Study on metal complexes of chelating resins bearing iminodiacetate groups
Cu(II), Co(II) and Ni(II) complexes of chelating resins (CR) bearing iminodiacetate (IDA) ligands were prepared. The CR-metal complexes were characterized by FT-IR spectroscopy, X-ray diffraction (XRD), thermal behavior (TG and DTG) under nitrogen atmosphere, and electron paramagnetic resonance (EPR...
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| Veröffentlicht in: | European polymer journal 2009-07, Vol.45 (7), p.2119-2130 |
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| container_end_page | 2130 |
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| container_issue | 7 |
| container_start_page | 2119 |
| container_title | European polymer journal |
| container_volume | 45 |
| creator | Dragan, Ecaterina Stela Dinu, Maria Valentina Lisa, Gabriela Trochimczuk, Andrzej W. |
| description | Cu(II), Co(II) and Ni(II) complexes of chelating resins (CR) bearing iminodiacetate (IDA) ligands were prepared. The CR-metal complexes were characterized by FT-IR spectroscopy, X-ray diffraction (XRD), thermal behavior (TG and DTG) under nitrogen atmosphere, and electron paramagnetic resonance (EPR). FT-IR spectra of the CR-metal complexes showed the characteristic bands of CR were still present but red-shifted after the metal complexation, and new bands assigned to Me–N bonds were observed. Thermal behavior of the metal-CR complexes supported the metal complexation, metal complexation leading to the decrease of the thermal stability of the CR, the lowest thermal stability being found when the highest amount of Cu(II) was loaded. Based on the EPR results and the thermal behavior of Cu(II)-CR complexes, the scheme for the complexation of Cu(II) on the CR was suggested. |
| doi_str_mv | 10.1016/j.eurpolymj.2009.03.012 |
| format | Article |
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The CR-metal complexes were characterized by FT-IR spectroscopy, X-ray diffraction (XRD), thermal behavior (TG and DTG) under nitrogen atmosphere, and electron paramagnetic resonance (EPR). FT-IR spectra of the CR-metal complexes showed the characteristic bands of CR were still present but red-shifted after the metal complexation, and new bands assigned to Me–N bonds were observed. Thermal behavior of the metal-CR complexes supported the metal complexation, metal complexation leading to the decrease of the thermal stability of the CR, the lowest thermal stability being found when the highest amount of Cu(II) was loaded. Based on the EPR results and the thermal behavior of Cu(II)-CR complexes, the scheme for the complexation of Cu(II) on the CR was suggested.</description><identifier>ISSN: 0014-3057</identifier><identifier>EISSN: 1873-1945</identifier><identifier>DOI: 10.1016/j.eurpolymj.2009.03.012</identifier><identifier>CODEN: EUPJAG</identifier><language>eng</language><publisher>Kidlington: Elsevier Ltd</publisher><subject>Applied sciences ; Chelating resins ; Electron paramagnetic resonance ; Exact sciences and technology ; Exchange resins and membranes ; Forms of application and semi-finished materials ; FT-IR spectroscopy ; Polymer industry, paints, wood ; Polymer-metal complexes ; Technology of polymers ; Thermogravimetric analysis</subject><ispartof>European polymer journal, 2009-07, Vol.45 (7), p.2119-2130</ispartof><rights>2009 Elsevier Ltd</rights><rights>2009 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c376t-95197e2438d5800a22ff0db9647f1209231307cd1cf7ee4ab48c17a0dbd986d63</citedby><cites>FETCH-LOGICAL-c376t-95197e2438d5800a22ff0db9647f1209231307cd1cf7ee4ab48c17a0dbd986d63</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://www.sciencedirect.com/science/article/pii/S0014305709001190$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,776,780,3537,27901,27902,65306</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=21691484$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Dragan, Ecaterina Stela</creatorcontrib><creatorcontrib>Dinu, Maria Valentina</creatorcontrib><creatorcontrib>Lisa, Gabriela</creatorcontrib><creatorcontrib>Trochimczuk, Andrzej W.</creatorcontrib><title>Study on metal complexes of chelating resins bearing iminodiacetate groups</title><title>European polymer journal</title><description>Cu(II), Co(II) and Ni(II) complexes of chelating resins (CR) bearing iminodiacetate (IDA) ligands were prepared. The CR-metal complexes were characterized by FT-IR spectroscopy, X-ray diffraction (XRD), thermal behavior (TG and DTG) under nitrogen atmosphere, and electron paramagnetic resonance (EPR). FT-IR spectra of the CR-metal complexes showed the characteristic bands of CR were still present but red-shifted after the metal complexation, and new bands assigned to Me–N bonds were observed. Thermal behavior of the metal-CR complexes supported the metal complexation, metal complexation leading to the decrease of the thermal stability of the CR, the lowest thermal stability being found when the highest amount of Cu(II) was loaded. Based on the EPR results and the thermal behavior of Cu(II)-CR complexes, the scheme for the complexation of Cu(II) on the CR was suggested.