An anelastic spectroscopy, differential scanning calorimetry and X-ray diffraction study of the crystallization process of Mg–Ni–Fe alloys

The effects of heating-induced crystallization on the structural and mechanical properties of Mg–Ni–Fe amorphous ribbons were studied by anelastic spectroscopy, differential scanning calorimetry (DSC) and X-ray diffraction. DSC results show that the crystallization occurs through several non-reversi...

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Veröffentlicht in:Journal of alloys and compounds 2008-09, Vol.463 (1), p.148-152
Hauptverfasser: Palumbo, O., Paolone, A., Cantelli, R., Giannini, C., Gagliardi, A., Reale, P., Scrosati, B., Russo, S. Lo, Maddalena, A., Palade, P., Principi, G., Schinteie, G.
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container_end_page 152
container_issue 1
container_start_page 148
container_title Journal of alloys and compounds
container_volume 463
creator Palumbo, O.
Paolone, A.
Cantelli, R.
Giannini, C.
Gagliardi, A.
Reale, P.
Scrosati, B.
Russo, S. Lo
Maddalena, A.
Palade, P.
Principi, G.
Schinteie, G.
description The effects of heating-induced crystallization on the structural and mechanical properties of Mg–Ni–Fe amorphous ribbons were studied by anelastic spectroscopy, differential scanning calorimetry (DSC) and X-ray diffraction. DSC results show that the crystallization occurs through several non-reversible steps, which correspond to significant changes in the Young's modulus and concomitant irreversible elastic energy loss peaks. Moreover, an anelastic peak is found at 215 K, which for the first time indicates the presence of some dynamical process related to the simultaneous presence of different phases. The formation of a metastable Mg 6Ni phase is detected, which transforms into Mg and Mg 2Ni stable phases. A quantitative analysis of the different phases present at the different steps was also carried out.
doi_str_mv 10.1016/j.jallcom.2007.08.081
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subjects Cross-disciplinary physics: materials science
rheology
Crystal structure and symmetry
Exact sciences and technology
Growth from solid phases (including multiphase diffusion and recrystallization)
Materials science
Methods of crystal growth
physics of crystal growth
Physics
Thermal analysis
X-ray diffraction
title An anelastic spectroscopy, differential scanning calorimetry and X-ray diffraction study of the crystallization process of Mg–Ni–Fe alloys
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