IR and NMR time-resolved studies on the hydrolysis and condensation of methacryloxyalkylsilanes
The sol–gel reactions of the two methacrylate-modified silanes methacryloxymethyltriethoxysilane (MAMTES) and methacryloxypropyltrimethoxysilane (MAPTMS) were followed by using two independent time-resolved spectroscopic methods, viz., IR ATR and NMR with the aim to optimise their pre-hydrolysis tim...
Gespeichert in:
| Veröffentlicht in: | Journal of sol-gel science and technology 2009-03, Vol.49 (3), p.329-335 |
|---|---|
| Hauptverfasser: | , , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 335 |
|---|---|
| container_issue | 3 |
| container_start_page | 329 |
| container_title | Journal of sol-gel science and technology |
| container_volume | 49 |
| creator | Lavrencic Stangar, Urska Sassi, Alessandro Venzo, Alfonso Zattin, Andrea Japelj, Boštjan Orel, Boris Gross, Silvia |
| description | The sol–gel reactions of the two methacrylate-modified silanes methacryloxymethyltriethoxysilane (MAMTES) and methacryloxypropyltrimethoxysilane (MAPTMS) were followed by using two independent time-resolved spectroscopic methods, viz., IR ATR and NMR with the aim to optimise their pre-hydrolysis times and consequently their use as precursors for hybrid materials. Time resolved measurements were carried out on the two systems under sol–gel conditions. Whereas the hydrolysis of both siloxanes is very fast, condensation proceeds gradually and is not completely finished within 5 h. |
| doi_str_mv | 10.1007/s10971-008-1882-1 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_33477403</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>33477403</sourcerecordid><originalsourceid>FETCH-LOGICAL-c377t-2fee67a680ad580f895e99c6bf68c0604c1dce5a2c908c3b53d9b53413d85c9c3</originalsourceid><addsrcrecordid>eNp1kEFrFTEUhUNR6LP1B7gbKHUXvUkmk2RZiraFaqHYdUiTO76peZM2d544_77zfEVBcHPv4nzncDiMvRPwQQCYjyTAGcEBLBfWSi4O2Epoo3hr2-4VW4GTloMBc8jeED0AgG6FWTF_dduEMTVfv9w207BBXpFK_ompoWmbBqSmjM20xmY9p1ryTAP95mMZE44UpmHRS99scFqHWOdcfs0h_5gzDTmMSMfsdR8y4duXf8TuPn_6dn7Jr28urs7PrnlUxkxc9oidCZ2FkLSF3jqNzsXuvu9shA7aKFJEHWR0YKO61yq55bRCJauji-qIvd_nPtbytEWa_GagiHlXomzJK9Ua04JawJN_wIeyrePSzUupne5cq8VCiT0VayGq2PvHOmxCnb0Avxvc7wf3y-B-N7jfeU5fkgPFkPsaxjjQH6OUFjqnYOHknqNFGr9j_dvg_-HPKHyQ3A</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2259569451</pqid></control><display><type>article</type><title>IR and NMR time-resolved studies on the hydrolysis and condensation of methacryloxyalkylsilanes</title><source>SpringerLink</source><creator>Lavrencic Stangar, Urska ; Sassi, Alessandro ; Venzo, Alfonso ; Zattin, Andrea ; Japelj, Boštjan ; Orel, Boris ; Gross, Silvia</creator><creatorcontrib>Lavrencic Stangar, Urska ; Sassi, Alessandro ; Venzo, Alfonso ; Zattin, Andrea ; Japelj, Boštjan ; Orel, Boris ; Gross, Silvia</creatorcontrib><description>The sol–gel reactions of the two methacrylate-modified silanes methacryloxymethyltriethoxysilane (MAMTES) and methacryloxypropyltrimethoxysilane (MAPTMS) were followed by using two independent time-resolved spectroscopic methods, viz., IR ATR and NMR with the aim to optimise their pre-hydrolysis times and consequently their use as precursors for hybrid materials. Time resolved measurements were carried out on the two systems under sol–gel conditions. Whereas the hydrolysis of both siloxanes is very fast, condensation proceeds gradually and is not completely finished within 5 h.</description><identifier>ISSN: 0928-0707</identifier><identifier>EISSN: 1573-4846</identifier><identifier>DOI: 10.1007/s10971-008-1882-1</identifier><language>eng</language><publisher>Boston: Springer US</publisher><subject>Ceramics ; Chemistry ; Chemistry and Materials Science ; Colloidal gels. Colloidal sols ; Colloidal state and disperse state ; Composites ; Condensation ; Exact sciences and technology ; General and physical chemistry ; Glass ; Hydrolysis ; Inorganic Chemistry ; Materials Science ; Nanotechnology ; Natural Materials ; NMR ; Nuclear magnetic resonance ; Optical and Electronic Materials ; Original Paper ; Silanes ; Siloxanes ; Sol-gel processes</subject><ispartof>Journal of sol-gel science and technology, 2009-03, Vol.49 (3), p.329-335</ispartof><rights>Springer Science+Business Media, LLC 2009</rights><rights>2015 INIST-CNRS</rights><rights>Journal of Sol-Gel Science and Technology is a copyright of Springer, (2009). All Rights Reserved.