Oxidation refining of iron using plasma-arc melting

Oxidation refining of Fe using plasma arc melting, by the addition of iron oxide as an oxidizing agent, has been carried out. In this refining process, an impurity element which has higher affinity for oxygen than iron was expected to be eliminated. As the result, decreases in Si, Mn, Al, Ca, Ga, an...

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Veröffentlicht in:Journal of materials science 2008-08, Vol.43 (16), p.5430-5435
Hauptverfasser: Uchikoshi, Masahito, Imai, Kazuki, Mimura, Kouji, Isshiki, Minoru
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container_issue 16
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creator Uchikoshi, Masahito
Imai, Kazuki
Mimura, Kouji
Isshiki, Minoru
description Oxidation refining of Fe using plasma arc melting, by the addition of iron oxide as an oxidizing agent, has been carried out. In this refining process, an impurity element which has higher affinity for oxygen than iron was expected to be eliminated. As the result, decreases in Si, Mn, Al, Ca, Ga, and Zr were observed and 99.996 mass% of iron could be obtained from 99.93 mass% of electrolytic iron by plasma arc melting under oxidizing conditions followed by argon–hydrogen plasma arc melting. Specifically, the removal of Si was found to proceed by the distribution between in the liquid Fe phase and in the oxide phase. In addition, the relation of Si and oxygen concentration in liquid iron was consistent with the data in the literature.
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In this refining process, an impurity element which has higher affinity for oxygen than iron was expected to be eliminated. As the result, decreases in Si, Mn, Al, Ca, Ga, and Zr were observed and 99.996 mass% of iron could be obtained from 99.93 mass% of electrolytic iron by plasma arc melting under oxidizing conditions followed by argon–hydrogen plasma arc melting. Specifically, the removal of Si was found to proceed by the distribution between in the liquid Fe phase and in the oxide phase. 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In this refining process, an impurity element which has higher affinity for oxygen than iron was expected to be eliminated. As the result, decreases in Si, Mn, Al, Ca, Ga, and Zr were observed and 99.996 mass% of iron could be obtained from 99.93 mass% of electrolytic iron by plasma arc melting under oxidizing conditions followed by argon–hydrogen plasma arc melting. Specifically, the removal of Si was found to proceed by the distribution between in the liquid Fe phase and in the oxide phase. 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In this refining process, an impurity element which has higher affinity for oxygen than iron was expected to be eliminated. As the result, decreases in Si, Mn, Al, Ca, Ga, and Zr were observed and 99.996 mass% of iron could be obtained from 99.93 mass% of electrolytic iron by plasma arc melting under oxidizing conditions followed by argon–hydrogen plasma arc melting. Specifically, the removal of Si was found to proceed by the distribution between in the liquid Fe phase and in the oxide phase. In addition, the relation of Si and oxygen concentration in liquid iron was consistent with the data in the literature.</abstract><cop>New York</cop><pub>Springer US</pub><doi>10.1007/s10853-008-2845-1</doi><tpages>6</tpages></addata></record>
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subjects Aluminum
Applied sciences
Argon
calcium
Characterization and Evaluation of Materials
Chemistry and Materials Science
Classical Mechanics
Crystallography and Scattering Methods
Electric arc melting
Exact sciences and technology
gallium
Hydrogen plasma
iron
Iron oxides
Manganese
Materials Science
melting
Metals. Metallurgy
oxidants
Oxidation
Oxidizing agents
oxygen
Plasma
Plasma arc melting
Polymer Sciences
Production of metals
Production of non ferrous metals. Process materials
Production of pure metals
Reagents
refining
Silicon
Solid Mechanics
Zirconium
title Oxidation refining of iron using plasma-arc melting
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