G ′ band Raman spectra of single, double and triple layer graphene

We have measured the Raman spectra of one to three layer graphene as a function of laser excitation energy. The observed G ′ band Raman peak (∼2650 cm −1) intensity decreases with increasing numbers of graphene layers. The electronic energy band structure calculated by the extended tight binding mod...

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Veröffentlicht in:Carbon (New York) 2009-04, Vol.47 (5), p.1303-1310
Hauptverfasser: Park, J.S., Reina, A., Saito, R., Kong, J., Dresselhaus, G., Dresselhaus, M.S.
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container_end_page 1310
container_issue 5
container_start_page 1303
container_title Carbon (New York)
container_volume 47
creator Park, J.S.
Reina, A.
Saito, R.
Kong, J.
Dresselhaus, G.
Dresselhaus, M.S.
description We have measured the Raman spectra of one to three layer graphene as a function of laser excitation energy. The observed G ′ band Raman peak (∼2650 cm −1) intensity decreases with increasing numbers of graphene layers. The electronic energy band structure calculated by the extended tight binding model shows that there are four and nine possible optical processes in double resonance theory for the Raman G ′ band of double and triple layers graphene, respectively. Raman intensity calculations show that each peak position depends on its wavevector, and then the G ′ band of double and triple layer graphene has three and five components, respectively.
doi_str_mv 10.1016/j.carbon.2009.01.009
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subjects Cross-disciplinary physics: materials science
rheology
Exact sciences and technology
Fullerenes and related materials
diamonds, graphite
Materials science
Physics
Specific materials
title G ′ band Raman spectra of single, double and triple layer graphene
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