Polymer Foams Stabilized by Particles Adsorbed at the Air/Polymer Interface

In aqueous systems, partially hydrophobic particles are known to stabilize foams even in the absence of any added surfactant. This paper shows that the same principle can be applied to polymeric systems: particles that are partially wetted by a polymer melt can stabilize a foam of that polymer. The...

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Veröffentlicht in:Macromolecular rapid communications. 2008-08, Vol.29 (15), p.1329-1334
Hauptverfasser: Thareja, Prachi, Ising, Brian P., Kingston, Samuel J., Velankar, Sachin S.
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container_issue 15
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container_title Macromolecular rapid communications.
container_volume 29
creator Thareja, Prachi
Ising, Brian P.
Kingston, Samuel J.
Velankar, Sachin S.
description In aqueous systems, partially hydrophobic particles are known to stabilize foams even in the absence of any added surfactant. This paper shows that the same principle can be applied to polymeric systems: particles that are partially wetted by a polymer melt can stabilize a foam of that polymer. The foam stability is attributable to the adsorption of the particles at the air/polymer interface. Remarkably, stable foams are realized even from polymers that are liquid at room temperature, and hence are otherwise unfoamable. The implications of this result to practical foaming operations are discussed.
doi_str_mv 10.1002/marc.200800262
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source Wiley Online Library Journals Frontfile Complete
subjects Applied sciences
Cellular
colloids
Exact sciences and technology
foams
Forms of application and semi-finished materials
interfacial tension
Pickering emulsion
Polymer industry, paints, wood
Technology of polymers
wettability
title Polymer Foams Stabilized by Particles Adsorbed at the Air/Polymer Interface
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