PAN-based fibers modified with two-component ceramic nanoparticles

The authors determined conditions for manufacturing PAN precursor fibers containing a system of two nanoadditives, montmorillonite (MMT), and hydroxyapatite (HAp) in their structure. The PAN precursor fibers thus obtained are characterized by a tenacity of more than 30 cN/tex and a total volume of p...

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Veröffentlicht in:Journal of applied polymer science 2009-05, Vol.112 (4), p.2343-2350
Hauptverfasser: BOGUN, Maciej, MIKOLAJCZYK, Teresa
Format: Artikel
Sprache:eng
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Zusammenfassung:The authors determined conditions for manufacturing PAN precursor fibers containing a system of two nanoadditives, montmorillonite (MMT), and hydroxyapatite (HAp) in their structure. The PAN precursor fibers thus obtained are characterized by a tenacity of more than 30 cN/tex and a total volume of pores at the level of 0.29 cm³/g. Furthermore, it was found that the use of nanoadditives entails the remodeling of the paracrystalline structure of PAN fibers into a strictly crystalline one. This is accompanied by a decrease in spacing between MMT layers combined with their partial exfoliation. The fibers thus obtained, after being carbonized, will be used for medical applications.
ISSN:0021-8995
1097-4628
DOI:10.1002/app.29608