Novel hydrophobic/hydrophilic patterning process by photocatalytic Ag nucleation on TiO2 thin film and electroless Cu deposition

A hydrophobic/er-hydrophilic pattern was prepared on a TiO2 thin film by a new fabrication process. The process consists of five key steps: (1) photocatalytic reduction of Ag+ to Ag (nucleation), (2) electroless Cu deposition, (3) oxidation of Cu to CuO, (4) deposition of a self-assembled monolayer...

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Veröffentlicht in:Applied surface science 2008-07, Vol.254 (18), p.5891-5894
Hauptverfasser: NISHIMOTO, Shunsuke, KUBO, Atsushi, XINTONG ZHANG, ZHAOYUE LIU, TANEICHI, Noriaki, OKUI, Toshiki, MURAKAMI, Taketoshi, KOMINE, Takashi, FUJISHIMA, Akira
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container_end_page 5894
container_issue 18
container_start_page 5891
container_title Applied surface science
container_volume 254
creator NISHIMOTO, Shunsuke
KUBO, Atsushi
XINTONG ZHANG
ZHAOYUE LIU
TANEICHI, Noriaki
OKUI, Toshiki
MURAKAMI, Taketoshi
KOMINE, Takashi
FUJISHIMA, Akira
description A hydrophobic/er-hydrophilic pattern was prepared on a TiO2 thin film by a new fabrication process. The process consists of five key steps: (1) photocatalytic reduction of Ag+ to Ag (nucleation), (2) electroless Cu deposition, (3) oxidation of Cu to CuO, (4) deposition of a self-assembled monolayer (SAM), and (5) photocatalytic decomposition of selected areas of the SAM. A hydrophobic/er-hydrophilic pattern with 500-mum2 hydrophilic areas was obtained in this process. It is particularly noteworthy that a UV irradiation time of only 1 s was sufficient for the nucleation step in the patterning process.
doi_str_mv 10.1016/j.apsusc.2008.03.153
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subjects Catalytic methods
Cross-disciplinary physics: materials science
rheology
Exact sciences and technology
Materials science
Methods of nanofabrication
Physics
Surface cleaning, etching, patterning
Surface treatments
title Novel hydrophobic/hydrophilic patterning process by photocatalytic Ag nucleation on TiO2 thin film and electroless Cu deposition
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