Micro-structural and rheological characteristics of SBS-asphalt blends during their manufacturing

Two styrene–butadiene–styrene block (SBS) copolymers which differ in weight average molecular weight and two base asphalts (from local crude source, Argentina) had been blended under different experimental conditions. Rotational viscosity, fluorescence microscopy, size exclusion chromatography (SEC)...

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Veröffentlicht in:Construction & building materials 2009-08, Vol.23 (8), p.2769-2774
Hauptverfasser: Larsen, Diego O., Alessandrini, José Luis, Bosch, Alejandra, Cortizo, M. Susana
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container_end_page 2774
container_issue 8
container_start_page 2769
container_title Construction & building materials
container_volume 23
creator Larsen, Diego O.
Alessandrini, José Luis
Bosch, Alejandra
Cortizo, M. Susana
description Two styrene–butadiene–styrene block (SBS) copolymers which differ in weight average molecular weight and two base asphalts (from local crude source, Argentina) had been blended under different experimental conditions. Rotational viscosity, fluorescence microscopy, size exclusion chromatography (SEC) and FT-IR spectrometry were used in order to study the rheological and morphological changes of the blends during their manufacturing. Our results show that the high shear rate and temperature used during this procedure induce the SBS copolymer degradation and the degradation fragments distribution into maltenic asphalt phase. These events are responsible for the observed changes. The optimal time which produces the best rheological properties of modified asphalt depends on the blend composition and on the shear rate used.
doi_str_mv 10.1016/j.conbuildmat.2009.03.008
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source Elsevier ScienceDirect Journals
subjects Aromatic compounds
Asphalt industry
Bituminous materials
Block copolymers
Butadiene
Chromatography
FT-IR
Mechanical properties
Modified asphalt
Morphology
Polymers
Production processes
SBS copolymer
Viscosity
Weight average molecular weight
title Micro-structural and rheological characteristics of SBS-asphalt blends during their manufacturing
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