Inorganic precursor peroxides for antifouling coatings
Modern antifouling coatings are generally based on cuprous oxide (Cu 2 O) and organic biocides as active ingredients. Cu 2 O is prone to bioaccumulation, and should therefore be replaced by more environmentally benign compounds when technically possible. However, cuprous oxide does not only provide...
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| Veröffentlicht in: | JCT Research 2009-06, Vol.6 (2), p.187-199 |
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| creator | Olsen, S. M. Pedersen, L. T. Hermann, M. H. Kiil, S. Dam-Johansen, K. |
| description | Modern antifouling coatings are generally based on cuprous oxide (Cu
2
O) and organic biocides as active ingredients. Cu
2
O is prone to bioaccumulation, and should therefore be replaced by more environmentally benign compounds when technically possible. However, cuprous oxide does not only provide antifouling properties, it is also a vital ingredient for the antifouling coating to obtain its polishing and leaching mechanism. In this paper, peroxides of strontium, calcium, magnesium, and zinc are tested as pigments in antifouling coatings. The peroxides react with seawater to create hydrogen peroxide and highly seawater-soluble ions of the metal. The goals have been to establish the antifouling potency of an antifouling coating that releases hydrogen peroxide as biocide, and to investigate the potential use of peroxides as water-soluble polishing and leaching pigments. The investigations have shown that it is possible to identify particulates that, when applied as pigments in antifouling coatings, will provide polishing and leaching rates comparable to those of Cu
2
O-based coatings. Furthermore, the combination of polishing and hydrogen peroxide leaching by a coating based on zinc peroxide in a suitable binder matrix provides antifouling properties exceeding those of a similar coating based entirely on zinc oxide. |
| doi_str_mv | 10.1007/s11998-008-9143-3 |
| format | Article |
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2
O) and organic biocides as active ingredients. Cu
2
O is prone to bioaccumulation, and should therefore be replaced by more environmentally benign compounds when technically possible. However, cuprous oxide does not only provide antifouling properties, it is also a vital ingredient for the antifouling coating to obtain its polishing and leaching mechanism. In this paper, peroxides of strontium, calcium, magnesium, and zinc are tested as pigments in antifouling coatings. The peroxides react with seawater to create hydrogen peroxide and highly seawater-soluble ions of the metal. The goals have been to establish the antifouling potency of an antifouling coating that releases hydrogen peroxide as biocide, and to investigate the potential use of peroxides as water-soluble polishing and leaching pigments. The investigations have shown that it is possible to identify particulates that, when applied as pigments in antifouling coatings, will provide polishing and leaching rates comparable to those of Cu
2
O-based coatings. Furthermore, the combination of polishing and hydrogen peroxide leaching by a coating based on zinc peroxide in a suitable binder matrix provides antifouling properties exceeding those of a similar coating based entirely on zinc oxide.</description><identifier>ISSN: 1547-0091</identifier><identifier>ISSN: 1945-9645</identifier><identifier>EISSN: 1935-3804</identifier><identifier>EISSN: 2168-8028</identifier><identifier>DOI: 10.1007/s11998-008-9143-3</identifier><language>eng</language><publisher>Boston: Springer US</publisher><subject>Applied sciences ; Chemistry and Materials Science ; Coatings ; Coatings. Paints, varnishes and inks ; Components, formulation ; Copper oxide ; Corrosion and Coatings ; Cuprite ; Dyes and dyeing ; Exact sciences and technology ; Hydrogen peroxide ; Industrial Chemistry/Chemical Engineering ; Leaching ; Materials Science ; Polymer industry, paints, wood ; Polymer Sciences ; Sea-water ; Surfaces and Interfaces ; Thin Films ; Tribology</subject><ispartof>JCT Research, 2009-06, Vol.6 (2), p.187-199</ispartof><rights>FSCT and OCCA 2008</rights><rights>2015 INIST-CNRS</rights><rights>COPYRIGHT 2009 American Coatings Association, Inc.