MCM-41-supported ruthenium carbonyl cluster-derived catalysts for asymmetric hydrogenation reactions

Under optimal conditions the hydrogenations of methyl pyruvate and acetophenone by 1 give enantioselectivities of ≤75% and ≤30%, respectively. The enantioselectivity of 1 towards methyl pyruvate hydrogenation is retained even with a relatively high turnover. ▪ The anionic ruthenium carbonyl cluster...

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Veröffentlicht in:	Applied catalysis. A, General General, 2008-07, Vol.344 (1), p.124-130
Hauptverfasser:	Indra, Arindam, Basu, Susmit, Kulkarni, Dhanashree G., Gopinath, Chinnakonda S., Bhaduri, Sumit, Lahiri, Goutam Kumar
Format:	Artikel
Sprache:	eng
Schlagworte:	Asymmetric catalysis Catalysis Chemistry Colloidal state and disperse state Exact sciences and technology Functionalized MCM-41 General and physical chemistry Hydrogenation catalysts Nanocatalyst Porous materials Ruthenium carbonyl cluster Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry
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