Preparation of PANI-coated poly (styrene-co-styrene sulfonate) nanoparticles in microemulsion media

Electrically conductive core–shell nanoparticles (PANI/PS-PSS) were synthesized by coating poly (styrene-co-styrene sulfonate) (PS-PSS) nanoparticles with polyaniline (PANI). PS-PSS core particles were prepared in microemulsion system in nitrogen atmosphere and further coated with PANI by using in s...

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Veröffentlicht in:Colloids and surfaces. A, Physicochemical and engineering aspects Physicochemical and engineering aspects, 2009-08, Vol.345 (1), p.71-74
Hauptverfasser: Wang, Ying, Shi, Yuanchang, Xu, Xiaokuai, Liu, Feng, Yao, Huiling, Zhai, Guangyao, Hao, Jingcheng, Li, Ganzuo
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container_issue 1
container_start_page 71
container_title Colloids and surfaces. A, Physicochemical and engineering aspects
container_volume 345
creator Wang, Ying
Shi, Yuanchang
Xu, Xiaokuai
Liu, Feng
Yao, Huiling
Zhai, Guangyao
Hao, Jingcheng
Li, Ganzuo
description Electrically conductive core–shell nanoparticles (PANI/PS-PSS) were synthesized by coating poly (styrene-co-styrene sulfonate) (PS-PSS) nanoparticles with polyaniline (PANI). PS-PSS core particles were prepared in microemulsion system in nitrogen atmosphere and further coated with PANI by using in situ polymerization method at low temperature. The core–shell structure of PANI/PS-PSS composites was determined by transmission electron microscopy (TEM) and FTIR measurements. In addition, the role of the aniline content was also investigated. The stability of the coated latexes and the conductivity of PANI/PS-PSS pellets were investigated. It was found that the core–shell structure of PANI-coated PS-PSS can be obtained when PANI in PANI/PS-PSS copolymer varies from 2.78 to 12.5 wt%. The highest conductivity of PANI/PS-PSS pellets is 1.7 S/cm.
doi_str_mv 10.1016/j.colsurfa.2009.04.029
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subjects Chemistry
Colloidal state and disperse state
Core–shell
Emulsions. Microemulsions. Foams
Exact sciences and technology
General and physical chemistry
Microemulsion
Nanoparticles
PANI
Physical and chemical studies. Granulometry. Electrokinetic phenomena
Surface physical chemistry
title Preparation of PANI-coated poly (styrene-co-styrene sulfonate) nanoparticles in microemulsion media
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