Thermodynamic investigation of the Pb – Sb system

The enthalpies of mixing of lead – antimony alloys were determined at 973 K in the range 0.2 < X Sb < 0.6 by direct liquid–liquid reaction calorimetry (DLLRC). The results are compared with data of the literature. The mixing enthalpies in the Pb – Sb liquid phase are weakly negative over the e...

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Veröffentlicht in:	Journal of alloys and compounds 2009-05, Vol.476 (1), p.74-78
Hauptverfasser:	Hassam, S., Boa, D., Fouque, Y., Kotchi, K.P., Rogez, J.
Format:	Artikel
Sprache:	eng
Schlagworte:	Condensed matter: structure, mechanical and thermal properties Cross-disciplinary physics: materials science rheology DLLRC DSC Enthalpy of mixing Exact sciences and technology Lead–antimony system Materials science Optimization Phase diagram Phase diagrams and microstructures developed by solidification and solid-solid phase transformations Phase diagrams of metals and alloys Physics Thermal properties of condensed matter Thermal properties of crystalline solids Thermodynamic properties
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container_title	Journal of alloys and compounds
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creator	Hassam, S. Boa, D. Fouque, Y. Kotchi, K.P. Rogez, J.
description	The enthalpies of mixing of lead – antimony alloys were determined at 973 K in the range 0.2 < X Sb < 0.6 by direct liquid–liquid reaction calorimetry (DLLRC). The results are compared with data of the literature. The mixing enthalpies in the Pb – Sb liquid phase are weakly negative over the entire investigated concentration range with a minimum at Δ mix H m = −70 J mol −1 at X Sb = 0.4. In addition, the Pb – Sb phase diagram on the Pb-rich side was revised using differential scanning calorimetry (DSC). The coordinates of the eutectic point have been ensured. An optimization of the binary Pb – Sb system was finally performed. The calculated phase diagram and thermodynamic functions agree well with experimental data.
doi_str_mv	10.1016/j.jallcom.2008.09.002
format	Article
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subjects	Condensed matter: structure, mechanical and thermal properties Cross-disciplinary physics: materials science rheology DLLRC DSC Enthalpy of mixing Exact sciences and technology Lead–antimony system Materials science Optimization Phase diagram Phase diagrams and microstructures developed by solidification and solid-solid phase transformations Phase diagrams of metals and alloys Physics Thermal properties of condensed matter Thermal properties of crystalline solids Thermodynamic properties
title	Thermodynamic investigation of the Pb – Sb system
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