4qnubIuNIaKTZQUKwpiEK0QtMy1zmvhRZ5lpWgiqLkWGnWClUJoRpkyDRCk58k72bd-L7fWwyj3JhwSAM9um2QeVHWmSiLCL6fQeVdCB5bOXizAT_JjMrDnORhTvI4pwi_fVCFoMC2HnplwmMHoxXNaSUil83cnbE4_UdRfrtcnf3TTuceE0a8f-wBfyurOq9L-fPrhVz-oF_okleyjPybmW_BSVj7mOP6itEsj9-FcV6U-V95CcPA</recordid><startdate>20080915</startdate><enddate>20080915</enddate><creator>Park, Jin Su</creator><creator>Ryu, Tae In</creator><creator>Song, Myungkwan</creator><creator>Yoon, Kyung-Jin</creator><creator>Lee, Myung Jin</creator><creator>Shin, In Ae</creator><creator>Lee, Gi-Dong</creator><creator>Lee, Jae Wook</creator><creator>Gal, Yeong-Soon</creator><creator>Jin, Sung-Ho</creator><general>Wiley Subscription Services, Inc., A Wiley Company</general><general>Wiley</general><scope>FBQ</scope><scope>BSCLL</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7QF</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20080915</creationdate><title>Synthesis and characterization of fluorene-based low-band gap copolymers containing propylenedioxythiophene and benzothiadiazole derivatives for bulk heterojunction photovoltaic cell applications</title><author>Park, Jin Su ; Ryu, Tae In ; Song, Myungkwan ; Yoon, Kyung-Jin ; Lee, Myung Jin ; Shin, In Ae ; Lee, Gi-Dong ; Lee, Jae Wook ; Gal, Yeong-Soon ; Jin, Sung-Ho</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3968-3e28cdde0eba40e70a949f9d053d3879d93115ac4458e6d2f9c699cbe2e2deab3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2008</creationdate><topic>Applied sciences</topic><topic>conjugated polymers</topic><topic>copolymerization</topic><topic>Energy</topic><topic>Exact sciences and technology</topic><topic>fullerenes</topic><topic>Natural energy</topic><topic>Organic polymers</topic><topic>Photovoltaic conversion</topic><topic>Physicochemistry of polymers</topic><topic>Polymers with particular properties</topic><topic>Preparation, kinetics, thermodynamics, mechanism and catalysts</topic><topic>Solar cells. Photoelectrochemical cells</topic><topic>Solar energy</topic><toplevel>online_resources</toplevel><creatorcontrib>Park, Jin Su</creatorcontrib><creatorcontrib>Ryu, Tae In</creatorcontrib><creatorcontrib>Song, Myungkwan</creatorcontrib><creatorcontrib>Yoon, Kyung-Jin</creatorcontrib><creatorcontrib>Lee, Myung Jin</creatorcontrib><creatorcontrib>Shin, In Ae</creatorcontrib><creatorcontrib>Lee, Gi-Dong</creatorcontrib><creatorcontrib>Lee, Jae Wook</creatorcontrib><creatorcontrib>Gal, Yeong-Soon</creatorcontrib><creatorcontrib>Jin, Sung-Ho</creatorcontrib><collection>AGRIS</collection><collection>Istex</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Aluminium Industry Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Journal of polymer science. Part A, Polymer chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Park, Jin Su</au><au>Ryu, Tae In</au><au>Song, Myungkwan</au><au>Yoon, Kyung-Jin</au><au>Lee, Myung Jin</au><au>Shin, In Ae</au><au>Lee, Gi-Dong</au><au>Lee, Jae Wook</au><au>Gal, Yeong-Soon</au><au>Jin, Sung-Ho</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis and characterization of fluorene-based low-band gap copolymers containing propylenedioxythiophene and benzothiadiazole derivatives for bulk heterojunction photovoltaic cell applications</atitle><jtitle>Journal of polymer science. Part A, Polymer chemistry</jtitle><addtitle>J. Polym. Sci. A Polym. Chem</addtitle><date>2008-09-15</date><risdate>2008</risdate><volume>46</volume><issue>18</issue><spage>6175</spage><epage>6184</epage><pages>6175-6184</pages><issn>0887-624X</issn><eissn>1099-0518</eissn><coden>JPLCAT</coden><abstract>The following noble series of soluble π-conjugated statistical copolymers was synthesized by palladium catalyzed Suzuki polymerization: poly[(9,9-dioctylfluorene)-alt-(4,7-bis(3',3'-dihepyl-3,4-propylenedioxythienyl)-2,1,3-benzothiadiazole)] (PFO-PTBT) derived from poly(9,9-dioctylfluorene) (PFO) and poly[(4,7-bis(3',3'-dihepyl-3,4-propylenedioxythienyl)-2,1,3-benzothiadiazole)] poly(heptyl₄-PTBT). The structure and properties of these polymers were characterized using ¹H-, ¹³C-NMR, UV-visible spectroscopy, elemental analysis, GPC, DSC, TGA, photoluminescence (PL), and cyclic voltammetry (CV). The statistical copolymers, PFO-PTBT (9:1, 8.4:1.6, 6.5:3.5), were soluble in common organic solvents and easily spin coated onto indium-tin oxide (ITO) coated glass substrates. The weight-average molecular weight (Mw) and polydispersity of the PFO-PTBT ranged from (1.0-4.2) x 10⁴ and 1.5-2.3, respectively. Bulk heterojunction photovoltaic cells with an ITO/PEDOT/PFO-PTBT:PCBM/LiF/Al configuration were fabricated, and the devices using PFOPTBT (6.5:3.5) showed the best performance compared with those using PFO-PTBT (9:1, 8.4:1.6). A maximum power conversion efficiency (PCE) of 0.50% (Voc = 0.66 V, FF = 0.29) was achieved with PFO-PTBT (6.5:3.5).</abstract><cop>Hoboken</cop><pub>Wiley Subscription Services, Inc., A Wiley Company</pub><doi>10.1002/pola.22928</doi><tpages>10</tpages></addata></record> |
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| subjects | Applied sciences conjugated polymers copolymerization Energy Exact sciences and technology fullerenes Natural energy Organic polymers Photovoltaic conversion Physicochemistry of polymers Polymers with particular properties Preparation, kinetics, thermodynamics, mechanism and catalysts Solar cells. Photoelectrochemical cells Solar energy |
| title | Synthesis and characterization of fluorene-based low-band gap copolymers containing propylenedioxythiophene and benzothiadiazole derivatives for bulk heterojunction photovoltaic cell applications |
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