Hydrothermal growth of Ti:sapphire (Ti 3+: Al 2O 3) laser crystals
Titanium(III)-doped sapphire single crystals (Ti 3+:Al 2O 3) have been grown by the hydrothermal technique for the first time. Due to Ti 3+ instability, Ti:sapphire could not easily be grown in alkaline solution. Instead, we grew the crystals in acidic solutions. The solubility of Ti 3+:Al 2O 3 in H...
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| Veröffentlicht in: | Journal of crystal growth 2009-01, Vol.311 (3), p.443-447 |
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| container_title | Journal of crystal growth |
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| creator | Wang, Buguo Bliss, David F. Callahan, Michael J. |
| description | Titanium(III)-doped sapphire single crystals (Ti
3+:Al
2O
3) have been grown by the hydrothermal technique for the first time. Due to Ti
3+ instability, Ti:sapphire could not easily be grown in alkaline solution. Instead, we grew the crystals in acidic solutions. The solubility of Ti
3+:Al
2O
3 in HCl hydrothermal solutions was found to exhibit a negative temperature coefficient. The grown crystals were characterized by X-ray diffraction, elemental analysis, and electron paramagnetic resonance (EPR). The results indicated that the grown crystals have a uniform distribution of Ti(III) (about 2×10
20
atoms/cc) and are of high quality. |
| doi_str_mv | 10.1016/j.jcrysgro.2008.09.052 |
| format | Article |
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3+:Al
2O
3) have been grown by the hydrothermal technique for the first time. Due to Ti
3+ instability, Ti:sapphire could not easily be grown in alkaline solution. Instead, we grew the crystals in acidic solutions. The solubility of Ti
3+:Al
2O
3 in HCl hydrothermal solutions was found to exhibit a negative temperature coefficient. The grown crystals were characterized by X-ray diffraction, elemental analysis, and electron paramagnetic resonance (EPR). The results indicated that the grown crystals have a uniform distribution of Ti(III) (about 2×10
20
atoms/cc) and are of high quality.</description><identifier>ISSN: 0022-0248</identifier><identifier>EISSN: 1873-5002</identifier><identifier>DOI: 10.1016/j.jcrysgro.2008.09.052</identifier><identifier>CODEN: JCRGAE</identifier><language>eng</language><publisher>Amsterdam: Elsevier B.V</publisher><subject>A2. Hydrothermal technique ; B1. Oxides ; B1. Ti:sapphire ; B3. Solid state lasers ; Condensed matter: structure, mechanical and thermal properties ; Cross-disciplinary physics: materials science; rheology ; Equations of state, phase equilibria, and phase transitions ; Exact sciences and technology ; Materials science ; Methods of crystal growth; physics of crystal growth ; Physics ; Solubility, segregation, and mixing; phase separation</subject><ispartof>Journal of crystal growth, 2009-01, Vol.311 (3), p.443-447</ispartof><rights>2008 Elsevier B.V.</rights><rights>2009 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c439t-d61c290c55ea91ebd85a5695b43b71b06f85e1714f930f94968d2a54524622593</citedby><cites>FETCH-LOGICAL-c439t-d61c290c55ea91ebd85a5695b43b71b06f85e1714f930f94968d2a54524622593</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.jcrysgro.2008.09.052$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>309,310,314,780,784,789,790,3541,23921,23922,25131,27915,27916,45986</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=21295920$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Wang, Buguo</creatorcontrib><creatorcontrib>Bliss, David F.</creatorcontrib><creatorcontrib>Callahan, Michael J.</creatorcontrib><title>Hydrothermal growth of Ti:sapphire (Ti 3+: Al 2O 3) laser crystals</title><title>Journal of crystal growth</title><description>Titanium(III)-doped sapphire single crystals (Ti
3+:Al
2O
3) have been grown by the hydrothermal technique for the first time. Due to Ti
3+ instability, Ti:sapphire could not easily be grown in alkaline solution. Instead, we grew the crystals in acidic solutions. The solubility of Ti
3+:Al
2O
3 in HCl hydrothermal solutions was found to exhibit a negative temperature coefficient. The grown crystals were characterized by X-ray diffraction, elemental analysis, and electron paramagnetic resonance (EPR). The results indicated that the grown crystals have a uniform distribution of Ti(III) (about 2×10
20
