Simulation of RAFT Dispersion Polymerization in Supercritical Carbon Dioxide
The RAFT radical polymerization of vinyl monomers in supercritical carbon dioxide was modeled using the Predici® simulation package. The sensitivity of polymerization responses on formulation and process variables was analyzed. The simulations were carried out using kinetic and physical parameters c...
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| Veröffentlicht in: | Macromolecular theory and simulations 2008-08, Vol.17 (6), p.280-289 |
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| container_end_page | 289 |
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| container_issue | 6 |
| container_start_page | 280 |
| container_title | Macromolecular theory and simulations |
| container_volume | 17 |
| creator | Jaramillo-Soto, Gabriel Castellanos-Cárdenas, M. Luz García-Morán, Pedro R. Vivaldo-Lima, Eduardo Luna-Bárcenas, Gabriel Penlidis, Alexander |
| description | The RAFT radical polymerization of vinyl monomers in supercritical carbon dioxide was modeled using the Predici® simulation package. The sensitivity of polymerization responses on formulation and process variables was analyzed. The simulations were carried out using kinetic and physical parameters corresponding to the polymerization of methyl methacrylate in supercritical carbon dioxide, using AIBN as initiator, at 65 °C and 200 bar, and using values of the addition and fragmentation kinetic rate constants of a “typical” RAFT agent, as reference conditions. This is the first report in the literature addressing the modeling or simulation of RAFT polymerization in supercritical carbon dioxide. |
| doi_str_mv | 10.1002/mats.200800006 |
| format | Article |
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| subjects | Applied sciences dispersion polymerization Exact sciences and technology modeling Organic polymers Physicochemistry of polymers Polymerization Preparation, kinetics, thermodynamics, mechanism and catalysts radical polymerization reversible addition fragmentation chain transfer (RAFT) supercritical carbon dioxide |
| title | Simulation of RAFT Dispersion Polymerization in Supercritical Carbon Dioxide |
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