Synthesis of methyl benzoate by methoxycarbonylation of acetophenone with dimethyl carbonate over solid base catalysts
A convenient and simple route for synthesis of methyl benzoate from dimethyl carbonate and acetophenone has been exploited for the first time in the presence of solid base catalysts. The results showed that solid base with moderate strength, such as MgO, facilitated the formation of methyl benzoate...
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| Veröffentlicht in: | Fuel processing technology 2008-08, Vol.89 (8), p.803-807 |
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| container_title | Fuel processing technology |
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| creator | Wu, Dudu Chang, Wenming Wen, Xia Xiao, Fukui Li, Junping Zhao, Ning Wei, Wei Sun, Yuhan |
| description | A convenient and simple route for synthesis of methyl benzoate from dimethyl carbonate and acetophenone has been exploited for the first time in the presence of solid base catalysts. The results showed that solid base with moderate strength, such as MgO, facilitated the formation of methyl benzoate and the function of basic catalysts could mainly be attributed to the activation of ketone via the abstraction of H
α by base sites. |
| doi_str_mv | 10.1016/j.fuproc.2008.01.005 |
| format | Article |
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α by base sites.</description><identifier>ISSN: 0378-3820</identifier><identifier>EISSN: 1873-7188</identifier><identifier>DOI: 10.1016/j.fuproc.2008.01.005</identifier><identifier>CODEN: FPTEDY</identifier><language>eng</language><publisher>Amsterdam: Elsevier B.V</publisher><subject>Acetophenone ; Catalysis ; Chemistry ; Dimethyl carbonate ; Exact sciences and technology ; General and physical chemistry ; Methyl benzoate ; Solid base catalysts ; Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry</subject><ispartof>Fuel processing technology, 2008-08, Vol.89 (8), p.803-807</ispartof><rights>2008 Elsevier B.V.</rights><rights>2008 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c367t-1aa7860e01d59b0d29340719d2f1d510dd90865b50663a59afb517693891d74b3</citedby><cites>FETCH-LOGICAL-c367t-1aa7860e01d59b0d29340719d2f1d510dd90865b50663a59afb517693891d74b3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://www.sciencedirect.com/science/article/pii/S0378382008000180$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,776,780,3537,27901,27902,65306</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=20572946$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Wu, Dudu</creatorcontrib><creatorcontrib>Chang, Wenming</creatorcontrib><creatorcontrib>Wen, Xia</creatorcontrib><creatorcontrib>Xiao, Fukui</creatorcontrib><creatorcontrib>Li, Junping</creatorcontrib><creatorcontrib>Zhao, Ning</creatorcontrib><creatorcontrib>Wei, Wei</creatorcontrib><creatorcontrib>Sun, Yuhan</creatorcontrib><title>Synthesis of methyl benzoate by methoxycarbonylation of acetophenone with dimethyl carbonate over solid base catalysts</title><title>Fuel processing technology</title><description>A convenient and simple route for synthesis of methyl benzoate from dimethyl carbonate and acetophenone has been exploited for the first time in the presence of solid base catalysts. The results showed that solid base with moderate strength, such as MgO, facilitated the formation of methyl benzoate and the function of basic catalysts could mainly be attributed to the activation of ketone via the abstraction of H