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c494t-6b54dea145f9589c44991a598dc295349199cba58a37822405e6e634484c7dc03</citedby><cites>FETCH-LOGICAL-c494t-6b54dea145f9589c44991a598dc295349199cba58a37822405e6e634484c7dc03</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s11998-008-9143-3$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s11998-008-9143-3$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=21810336$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Olsen, S. M.</creatorcontrib><creatorcontrib>Pedersen, L. T.</creatorcontrib><creatorcontrib>Hermann, M. H.</creatorcontrib><creatorcontrib>Kiil, S.</creatorcontrib><creatorcontrib>Dam-Johansen, K.</creatorcontrib><title>Inorganic precursor peroxides for antifouling coatings</title><title>JCT Research</title><addtitle>J Coat Technol Res</addtitle><description>Modern antifouling coatings are generally based on cuprous oxide (Cu
2
O) and organic biocides as active ingredients. Cu
2
O is prone to bioaccumulation, and should therefore be replaced by more environmentally benign compounds when technically possible. However, cuprous oxide does not only provide antifouling properties, it is also a vital ingredient for the antifouling coating to obtain its polishing and leaching mechanism. In this paper, peroxides of strontium, calcium, magnesium, and zinc are tested as pigments in antifouling coatings. The peroxides react with seawater to create hydrogen peroxide and highly seawater-soluble ions of the metal. The goals have been to establish the antifouling potency of an antifouling coating that releases hydrogen peroxide as biocide, and to investigate the potential use of peroxides as water-soluble polishing and leaching pigments. The investigations have shown that it is possible to identify particulates that, when applied as pigments in antifouling coatings, will provide polishing and leaching rates comparable to those of Cu
2
O-based coatings. Furthermore, the combination of polishing and hydrogen peroxide leaching by a coating based on zinc peroxide in a suitable binder matrix provides antifouling properties exceeding those of a similar coating based entirely on zinc oxide.</description><subject>Applied sciences</subject><subject>Chemistry and Materials Science</subject><subject>Coatings</subject><subject>Coatings. Paints, varnishes and inks</subject><subject>Components, formulation</subject><subject>Copper oxide</subject><subject>Corrosion and Coatings</subject><subject>Cuprite</subject><subject>Dyes and dyeing</subject><subject>Exact sciences and technology</subject><subject>Hydrogen peroxide</subject><subject>Industrial Chemistry/Chemical Engineering</subject><subject>Leaching</subject><subject>Materials Science</subject><subject>Polymer industry, paints, wood</subject><subject>Polymer Sciences</subject><subject>Sea-water</subject><subject>Surfaces and Interfaces</subject><subject>Thin Films</subject><subject>Tribology</subject><issn>1547-0091</issn><issn>1945-9645</issn><issn>1935-3804</issn><issn>2168-8028</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2009</creationdate><recordtype>article</recordtype><sourceid>N95</sourceid><recordid>eNqFkV1rFTEQhhdRsFZ_gHfnRq_cmsnHbnJZitVCoTd6HeZkZ9eUPckxswv6781hiygUS2Amk3neIcPbNG9BXIAQ_UcGcM62QtjWgVatetacgVOmVVbo5_VudF-7Dl42r5jvhZC9teqs6W5SLhOmGHbHQmEtnMvuSCX_jAPxbqwVpiWOeZ1jmnYh41Izv25ejDgzvXnI5823609fr760t3efb64ub9ugnV7abm_0QAjajM5YF7R2DtA4OwTpjNKufjrs0VhUvZVSC0MddUprq0M_BKHOm_fb3GPJP1bixR8iB5pnTJRX9krLHqQ1T4ISQCnRdRVsN3DCmXxMY14KhokSFZxzojHW50spBFS4g8pfPMLXM9AhhkcFH_4S7FeOibgGjtP3hSdcmf_FYcNDycyFRn8s8YDllwfhT9b6zVpfrfUna72qmncPyyIHnMeCKUT-I5RgQSh12lVuHNdWmqj4-7yWVA37z_DfrRGwzA</recordid><startdate>20090601</startdate><enddate>20090601</enddate><creator>Olsen, S. M.</creator><creator>Pedersen, L. T.</creator><creator>Hermann, M. H.</creator><creator>Kiil, S.</creator><creator>Dam-Johansen, K.</creator><general>Springer US</general><general>Springer</general><general>American Coatings Association, Inc</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>N95</scope><scope>XI7</scope><scope>7TV</scope><scope>C1K</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20090601</creationdate><title>Inorganic precursor peroxides for antifouling coatings</title><author>Olsen, S. M. ; Pedersen, L. T. ; Hermann, M. H. ; Kiil, S. ; Dam-Johansen, K.