atoms/cc) and are of high quality.</description><subject>A2. Hydrothermal technique</subject><subject>B1. Oxides</subject><subject>B1. Ti:sapphire</subject><subject>B3. Solid state lasers</subject><subject>Condensed matter: structure, mechanical and thermal properties</subject><subject>Cross-disciplinary physics: materials science; rheology</subject><subject>Equations of state, phase equilibria, and phase transitions</subject><subject>Exact sciences and technology</subject><subject>Materials science</subject><subject>Methods of crystal growth; physics of crystal growth</subject><subject>Physics</subject><subject>Solubility, segregation, and mixing; phase separation</subject><issn>0022-0248</issn><issn>1873-5002</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2009</creationdate><recordtype>article</recordtype><recordid>eNqFkE9LwzAYxoMoOKdfQXJRFGl9kzRps5NzqBMGu8xzSNPUpXTrTDpl396MqVcv73N5_vD-ELokkBIg4r5JG-N34d13KQUoUpApcHqEBqTIWcIB6DEaxEsToFlxis5CaABiksAAPU53le_6pfUr3eLY8dUvcVfjhRsFvdksnbf4ZuEwuxvhcYvpHLNb3OpgPd6P9roN5-ikjmIvfnSI3p6fFpNpMpu_vE7Gs8RkTPZJJYihEgznVktiy6rgmgvJy4yVOSlB1AW3JCdZLRnUMpOiqKjmGaeZoJRLNkTXh96N7z62NvRq5YKxbavXttsGxVhOieAsGsXBaHwXgre12ni30n6nCKg9MtWoX2Rqj0yBVBFZDF79LOhgdFt7vTYu_KUpoZJLCtH3cPDZ-O6ns14F4-za2CriMr2qOvff1DeDy4JC</recordid><startdate>20090115</startdate><enddate>20090115</enddate><creator>Wang, Buguo</creator><creator>Bliss, David F.</creator><creator>Callahan, Michael J.</creator><general>Elsevier B.V</general><general>Elsevier</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7QF</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20090115</creationdate><title>Hydrothermal growth of Ti:sapphire (Ti 3+: Al 2O 3) laser crystals</title><author>Wang, Buguo ; Bliss, David F. ; Callahan, Michael J.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c439t-d61c290c55ea91ebd85a5695b43b71b06f85e1714f930f94968d2a54524622593</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2009</creationdate><topic>A2. Hydrothermal technique</topic><topic>B1. Oxides</topic><topic>B1. Ti:sapphire</topic><topic>B3. Solid state lasers</topic><topic>Condensed matter: structure, mechanical and thermal properties</topic><topic>Cross-disciplinary physics: materials science; rheology</topic><topic>Equations of state, phase equilibria, and phase transitions</topic><topic>Exact sciences and technology</topic><topic>Materials science</topic><topic>Methods of crystal growth; physics of crystal growth</topic><topic>Physics</topic><topic>Solubility, segregation, and mixing; phase separation</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Wang, Buguo</creatorcontrib><creatorcontrib>Bliss, David F.</creatorcontrib><creatorcontrib>Callahan, Michael J.</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Aluminium Industry Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Journal of crystal growth</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Wang, Buguo</au><au>Bliss, David F.</au><au>Callahan, Michael J.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Hydrothermal growth of Ti:sapphire (Ti 3+: Al 2O 3) laser crystals</atitle><jtitle>Journal of crystal growth</jtitle><date>2009-01-15</date><risdate>2009</risdate><volume>311</volume><issue>3</issue><spage>443</spage><epage>447</epage><pages>443-447</pages><issn>0022-0248</issn><eissn>1873-5002</eissn><coden>JCRGAE</coden><abstract>Titanium(III)-doped sapphire single crystals (Ti
3+:Al
2O
3) have been grown by the hydrothermal technique for the first time. Due to Ti
3+ instability, Ti:sapphire could not easily be grown in alkaline solution. Instead, we grew the crystals in acidic solutions. The solubility of Ti
3+:Al
2O
3 in HCl hydrothermal solutions was found to exhibit a negative temperature coefficient. The grown crystals were characterized by X-ray diffraction, elemental analysis, and electron paramagnetic resonance (EPR). The results indicated that the grown crystals have a uniform distribution of Ti(III) (about 2×10
20
atoms/cc) and are of high quality.</abstract><cop>Amsterdam</cop><pub>Elsevier B.V</pub><doi>10.1016/j.jcrysgro.2008.09.052</doi><tpages>5</tpages></addata></record> |
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| ispartof | Journal of crystal growth, 2009-01, Vol.311 (3), p.443-447 |
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| language | eng |
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| source | ScienceDirect Journals (5 years ago - present) |
| subjects | A2. Hydrothermal technique B1. Oxides B1. Ti:sapphire B3. Solid state lasers Condensed matter: structure, mechanical and thermal properties Cross-disciplinary physics: materials science rheology Equations of state, phase equilibria, and phase transitions Exact sciences and technology Materials science Methods of crystal growth physics of crystal growth Physics Solubility, segregation, and mixing phase separation |
| title | Hydrothermal growth of Ti:sapphire (Ti 3+: Al 2O 3) laser crystals |
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