The dependence of the synthesis condition on the dielectric behaviors of the 0.75Pb(Fe2/3W1/3)O3-0.25PbTiO3 based ceramics

In this paper, 0.75Pb(Fe2/3W1/3)O3-0.25PbTiO3-0.15 wt%MnO (0.75PFW-0.25PT-0.15 wt%MO) ceramics are synthesized by combining the conventional direct oxide synthesized (DS) method and the indirect synthesized (IS) method. Due to the IS method, the lattice structure and the grain structure of the 0.75P...

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Veröffentlicht in:Journal of alloys and compounds 2008-07, Vol.459 (1-2), p.328-332
Hauptverfasser: HONG, Cheng-Shong, CHU, Sheng-Yuan, SU, Wen-Chang, CHANG, Ren-Chuan, NIEN, Hsiau-Hsian, JUANG, Yung-Der
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container_end_page 332
container_issue 1-2
container_start_page 328
container_title Journal of alloys and compounds
container_volume 459
creator HONG, Cheng-Shong
CHU, Sheng-Yuan
SU, Wen-Chang
CHANG, Ren-Chuan
NIEN, Hsiau-Hsian
JUANG, Yung-Der
description In this paper, 0.75Pb(Fe2/3W1/3)O3-0.25PbTiO3-0.15 wt%MnO (0.75PFW-0.25PT-0.15 wt%MO) ceramics are synthesized by combining the conventional direct oxide synthesized (DS) method and the indirect synthesized (IS) method. Due to the IS method, the lattice structure and the grain structure of the 0.75PFW-0.25PT-0.15 wt%MO ceramics are changed. Furthermore, the low-field dielectric responses are evidently modified such as follows: (1) the broad dielectric peak becomes sharper; (2) in the paraelectric region, the space charge polarization is eliminated; (3) the frequency dispersion of the dielectric constant is suppressed; (4) the dielectric loss is effectively decreased in both the ferroelectric and paraelectric regions. In conclusion, the dielectric characteristics of the 0.75PFW-0.25PT-0.15 wt%MO ceramics synthesized by the IS method are trend to the long range order (LRO) ferroelectric behaviors.
doi_str_mv 10.1016/j.jallcom.2007.04.251
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Due to the IS method, the lattice structure and the grain structure of the 0.75PFW-0.25PT-0.15 wt%MO ceramics are changed. Furthermore, the low-field dielectric responses are evidently modified such as follows: (1) the broad dielectric peak becomes sharper; (2) in the paraelectric region, the space charge polarization is eliminated; (3) the frequency dispersion of the dielectric constant is suppressed; (4) the dielectric loss is effectively decreased in both the ferroelectric and paraelectric regions. 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Due to the IS method, the lattice structure and the grain structure of the 0.75PFW-0.25PT-0.15 wt%MO ceramics are changed. Furthermore, the low-field dielectric responses are evidently modified such as follows: (1) the broad dielectric peak becomes sharper; (2) in the paraelectric region, the space charge polarization is eliminated; (3) the frequency dispersion of the dielectric constant is suppressed; (4) the dielectric loss is effectively decreased in both the ferroelectric and paraelectric regions. 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subjects Condensed matter: electronic structure, electrical, magnetic, and optical properties
Dielectric properties of solids and liquids
Dielectrics, piezoelectrics, and ferroelectrics and their properties
Exact sciences and technology
Physics
title The dependence of the synthesis condition on the dielectric behaviors of the 0.75Pb(Fe2/3W1/3)O3-0.25PbTiO3 based ceramics
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