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c494t-6b54dea145f9589c44991a598dc295349199cba58a37822405e6e634484c7dc03</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2009</creationdate><topic>Applied sciences</topic><topic>Chemistry and Materials Science</topic><topic>Coatings</topic><topic>Coatings. Paints, varnishes and inks</topic><topic>Components, formulation</topic><topic>Copper oxide</topic><topic>Corrosion and Coatings</topic><topic>Cuprite</topic><topic>Dyes and dyeing</topic><topic>Exact sciences and technology</topic><topic>Hydrogen peroxide</topic><topic>Industrial Chemistry/Chemical Engineering</topic><topic>Leaching</topic><topic>Materials Science</topic><topic>Polymer industry, paints, wood</topic><topic>Polymer Sciences</topic><topic>Sea-water</topic><topic>Surfaces and Interfaces</topic><topic>Thin Films</topic><topic>Tribology</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Olsen, S. M.</creatorcontrib><creatorcontrib>Pedersen, L. T.</creatorcontrib><creatorcontrib>Hermann, M. H.</creatorcontrib><creatorcontrib>Kiil, S.</creatorcontrib><creatorcontrib>Dam-Johansen, K.</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Gale Business: Insights</collection><collection>Business Insights: Essentials</collection><collection>Pollution Abstracts</collection><collection>Environmental Sciences and Pollution Management</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>JCT Research</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Olsen, S. M.</au><au>Pedersen, L. T.</au><au>Hermann, M. H.</au><au>Kiil, S.</au><au>Dam-Johansen, K.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Inorganic precursor peroxides for antifouling coatings</atitle><jtitle>JCT Research</jtitle><stitle>J Coat Technol Res</stitle><date>2009-06-01</date><risdate>2009</risdate><volume>6</volume><issue>2</issue><spage>187</spage><epage>199</epage><pages>187-199</pages><issn>1547-0091</issn><issn>1945-9645</issn><eissn>1935-3804</eissn><eissn>2168-8028</eissn><abstract>Modern antifouling coatings are generally based on cuprous oxide (Cu
2
O) and organic biocides as active ingredients. Cu
2
O is prone to bioaccumulation, and should therefore be replaced by more environmentally benign compounds when technically possible. However, cuprous oxide does not only provide antifouling properties, it is also a vital ingredient for the antifouling coating to obtain its polishing and leaching mechanism. In this paper, peroxides of strontium, calcium, magnesium, and zinc are tested as pigments in antifouling coatings. The peroxides react with seawater to create hydrogen peroxide and highly seawater-soluble ions of the metal. The goals have been to establish the antifouling potency of an antifouling coating that releases hydrogen peroxide as biocide, and to investigate the potential use of peroxides as water-soluble polishing and leaching pigments. The investigations have shown that it is possible to identify particulates that, when applied as pigments in antifouling coatings, will provide polishing and leaching rates comparable to those of Cu
2
O-based coatings. Furthermore, the combination of polishing and hydrogen peroxide leaching by a coating based on zinc peroxide in a suitable binder matrix provides antifouling properties exceeding those of a similar coating based entirely on zinc oxide.</abstract><cop>Boston</cop><pub>Springer US</pub><doi>10.1007/s11998-008-9143-3</doi><tpages>13</tpages></addata></record> |
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| subjects | Applied sciences Chemistry and Materials Science Coatings Coatings. Paints, varnishes and inks Components, formulation Copper oxide Corrosion and Coatings Cuprite Dyes and dyeing Exact sciences and technology Hydrogen peroxide Industrial Chemistry/Chemical Engineering Leaching Materials Science Polymer industry, paints, wood Polymer Sciences Sea-water Surfaces and Interfaces Thin Films Tribology |
| title | Inorganic precursor peroxides for antifouling coatings |
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