Thermodynamic characterization of hybrid polymer blend systems
A thermodynamic model was used to predict the morphology of hybrid multicomponent polymer blend systems. Two systems were studied, both including two noncompatible polymers, a third compatibilizer polymer and layered, organo‐treated clays. The polar and nonpolar contributions of the surface energies...
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| Veröffentlicht in: | Polymer engineering and science 2009-06, Vol.49 (6), p.1168-1176 |
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| creator | Ophir, Amos Zonder, Lior Rios, Pablo F. |
| description | A thermodynamic model was used to predict the morphology of hybrid multicomponent polymer blend systems. Two systems were studied, both including two noncompatible polymers, a third compatibilizer polymer and layered, organo‐treated clays. The polar and nonpolar contributions of the surface energies of the components of the systems were calculated using measurements of the contact angles. The morphology of the multicomponent systems and the relative position of the organo‐clays within them, were predicted by calculating the interaction energies between the different components of the system and evaluating these values according to the Vaia and Giannelis thermodynamic model for polymer melt intercalation in organically modified layered silicates. The experimental results show good correlation with the prediction that the organo‐clays will have higher affinity to the compatibilizer polymer component situated at the interface between the two noncompatible blend components. In addition, the presence of the organo‐clays in this interface was found to have a significant additional compatibilizing effect between the two polymer phases. The results presented in this work support the idea that hybrid formation via polymer melt intercalation depends mostly on energetic factors that can be determined from surface energies of polymers and organo‐modified layered silicates, also in the case of multiphase polymer system. POLYM. ENG. SCI., 2009. © 2009 Society of Plastics Engineers |
| doi_str_mv | 10.1002/pen.21364 |
| format | Article |
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Two systems were studied, both including two noncompatible polymers, a third compatibilizer polymer and layered, organo‐treated clays. The polar and nonpolar contributions of the surface energies of the components of the systems were calculated using measurements of the contact angles. The morphology of the multicomponent systems and the relative position of the organo‐clays within them, were predicted by calculating the interaction energies between the different components of the system and evaluating these values according to the Vaia and Giannelis thermodynamic model for polymer melt intercalation in organically modified layered silicates. The experimental results show good correlation with the prediction that the organo‐clays will have higher affinity to the compatibilizer polymer component situated at the interface between the two noncompatible blend components. In addition, the presence of the organo‐clays in this interface was found to have a significant additional compatibilizing effect between the two polymer phases. The results presented in this work support the idea that hybrid formation via polymer melt intercalation depends mostly on energetic factors that can be determined from surface energies of polymers and organo‐modified layered silicates, also in the case of multiphase polymer system. POLYM. ENG. SCI., 2009. © 2009 Society of Plastics Engineers</description><identifier>ISSN: 0032-3888</identifier><identifier>EISSN: 1548-2634</identifier><identifier>DOI: 10.1002/pen.21364</identifier><identifier>CODEN: PYESAZ</identifier><language>eng</language><publisher>Hoboken: Wiley Subscription Services, Inc., A Wiley Company</publisher><subject>Applied sciences ; Chemical properties ; Composites ; Exact sciences and technology ; Forms of application and semi-finished materials ; Morphology ; Polymer blends ; Polymer industry, paints, wood ; Polymers ; Technology of polymers ; Thermal properties ; Thermodynamics</subject><ispartof>Polymer engineering and science, 2009-06, Vol.49 (6), p.1168-1176</ispartof><rights>Copyright © 2009 Society of Plastics Engineers</rights><rights>2009 INIST-CNRS</rights><rights>COPYRIGHT 2009 Society of Plastics Engineers, Inc.</rights><rights>Copyright Society of Plastics Engineers Jun 2009</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c5434-620a652d6ed628d269ee487747a6ed614519dfe696acc1d96eba59ab264be08b3</citedby><cites>FETCH-LOGICAL-c5434-620a652d6ed628d269ee487747a6ed614519dfe696acc1d96eba59ab264be08b3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fpen.21364$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fpen.21364$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>315,781,785,1418,27928,27929,45578,45579</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=21487993$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Ophir, Amos</creatorcontrib><creatorcontrib>Zonder, Lior</creatorcontrib><creatorcontrib>Rios, Pablo F.