</description><subject>Applied sciences</subject><subject>Chelating resins</subject><subject>Electron paramagnetic resonance</subject><subject>Exact sciences and technology</subject><subject>Exchange resins and membranes</subject><subject>Forms of application and semi-finished materials</subject><subject>FT-IR spectroscopy</subject><subject>Polymer industry, paints, wood</subject><subject>Polymer-metal complexes</subject><subject>Technology of polymers</subject><subject>Thermogravimetric analysis</subject><issn>0014-3057</issn><issn>1873-1945</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2009</creationdate><recordtype>article</recordtype><recordid>eNqFkMtOwzAQRS0EEqXwDWQDu4TxI3GyrCqeqsQCWFuuPSmukjjYCaJ_T6pWbFmNRjp3ruYQck0ho0CLu22GY-h9s2u3GQOoMuAZUHZCZrSUPKWVyE_JDICKlEMuz8lFjFsAkLzgM_LyNox2l_guaXHQTWJ82zf4gzHxdWI-sdGD6zZJwOi6mKxRh_3qWtd567SZMgMmm-DHPl6Ss1o3Ea-Oc04-Hu7fl0_p6vXxeblYpYbLYkirnFYSmeClzUsAzVhdg11XhZA1ZVAxTjlIY6mpJaLQa1EaKvWE2KosbMHn5PZwtw_-a8Q4qNZFg02jO_RjVFzkPGdsD8oDaIKPMWCt-uBaHXaKgtq7U1v1507t3SnganI3JW-OFToa3dRBd8bFvzijRUVFKSZuceBw-vfbYVDROOwMWhfQDMp692_XL3x3iho</recordid><startdate>20090701</startdate><enddate>20090701</enddate><creator>Dragan, Ecaterina Stela</creator><creator>Dinu, Maria Valentina</creator><creator>Lisa, Gabriela</creator><creator>Trochimczuk, Andrzej W.</creator><general>Elsevier Ltd</general><general>Elsevier</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20090701</creationdate><title>Study on metal complexes of chelating resins bearing iminodiacetate groups</title><author>Dragan, Ecaterina Stela ; Dinu, Maria Valentina ; Lisa, Gabriela ; Trochimczuk, Andrzej W.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c376t-95197e2438d5800a22ff0db9647f1209231307cd1cf7ee4ab48c17a0dbd986d63</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2009</creationdate><topic>Applied sciences</topic><topic>Chelating resins</topic><topic>Electron paramagnetic resonance</topic><topic>Exact sciences and technology</topic><topic>Exchange resins and membranes</topic><topic>Forms of application and semi-finished materials</topic><topic>FT-IR spectroscopy</topic><topic>Polymer industry, paints, wood</topic><topic>Polymer-metal complexes</topic><topic>Technology of polymers</topic><topic>Thermogravimetric analysis</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Dragan, Ecaterina Stela</creatorcontrib><creatorcontrib>Dinu, Maria Valentina</creatorcontrib><creatorcontrib>Lisa, Gabriela</creatorcontrib><creatorcontrib>Trochimczuk, Andrzej W.</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>European polymer journal</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Dragan, Ecaterina Stela</au><au>Dinu, Maria Valentina</au><au>Lisa, Gabriela</au><au>Trochimczuk, Andrzej W.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Study on metal complexes of chelating resins bearing iminodiacetate groups</atitle><jtitle>European polymer journal</jtitle><date>2009-07-01</date><risdate>2009</risdate><volume>45</volume><issue>7</issue><spage>2119</spage><epage>2130</epage><pages>2119-2130</pages><issn>0014-3057</issn><eissn>1873-1945</eissn><coden>EUPJAG</coden><abstract>Cu(II), Co(II) and Ni(II) complexes of chelating resins (CR) bearing iminodiacetate (IDA) ligands were prepared. The CR-metal complexes were characterized by FT-IR spectroscopy, X-ray diffraction (XRD), thermal behavior (TG and DTG) under nitrogen atmosphere, and electron paramagnetic resonance (EPR). FT-IR spectra of the CR-metal complexes showed the characteristic bands of CR were still present but red-shifted after the metal complexation, and new bands assigned to Me–N bonds were observed. Thermal behavior of the metal-CR complexes supported the metal complexation, metal complexation leading to the decrease of the thermal stability of the CR, the lowest thermal stability being found when the highest amount of Cu(II) was loaded. Based on the EPR results and the thermal behavior of Cu(II)-CR complexes, the scheme for the complexation of Cu(II) on the CR was suggested.</abstract><cop>Kidlington</cop><pub>Elsevier Ltd</pub><doi>10.1016/j.eurpolymj.2009.03.012</doi><tpages>12</tpages></addata></record> |
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| source | Elsevier ScienceDirect Journals Complete |
| subjects | Applied sciences Chelating resins Electron paramagnetic resonance Exact sciences and technology Exchange resins and membranes Forms of application and semi-finished materials FT-IR spectroscopy Polymer industry, paints, wood Polymer-metal complexes Technology of polymers Thermogravimetric analysis |
| title | Study on metal complexes of chelating resins bearing iminodiacetate groups |
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