Preparation of novel axially chiral NHC-Pd(II) complexes and their application in oxidative kinetic resolution of secondary alcohols

Novel axially chiral N‐heterocyclic carbene (NHC) Pd(II) complexes were prepared from optically active 1,1′‐binaphthalenyl‐2,2′‐diamine (BINAM) and H8‐BINAM and their crystal structures were unambiguously determined by X‐ray diffraction. These chiral N‐heterocyclic carbene (NHC) Pd(II) complexes wer...

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Veröffentlicht in:	Applied organometallic chemistry 2009-05, Vol.23 (5), p.183-190
Hauptverfasser:	Liu, Shi-Jia, Liu, Lian-jun, Shi, Min
Format:	Artikel
Sprache:	eng
Schlagworte:	1,1′‐binaphthalenyl‐2,2′‐diamine (BINAM) 1′-binaphthalenyl-2 2′-diamine (BINAM) axially chiral NHC-Pd(II) complex H8-BINAM oxidative kinetic resolution of secondary alcohols X-ray diffraction
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