</creatorcontrib><title>Thermodynamic characterization of hybrid polymer blend systems</title><title>Polymer engineering and science</title><addtitle>Polym Eng Sci</addtitle><description>A thermodynamic model was used to predict the morphology of hybrid multicomponent polymer blend systems. Two systems were studied, both including two noncompatible polymers, a third compatibilizer polymer and layered, organo‐treated clays. The polar and nonpolar contributions of the surface energies of the components of the systems were calculated using measurements of the contact angles. The morphology of the multicomponent systems and the relative position of the organo‐clays within them, were predicted by calculating the interaction energies between the different components of the system and evaluating these values according to the Vaia and Giannelis thermodynamic model for polymer melt intercalation in organically modified layered silicates. The experimental results show good correlation with the prediction that the organo‐clays will have higher affinity to the compatibilizer polymer component situated at the interface between the two noncompatible blend components. In addition, the presence of the organo‐clays in this interface was found to have a significant additional compatibilizing effect between the two polymer phases. The results presented in this work support the idea that hybrid formation via polymer melt intercalation depends mostly on energetic factors that can be determined from surface energies of polymers and organo‐modified layered silicates, also in the case of multiphase polymer system. POLYM. ENG. SCI., 2009. © 2009 Society of Plastics Engineers</description><subject>Applied sciences</subject><subject>Chemical properties</subject><subject>Composites</subject><subject>Exact sciences and technology</subject><subject>Forms of application and semi-finished materials</subject><subject>Morphology</subject><subject>Polymer blends</subject><subject>Polymer industry, paints, wood</subject><subject>Polymers</subject><subject>Technology of polymers</subject><subject>Thermal properties</subject><subject>Thermodynamics</subject><issn>0032-3888</issn><issn>1548-2634</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2009</creationdate><recordtype>article</recordtype><sourceid>N95</sourceid><sourceid>8G5</sourceid><sourceid>ABUWG</sourceid><sourceid>AFKRA</sourceid><sourceid>AZQEC</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><sourceid>GNUQQ</sourceid><sourceid>GUQSH</sourceid><sourceid>M2O</sourceid><recordid>eNp1kl9rFDEUxQdRcK0--A0GQUFwtvk_kxehlLoW1lp1xceQydzZTZ1JtskMdvz0pu5arKwEErj8zuHem5NlzzGaY4TI8RbcnGAq2INshjmrCiIoe5jNEKKkoFVVPc6exHiFEku5nGVvVxsIvW8mp3trcrPRQZsBgv2pB-td7tt8M9XBNvnWd1MPIa87cE0epzhAH59mj1rdRXi2f4-yr-_OVqfvi-XHxfnpybIwnFFWCIK04KQR0AhSNURIAFaVJSv1bQkzjmXTgpBCG4MbKaDWXOqaCFYDqmp6lL3a-W6Dvx4hDqq30UDXaQd-jIoyTitCWAJf_ANe-TG41JsiuBKYEiQTVOygte5AWdf6IU29BgdBd95Ba1P5hCAsCOMlSfz8AJ9OA2lpBwWv7wkSM8DNsNZjjOr8y-f77Ju_2HqM1kFMV7TrzRB3kkPWJvgYA7RqG2yvw6QwUrcRUCkC6ncEEvtyvwwdje7aoJ2x8U5AcPoDKWnijnfcjzTH9H9DdXl28cd5v0GbYnBzp9DhuxIlLbn6drFQy0suFyv-QX2ivwBh_MwI</recordid><startdate>200906</startdate><enddate>200906</enddate><creator>Ophir, Amos</creator><creator>Zonder, Lior</creator><creator>Rios, Pablo F.</creator><general>Wiley Subscription Services, Inc., A Wiley Company</general><general>Wiley</general><general>Society of Plastics Engineers, Inc</general><general>Blackwell Publishing Ltd</general><scope>BSCLL</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>N95</scope><scope>XI7</scope><scope>ISR</scope><scope>3V.</scope><scope>7SR</scope><scope>7XB</scope><scope>88I</scope><scope>8AF</scope><scope>8FD</scope><scope>8FE</scope><scope>8FG</scope><scope>8FK</scope><scope>8G5</scope><scope>ABJCF</scope><scope>ABUWG</scope><scope>AFKRA</scope><scope>ARAPS</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>GNUQQ</scope><scope>GUQSH</scope><scope>HCIFZ</scope><scope>JG9</scope><scope>KB.</scope><scope>L6V</scope><scope>M2O</scope><scope>M2P</scope><scope>M7S</scope><scope>MBDVC</scope><scope>P5Z</scope><scope>P62</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><scope>PTHSS</scope><scope>Q9U</scope><scope>S0X</scope></search><sort><creationdate>200906</creationdate><title>Thermodynamic characterization of hybrid polymer blend systems</title><author>Ophir, Amos ; Zonder, Lior ; Rios, Pablo F.