Efficient Cross‐Coupling Reactions of Nitrogen Nucleophiles with Aryl Halides in Water
A facile and practical strategy has been developed for the N‐arylation of nitrogen nucleophiles with aryl halides catalyzed by a combination of iron(III) chloride [FeCl3] and dimethylethylenediamine (dmeda) in water. A variety of nitrogen nucleophiles including pyrazole, indole, 7‐azaindole and benz...
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| Veröffentlicht in: | Advanced synthesis & catalysis 2009-03, Vol.351 (5), p.720-724 |
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| container_title | Advanced synthesis & catalysis |
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| creator | Teo, Yong‐Chua |
| description | A facile and practical strategy has been developed for the N‐arylation of nitrogen nucleophiles with aryl halides catalyzed by a combination of iron(III) chloride [FeCl3] and dimethylethylenediamine (dmeda) in water. A variety of nitrogen nucleophiles including pyrazole, indole, 7‐azaindole and benzamide afforded the N‐arylated products in the presence of the catalytic system (in up to 88% yield). |
| doi_str_mv | 10.1002/adsc.200800746 |
| format | Article |
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| ispartof | Advanced synthesis & catalysis, 2009-03, Vol.351 (5), p.720-724 |
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| source | Wiley Online Library |
| subjects | arylation cross‐coupling heterogeneous catalysis iron water |
| title | Efficient Cross‐Coupling Reactions of Nitrogen Nucleophiles with Aryl Halides in Water |
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