Dissolved oxygen control and monitoring implementation in the liquid lead–bismuth eutectic loop: HELIOS
A 12 m tall LBE coolant loop, named as HELIOS, has been developed by thermal-hydraulic scaling of the PEACER-300MWe. Thermo-hydraulic experiment and materials test are the principal purposes of HELIOS operation. In this study, an yttria stabilized zirconia (YSZ) based oxygen sensor that was hermetic...
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Veröffentlicht in: | Journal of nuclear materials 2008-06, Vol.376 (3), p.381-385 |
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Format: | Artikel |
Sprache: | eng |
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Zusammenfassung: | A 12
m tall LBE coolant loop, named as HELIOS, has been developed by thermal-hydraulic scaling of the PEACER-300MWe. Thermo-hydraulic experiment and materials test are the principal purposes of HELIOS operation. In this study, an yttria stabilized zirconia (YSZ) based oxygen sensor that was hermetically sealed for long-term applications using the electromagnetically swaged metal–ceramic joining method, have been developed for high temperature oxygen control application over a long period of time. The rugged electrode design has been calibrated to absolute metal–oxide equilibrium by using a first principle of detecting pure metal–oxide transition using electrochemical impedance spectroscopy (EIS). During the materials tests in HELIOS, dissolved oxygen concentration was administered at the intended condition of 10
−6
wt% by direct gas bubbling with Ar
+
4%H
2, Ar
+
5%O
2 and/or pure Ar while corrosion tests were conducted for up to 1000
h with inspection after each 333
h. During the total 1000
h corrosion test, oxygen concentration was measured by oxygen sensor. The result confirmed that the direct gas bubbling method is a viable and practical option for controlling oxygen concentration in large loops including HELIOS. |
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ISSN: | 0022-3115 1873-4820 |
DOI: | 10.1016/j.jnucmat.2008.02.038 |