Electrochemical lithium insertion in (PO2)4(WO3)2m (2 ≤ m ≤ 10) : Relation among the electrochemical insertion process and structural features
In this work it is presented a review of the main results obtained during the electrochemical lithium insertion in the family of monophosphate tungsten bronzes (PO2)4(WO3)2m (2 < = m < = 10). This family of oxides is a good system in order to study the relation among the electrochemical proces...
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| Veröffentlicht in: | Electrochimica acta 2009-04, Vol.54 (11), p.3176-3183 |
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| container_title | Electrochimica acta |
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| creator | MARTINEZ-DE LA CRUZ, A LONGORIA RODRIGUEZ, F. E |
| description | In this work it is presented a review of the main results obtained during the electrochemical lithium insertion in the family of monophosphate tungsten bronzes (PO2)4(WO3)2m (2 < = m < = 10). This family of oxides is a good system in order to study the relation among the electrochemical processes observed in the course of lithium insertion and the changes of bronzes structures. By means of X-ray diffraction experiments, the nature of Lix(PO2)4(WO3)2m phases has been elucidated and a correlation with the reversible/irreversible processes observed during the electrochemical insertion has been established. The electrical properties of the inserted Lix(PO2)4(WO3)2m phases were measured and a relation with the amount of lithium inserted and m was also found. |
| doi_str_mv | 10.1016/j.electacta.2008.11.056 |
| format | Article |
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The electrical properties of the inserted Lix(PO2)4(WO3)2m phases were measured and a relation with the amount of lithium inserted and m was also found.</description><identifier>ISSN: 0013-4686</identifier><identifier>EISSN: 1873-3859</identifier><identifier>DOI: 10.1016/j.electacta.2008.11.056</identifier><identifier>CODEN: ELCAAV</identifier><language>eng</language><publisher>Kidlington: Elsevier</publisher><subject>Applied sciences ; Direct energy conversion and energy accumulation ; Electrical engineering. 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The electrical properties of the inserted Lix(PO2)4(WO3)2m phases were measured and a relation with the amount of lithium inserted and m was also found.</description><subject>Applied sciences</subject><subject>Direct energy conversion and energy accumulation</subject><subject>Electrical engineering. 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| source | Elsevier ScienceDirect Journals |
| subjects | Applied sciences Direct energy conversion and energy accumulation Electrical engineering. Electrical power engineering Electrical power engineering Electrochemical conversion: primary and secondary batteries, fuel cells Exact sciences and technology |
| title | Electrochemical lithium insertion in (PO2)4(WO3)2m (2 ≤ m ≤ 10) : Relation among the electrochemical insertion process and structural features |
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