Increased growth rate of anodic porous alumina by use of ionic liquid as electrolyte additive
The use of ionic liquids 1-Butyl-3-methylimidazolium 2-(2-methoxyethoxy) ethyl sulfate and 1-Butyl-3-methylimidazolium tetrafluoborate has been tested in the fabrication of anodic porous alumina. The anodizations of the aluminium substrate have been carried out in oxalic acid in galvanostatic mode....
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Veröffentlicht in: | Materials letters 2009-08, Vol.63 (21), p.1826-1829 |
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creator | Salerno, Marco Patra, Niranjan Losso, Romeo Cingolani, Roberto |
description | The use of ionic liquids 1-Butyl-3-methylimidazolium 2-(2-methoxyethoxy) ethyl sulfate and 1-Butyl-3-methylimidazolium tetrafluoborate has been tested in the fabrication of anodic porous alumina. The anodizations of the aluminium substrate have been carried out in oxalic acid in galvanostatic mode. During anodization with 1-Butyl-3-methylimidazolium tetrafluoborate added electrolyte, proper tuning of the current density and of the additive concentration resulted in a three-fold increase of the growth rate as compared to the bare acidic solution with the same acid concentration. This did not cause cracks in the film during growth, and did not affect the regular structure of the pores at the interface with the substrate. |
doi_str_mv | 10.1016/j.matlet.2009.05.058 |
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The anodizations of the aluminium substrate have been carried out in oxalic acid in galvanostatic mode. During anodization with 1-Butyl-3-methylimidazolium tetrafluoborate added electrolyte, proper tuning of the current density and of the additive concentration resulted in a three-fold increase of the growth rate as compared to the bare acidic solution with the same acid concentration. This did not cause cracks in the film during growth, and did not affect the regular structure of the pores at the interface with the substrate.</description><subject>Alumina</subject><subject>Anodization</subject><subject>Growth rate</subject><subject>Ionic liquid</subject><subject>Nanomaterials</subject><subject>Porosity</subject><issn>0167-577X</issn><issn>1873-4979</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2009</creationdate><recordtype>article</recordtype><recordid>eNp9UMtKAzEUDaJgrf6Bi6zcTc00yWSyEUR8FAQ3Cm4k3CY3mjKdtMmM0r83WtfCgbs4D-45hJzXbFazurlczdYwdDjM5ozpGZMF7QGZ1K3ildBKH5JJkalKKvV6TE5yXjHGhGZiQt4WvU0IGR19T_Fr-KAJBqTRU-ijC5ZuYopjptCN69ADXe7omH_5EPtCd2E7BkchU-zQDil2u2IH58IQPvGUHHnoMp793Sl5ubt9vnmoHp_uFzfXj5XlLR8qnAumQMhGADS19Ew3suWKta30unYaNHAtXOvkUogGvNVz5YXjS88Vemv5lFzsczcpbkfMg1mHbLHroMfyveFCMiEFL0KxF9oUc07ozSaFNaSdqZn52dKszH5L87OlYbKgLbarvQ1Lic-AyWQbsLfoQiqtjYvh_4BvftuAdA</recordid><startdate>20090831</startdate><enddate>20090831</enddate><creator>Salerno, Marco</creator><creator>Patra, Niranjan</creator><creator>Losso, Romeo</creator><creator>Cingolani, Roberto</creator><general>Elsevier B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7QF</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20090831</creationdate><title>Increased growth rate of anodic porous alumina by use of ionic liquid as electrolyte additive</title><author>Salerno, Marco ; Patra, Niranjan ; Losso, Romeo ; Cingolani, Roberto</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c383t-e2407a4564aa615f09658370885f91d9a9a394d8d5b446afc927f4d3bf37efcc3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2009</creationdate><topic>Alumina</topic><topic>Anodization</topic><topic>Growth rate</topic><topic>Ionic liquid</topic><topic>Nanomaterials</topic><topic>Porosity</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Salerno, Marco</creatorcontrib><creatorcontrib>Patra, Niranjan</creatorcontrib><creatorcontrib>Losso, Romeo</creatorcontrib><creatorcontrib>Cingolani, Roberto</creatorcontrib><collection>CrossRef</collection><collection>Aluminium Industry Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Materials letters</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Salerno, Marco</au><au>Patra, Niranjan</au><au>Losso, Romeo</au><au>Cingolani, Roberto</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Increased growth rate of anodic porous alumina by use of ionic liquid as electrolyte additive</atitle><jtitle>Materials letters</jtitle><date>2009-08-31</date><risdate>2009</risdate><volume>63</volume><issue>21</issue><spage>1826</spage><epage>1829</epage><pages>1826-1829</pages><issn>0167-577X</issn><eissn>1873-4979</eissn><abstract>The use of ionic liquids 1-Butyl-3-methylimidazolium 2-(2-methoxyethoxy) ethyl sulfate and 1-Butyl-3-methylimidazolium tetrafluoborate has been tested in the fabrication of anodic porous alumina. 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subjects | Alumina Anodization Growth rate Ionic liquid Nanomaterials Porosity |
title | Increased growth rate of anodic porous alumina by use of ionic liquid as electrolyte additive |
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