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c377t-2fee67a680ad580f895e99c6bf68c0604c1dce5a2c908c3b53d9b53413d85c9c3</citedby><cites>FETCH-LOGICAL-c377t-2fee67a680ad580f895e99c6bf68c0604c1dce5a2c908c3b53d9b53413d85c9c3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10971-008-1882-1$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10971-008-1882-1$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=22806930$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Lavrencic Stangar, Urska</creatorcontrib><creatorcontrib>Sassi, Alessandro</creatorcontrib><creatorcontrib>Venzo, Alfonso</creatorcontrib><creatorcontrib>Zattin, Andrea</creatorcontrib><creatorcontrib>Japelj, Boštjan</creatorcontrib><creatorcontrib>Orel, Boris</creatorcontrib><creatorcontrib>Gross, Silvia</creatorcontrib><title>IR and NMR time-resolved studies on the hydrolysis and condensation of methacryloxyalkylsilanes</title><title>Journal of sol-gel science and technology</title><addtitle>J Sol-Gel Sci Technol</addtitle><description>The sol–gel reactions of the two methacrylate-modified silanes methacryloxymethyltriethoxysilane (MAMTES) and methacryloxypropyltrimethoxysilane (MAPTMS) were followed by using two independent time-resolved spectroscopic methods, viz., IR ATR and NMR with the aim to optimise their pre-hydrolysis times and consequently their use as precursors for hybrid materials. Time resolved measurements were carried out on the two systems under sol–gel conditions. Whereas the hydrolysis of both siloxanes is very fast, condensation proceeds gradually and is not completely finished within 5 h.</description><subject>Ceramics</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Colloidal gels. Colloidal sols</subject><subject>Colloidal state and disperse state</subject><subject>Composites</subject><subject>Condensation</subject><subject>Exact sciences and technology</subject><subject>General and physical chemistry</subject><subject>Glass</subject><subject>Hydrolysis</subject><subject>Inorganic Chemistry</subject><subject>Materials Science</subject><subject>Nanotechnology</subject><subject>Natural Materials</subject><subject>NMR</subject><subject>Nuclear magnetic resonance</subject><subject>Optical and Electronic Materials</subject><subject>Original Paper</subject><subject>Silanes</subject><subject>Siloxanes</subject><subject>Sol-gel processes</subject><issn>0928-0707</issn><issn>1573-4846</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2009</creationdate><recordtype>article</recordtype><sourceid>BENPR</sourceid><recordid>eNp1kEFrFTEUhUNR6LP1B7gbKHUXvUkmk2RZiraFaqHYdUiTO76peZM2d544_77zfEVBcHPv4nzncDiMvRPwQQCYjyTAGcEBLBfWSi4O2Epoo3hr2-4VW4GTloMBc8jeED0AgG6FWTF_dduEMTVfv9w207BBXpFK_ompoWmbBqSmjM20xmY9p1ryTAP95mMZE44UpmHRS99scFqHWOdcfs0h_5gzDTmMSMfsdR8y4duXf8TuPn_6dn7Jr28urs7PrnlUxkxc9oidCZ2FkLSF3jqNzsXuvu9shA7aKFJEHWR0YKO61yq55bRCJauji-qIvd_nPtbytEWa_GagiHlXomzJK9Ua04JawJN_wIeyrePSzUupne5cq8VCiT0VayGq2PvHOmxCnb0Avxvc7wf3y-B-N7jfeU5fkgPFkPsaxjjQH6OUFjqnYOHknqNFGr9j_dvg_-HPKHyQ3A</recordid><startdate>20090301</startdate><enddate>20090301</enddate><creator>Lavrencic Stangar, Urska</creator><creator>Sassi, Alessandro</creator><creator>Venzo, Alfonso</creator><creator>Zattin, Andrea</creator><creator>Japelj, Boštjan</creator><creator>Orel, Boris</creator><creator>Gross, Silvia</creator><general>Springer US</general><general>Springer</general><general>Springer Nature B.V</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>KB.</scope><scope>L6V</scope><scope>M7S</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><scope>PTHSS</scope><scope>7U5</scope><scope>8FD</scope><scope>L7M</scope></search><sort><creationdate>20090301</creationdate><title>IR and NMR time-resolved studies on the hydrolysis and condensation of methacryloxyalkylsilanes</title><author>Lavrencic Stangar, Urska ; Sassi, Alessandro ; Venzo, Alfonso ; Zattin, Andrea ; Japelj, Boštjan ; Orel, Boris ; Gross, Silvia</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c377t-2fee67a680ad580f895e99c6bf68c0604c1dce5a2c908c3b53d9b53413d85c9c3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2009</creationdate><topic>Ceramics</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Colloidal