Microstructure and local magnetic induction of segmented and alloyed Pd/Co nanocomposites encapsulated inside vertically aligned multiwalled carbon nanotubes

We have successfully synthesized the Co/Pd magnetic and nonmagnetic multisegment nanowires encapsulated inside multiwalled carbon nanotubes (MWCNTs) by using Co and Pd thin-layers deposited on Si substrate by microwave plasma enhanced chemical vapor deposition. Energy dispersive X-ray spectroscopy r...

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Veröffentlicht in:Diamond and related materials 2008-07, Vol.17 (7), p.1525-1528
Hauptverfasser: Hayashi, Yasuhiko, Fujita, T., Tokunaga, T., Kaneko, K., Tanemura, M., Butler, T., Rupesinghe, N., Carey, J.D., Silva, S.R.P., Teo, K.B.K., Amaratunga, G.A.J.
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container_end_page 1528
container_issue 7
container_start_page 1525
container_title Diamond and related materials
container_volume 17
creator Hayashi, Yasuhiko
Fujita, T.
Tokunaga, T.
Kaneko, K.
Tanemura, M.
Butler, T.
Rupesinghe, N.
Carey, J.D.
Silva, S.R.P.
Teo, K.B.K.
Amaratunga, G.A.J.
description We have successfully synthesized the Co/Pd magnetic and nonmagnetic multisegment nanowires encapsulated inside multiwalled carbon nanotubes (MWCNTs) by using Co and Pd thin-layers deposited on Si substrate by microwave plasma enhanced chemical vapor deposition. Energy dispersive X-ray spectroscopy revealed that MWCNTs were encapsulated with Co and Pd nanowires, separately, at the tube top and the bottom of Co nanowire, respectively. The face-centered-cubic (fcc) structure of Co nanowires was confirmed by a selected area diffraction pattern. We proposed a fruitful description for the encapsulating mechanisms of both Co and Pd multisegment nanowires. The component of magnetic induction from Co region, not Pd region, was then estimated to be 1.2 ± 0.1 T, based on results of off-axis electron holography, which is lower than the expected saturation magnetization of fcc bulk Co of 1.7 T. We proposed a fruitful description for the mechanisms of reduced magnetic induction from Co nanowires.
doi_str_mv 10.1016/j.diamond.2008.03.012
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subjects Condensed matter: electronic structure, electrical, magnetic, and optical properties
Condensed matter: structure, mechanical and thermal properties
Cross-disciplinary physics: materials science
rheology
Encapsulation of multisegments
Energy dispersive X-ray spectroscopy
Exact sciences and technology
Magnetic properties and materials
Magnetic properties of nanostructures
Materials science
Multiwalled carbon nanotubes (MWCNTs)
Nanoscale materials and structures: fabrication and characterization
Nanotubes
Off-axis electron holography
Physics
Quantum wires
Structure and morphology
thickness
Surfaces and interfaces
thin films and whiskers (structure and nonelectronic properties)
Thin film structure and morphology
title Microstructure and local magnetic induction of segmented and alloyed Pd/Co nanocomposites encapsulated inside vertically aligned multiwalled carbon nanotubes
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