α by base sites.</description><subject>Acetophenone</subject><subject>Catalysis</subject><subject>Chemistry</subject><subject>Dimethyl carbonate</subject><subject>Exact sciences and technology</subject><subject>General and physical chemistry</subject><subject>Methyl benzoate</subject><subject>Solid base catalysts</subject><subject>Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry</subject><issn>0378-3820</issn><issn>1873-7188</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2008</creationdate><recordtype>article</recordtype><recordid>eNp9kE1v3CAQhlHVSN0m-Qc5-JLe7Az2YuASqYr6ESlSDm3PCMNYy8oLG2C3dX992XjVY05Iw_O8o3kJuaHQUKD93bYZD_sYTNMCiAZoA8DekRUVvKs5FeI9WUHHRd2JFj6QjyltoRBM8hU5_ph93mByqQpjtcO8madqQP836IzVML-Owp_Z6DgEP086u-BPqDaYw36DPnisfru8qaw76wt78sMRY5XC5Gw16ITlJ-tpTjldkYtRTwmvz-8l-fX1y8-H7_XT87fHh89Ptel6nmuqNRc9IFDL5AC2ld0aOJW2HcuEgrUSRM8GBn3faSb1ODDKe9kJSS1fD90l-bTklnpeDpiy2rlkcJq0x3BIqsQVl_ECrhfQxJBSxFHto9vpOCsK6lSy2qqlZHUqWQFVpcKi3Z7zdTJ6GqP2xqX_bguMt3LdF-5-4bAce3QYVTIOvUHrIpqsbHBvL_oHAPqWyg</recordid><startdate>20080801</startdate><enddate>20080801</enddate><creator>Wu, Dudu</creator><creator>Chang, Wenming</creator><creator>Wen, Xia</creator><creator>Xiao, Fukui</creator><creator>Li, Junping</creator><creator>Zhao, Ning</creator><creator>Wei, Wei</creator><creator>Sun, Yuhan</creator><general>Elsevier B.V</general><general>Elsevier Science</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7TB</scope><scope>8FD</scope><scope>FR3</scope><scope>H8D</scope><scope>L7M</scope></search><sort><creationdate>20080801</creationdate><title>Synthesis of methyl benzoate by methoxycarbonylation of acetophenone with dimethyl carbonate over solid base catalysts</title><author>Wu, Dudu ; Chang, Wenming ; Wen, Xia ; Xiao, Fukui ; Li, Junping ; Zhao, Ning ; Wei, Wei ; Sun, Yuhan</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c367t-1aa7860e01d59b0d29340719d2f1d510dd90865b50663a59afb517693891d74b3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2008</creationdate><topic>Acetophenone</topic><topic>Catalysis</topic><topic>Chemistry</topic><topic>Dimethyl carbonate</topic><topic>Exact sciences and technology</topic><topic>General and physical chemistry</topic><topic>Methyl benzoate</topic><topic>Solid base catalysts</topic><topic>Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Wu, Dudu</creatorcontrib><creatorcontrib>Chang, Wenming</creatorcontrib><creatorcontrib>Wen, Xia</creatorcontrib><creatorcontrib>Xiao, Fukui</creatorcontrib><creatorcontrib>Li, Junping</creatorcontrib><creatorcontrib>Zhao, Ning</creatorcontrib><creatorcontrib>Wei, Wei</creatorcontrib><creatorcontrib>Sun, Yuhan</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Mechanical & Transportation Engineering Abstracts</collection><collection>Technology Research Database</collection><collection>Engineering Research Database</collection><collection>Aerospace Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Fuel processing technology</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Wu, Dudu</au><au>Chang, Wenming</au><au>Wen, Xia</au><au>Xiao, Fukui</au><au>Li, Junping</au><au>Zhao, Ning</au><au>Wei, Wei</au><au>Sun, Yuhan</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis of methyl benzoate by methoxycarbonylation of acetophenone with dimethyl carbonate over solid base catalysts</atitle><jtitle>Fuel processing technology</jtitle><date>2008-08-01</date><risdate>2008</risdate><volume>89</volume><issue>8</issue><spage>803</spage><epage>807</epage><pages>803-807</pages><issn>0378-3820</issn><eissn>1873-7188</eissn><coden>FPTEDY</coden><abstract>A convenient and simple route for synthesis of methyl benzoate from dimethyl carbonate and acetophenone has been exploited for the first time in the presence of solid base catalysts. The results showed that solid base with moderate strength, such as MgO, facilitated the formation of methyl benzoate and the function of basic catalysts could mainly be attributed to the activation of ketone via the abstraction of H
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| ispartof | Fuel processing technology, 2008-08, Vol.89 (8), p.803-807 |
| issn | 0378-3820 1873-7188 |
| language | eng |
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| source | Elsevier ScienceDirect Journals |
| subjects | Acetophenone Catalysis Chemistry Dimethyl carbonate Exact sciences and technology General and physical chemistry Methyl benzoate Solid base catalysts Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry |
| title | Synthesis of methyl benzoate by methoxycarbonylation of acetophenone with dimethyl carbonate over solid base catalysts |
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