gels. Colloidal sols</topic><topic>Colloidal state and disperse state</topic><topic>Composites</topic><topic>Condensation</topic><topic>Exact sciences and technology</topic><topic>General and physical chemistry</topic><topic>Glass</topic><topic>Hydrolysis</topic><topic>Inorganic Chemistry</topic><topic>Materials Science</topic><topic>Nanotechnology</topic><topic>Natural Materials</topic><topic>NMR</topic><topic>Nuclear magnetic resonance</topic><topic>Optical and Electronic Materials</topic><topic>Original Paper</topic><topic>Silanes</topic><topic>Siloxanes</topic><topic>Sol-gel processes</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Lavrencic Stangar, Urska</creatorcontrib><creatorcontrib>Sassi, Alessandro</creatorcontrib><creatorcontrib>Venzo, Alfonso</creatorcontrib><creatorcontrib>Zattin, Andrea</creatorcontrib><creatorcontrib>Japelj, Boštjan</creatorcontrib><creatorcontrib>Orel, Boris</creatorcontrib><creatorcontrib>Gross, Silvia</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central</collection><collection>SciTech Premium Collection</collection><collection>ProQuest Materials Science Database</collection><collection>ProQuest Engineering Collection</collection><collection>ProQuest Engineering Database</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><collection>Engineering collection</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Technology Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Journal of sol-gel science and technology</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Lavrencic Stangar, Urska</au><au>Sassi, Alessandro</au><au>Venzo, Alfonso</au><au>Zattin, Andrea</au><au>Japelj, Boštjan</au><au>Orel, Boris</au><au>Gross, Silvia</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>IR and NMR time-resolved studies on the hydrolysis and condensation of methacryloxyalkylsilanes</atitle><jtitle>Journal of sol-gel science and technology</jtitle><stitle>J Sol-Gel Sci Technol</stitle><date>2009-03-01</date><risdate>2009</risdate><volume>49</volume><issue>3</issue><spage>329</spage><epage>335</epage><pages>329-335</pages><issn>0928-0707</issn><eissn>1573-4846</eissn><abstract>The sol–gel reactions of the two methacrylate-modified silanes methacryloxymethyltriethoxysilane (MAMTES) and methacryloxypropyltrimethoxysilane (MAPTMS) were followed by using two independent time-resolved spectroscopic methods, viz., IR ATR and NMR with the aim to optimise their pre-hydrolysis times and consequently their use as precursors for hybrid materials. Time resolved measurements were carried out on the two systems under sol–gel conditions. Whereas the hydrolysis of both siloxanes is very fast, condensation proceeds gradually and is not completely finished within 5 h.</abstract><cop>Boston</cop><pub>Springer US</pub><doi>10.1007/s10971-008-1882-1</doi><tpages>7</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0928-0707 |
| ispartof | Journal of sol-gel science and technology, 2009-03, Vol.49 (3), p.329-335 |
| issn | 0928-0707 1573-4846 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_33477403 |
| source | SpringerLink |
| subjects | Ceramics Chemistry Chemistry and Materials Science Colloidal gels. Colloidal sols Colloidal state and disperse state Composites Condensation Exact sciences and technology General and physical chemistry Glass Hydrolysis Inorganic Chemistry Materials Science Nanotechnology Natural Materials NMR Nuclear magnetic resonance Optical and Electronic Materials Original Paper Silanes Siloxanes Sol-gel processes |
| title | IR and NMR time-resolved studies on the hydrolysis and condensation of methacryloxyalkylsilanes |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-02-07T17%3A28%3A41IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=IR%20and%20NMR%20time-resolved%20studies%20on%20the%20hydrolysis%20and%20condensation%20of%20methacryloxyalkylsilanes&rft.jtitle=Journal%20of%20sol-gel%20science%20and%20technology&rft.au=Lavrencic%20Stangar,%20Urska&rft.date=2009-03-01&rft.volume=49&rft.issue=3&rft.spage=329&rft.epage=335&rft.pages=329-335&rft.issn=0928-0707&rft.eissn=1573-4846&rft_id=info:doi/10.1007/s10971-008-1882-1&rft_dat=%3Cproquest_cross%3E33477403%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2259569451&rft_id=info:pmid/&rfr_iscdi=true |