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c5434-620a652d6ed628d269ee487747a6ed614519dfe696acc1d96eba59ab264be08b3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2009</creationdate><topic>Applied sciences</topic><topic>Chemical properties</topic><topic>Composites</topic><topic>Exact sciences and technology</topic><topic>Forms of application and semi-finished materials</topic><topic>Morphology</topic><topic>Polymer blends</topic><topic>Polymer industry, paints, wood</topic><topic>Polymers</topic><topic>Technology of polymers</topic><topic>Thermal properties</topic><topic>Thermodynamics</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Ophir, Amos</creatorcontrib><creatorcontrib>Zonder, Lior</creatorcontrib><creatorcontrib>Rios, Pablo F.</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Gale Business: Insights</collection><collection>Business Insights: Essentials</collection><collection>Gale In Context: Science</collection><collection>ProQuest Central (Corporate)</collection><collection>Engineered Materials Abstracts</collection><collection>ProQuest Central (purchase pre-March 2016)</collection><collection>Science Database (Alumni Edition)</collection><collection>STEM Database</collection><collection>Technology Research Database</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>ProQuest Central (Alumni) (purchase pre-March 2016)</collection><collection>Research Library (Alumni Edition)</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central (Alumni Edition)</collection><collection>ProQuest Central UK/Ireland</collection><collection>Advanced Technologies & Aerospace Collection</collection><collection>ProQuest Central Essentials</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>ProQuest Central Student</collection><collection>Research Library Prep</collection><collection>SciTech Premium Collection</collection><collection>Materials Research Database</collection><collection>Materials Science Database</collection><collection>ProQuest Engineering Collection</collection><collection>Research Library</collection><collection>Science Database</collection><collection>Engineering Database</collection><collection>Research Library (Corporate)</collection><collection>Advanced Technologies & Aerospace Database</collection><collection>ProQuest Advanced Technologies & Aerospace Collection</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><collection>Engineering Collection</collection><collection>ProQuest Central Basic</collection><collection>SIRS Editorial</collection><jtitle>Polymer engineering and science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Ophir, Amos</au><au>Zonder, Lior</au><au>Rios, Pablo F.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Thermodynamic characterization of hybrid polymer blend systems</atitle><jtitle>Polymer engineering and science</jtitle><addtitle>Polym Eng Sci</addtitle><date>2009-06</date><risdate>2009</risdate><volume>49</volume><issue>6</issue><spage>1168</spage><epage>1176</epage><pages>1168-1176</pages><issn>0032-3888</issn><eissn>1548-2634</eissn><coden>PYESAZ</coden><abstract>A thermodynamic model was used to predict the morphology of hybrid multicomponent polymer blend systems. Two systems were studied, both including two noncompatible polymers, a third compatibilizer polymer and layered, organo‐treated clays. The polar and nonpolar contributions of the surface energies of the components of the systems were calculated using measurements of the contact angles. The morphology of the multicomponent systems and the relative position of the organo‐clays within them, were predicted by calculating the interaction energies between the different components of the system and evaluating these values according to the Vaia and Giannelis thermodynamic model for polymer melt intercalation in organically modified layered silicates. The experimental results show good correlation with the prediction that the organo‐clays will have higher affinity to the compatibilizer polymer component situated at the interface between the two noncompatible blend components. In addition, the presence of the organo‐clays in this interface was found to have a significant additional compatibilizing effect between the two polymer phases. The results presented in this work support the idea that hybrid formation via polymer melt intercalation depends mostly on energetic factors that can be determined from surface energies of polymers and organo‐modified layered silicates, also in the case of multiphase polymer system. POLYM. ENG. SCI., 2009. © 2009 Society of Plastics Engineers</abstract><cop>Hoboken</cop><pub>Wiley Subscription Services, Inc., A Wiley Company</pub><doi>10.1002/pen.21364</doi><tpages>9</tpages></addata></record> |
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| subjects | Applied sciences Chemical properties Composites Exact sciences and technology Forms of application and semi-finished materials Morphology Polymer blends Polymer industry, paints, wood Polymers Technology of polymers Thermal properties Thermodynamics |
| title | Thermodynamic characterization of hybrid polymer blend systems |
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