A new luminol derivative as a fluorescent probe for trace analysis of copper(II)
A new luminol derivative has been synthesized and its fluorescence has been studied. The luminol derivative emits at 460 nm in pH 10.0 phosphate buffer which is different from the original luminol that emits at 425 nm under the same conditions. Cu 2+ exhibits strong fluorescence quenching effect on...
Gespeichert in:
| Veröffentlicht in: | Mikrochimica acta (1966) 2009-03, Vol.164 (3-4), p.411-417 |
|---|---|
| Hauptverfasser: | , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 417 |
|---|---|
| container_issue | 3-4 |
| container_start_page | 411 |
| container_title | Mikrochimica acta (1966) |
| container_volume | 164 |
| creator | Luo, Yun Li, Yi Lv, Baoqiang Zhou, Zaide Xiao, Dan Choi, Martin M. F. |
| description | A new luminol derivative has been synthesized and its fluorescence has been studied. The luminol derivative emits at 460 nm in pH 10.0 phosphate buffer which is different from the original luminol that emits at 425 nm under the same conditions. Cu
2+
exhibits strong fluorescence quenching effect on the luminol derivative and the quenching mechanism is discussed in detail. This luminol derivative can be applied as a fluorescent probe for ultra-trace analysis of Cu
2+
. The effects of pH, interferents and the stability have also been investigated. The fluorescent probe shows good reproducibility, and the relative standard deviation of response to Cu
2+
is 0.7% (
n
= 6). The lower linear range and the limit of detection are 0–500 and 0.27 nmol L
−1
, respectively. |
| doi_str_mv | 10.1007/s00604-008-0076-4 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_33380859</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>33380859</sourcerecordid><originalsourceid>FETCH-LOGICAL-c349t-45cd4899ec586ccac340f315e8e8ce8d03afadb0e3fb0c7115dcff6cd08eff4a3</originalsourceid><addsrcrecordid>eNp9kE1LAzEQhoMoWKs_wFsuih5WJ5vsbvZYih-Fgh70HNLsRLakmzXZrfTfm9Li0cMwMPPMy_AQcs3ggQFUjxGgBJEByFRVmYkTMmGCl1kBFT8lE4C8zHhZ5efkIsY1AKvKXEzI-4x2-EPduGk772iDod3qod0i1ZFqat3oA0aD3UD74FdIrQ90CNokoNNuF9tIvaXG9z2Gu8Xi_pKcWe0iXh37lHw-P33MX7Pl28tiPltmhot6yERhGiHrGk0hS2N0moLlrECJ0qBsgGurmxUgtyswFWNFY6wtTQMSrRWaT8ntITe99T1iHNSmTX86pzv0Y1SccwmyqBPIDqAJPsaAVvWh3eiwUwzU3p06uFPJndq7UyLd3BzDdTTa2aA708a_w5zxuk5GE5cfuJhW3RcGtfZjSF7iP-G_39R_cg</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>33380859</pqid></control><display><type>article</type><title>A new luminol derivative as a fluorescent probe for trace analysis of copper(II)</title><source>SpringerLink Journals</source><creator>Luo, Yun ; Li, Yi ; Lv, Baoqiang ; Zhou, Zaide ; Xiao, Dan ; Choi, Martin M. F.</creator><creatorcontrib>Luo, Yun ; Li, Yi ; Lv, Baoqiang ; Zhou, Zaide ; Xiao, Dan ; Choi, Martin M. F.</creatorcontrib><description>A new luminol derivative has been synthesized and its fluorescence has been studied. The luminol derivative emits at 460 nm in pH 10.0 phosphate buffer which is different from the original luminol that emits at 425 nm under the same conditions. Cu
2+
exhibits strong fluorescence quenching effect on the luminol derivative and the quenching mechanism is discussed in detail. This luminol derivative can be applied as a fluorescent probe for ultra-trace analysis of Cu
2+
. The effects of pH, interferents and the stability have also been investigated. The fluorescent probe shows good reproducibility, and the relative standard deviation of response to Cu
2+
is 0.7% (
n
= 6). The lower linear range and the limit of detection are 0–500 and 0.27 nmol L
−1
, respectively.</description><identifier>ISSN: 0026-3672</identifier><identifier>EISSN: 1436-5073</identifier><identifier>DOI: 10.1007/s00604-008-0076-4</identifier><identifier>CODEN: MIACAQ</identifier><language>eng</language><publisher>Vienna: Springer Vienna</publisher><subject>Analytical Chemistry ; Characterization and Evaluation of Materials ; Chemistry ; Chemistry and Materials Science ; Exact sciences and technology ; Microengineering ; Nanochemistry ; Nanotechnology ; Original Paper ; Spectrometric and optical methods</subject><ispartof>Mikrochimica acta (1966), 2009-03, Vol.164 (3-4), p.411-417</ispartof><rights>Springer-Verlag 2008</rights><rights>2009 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c349t-45cd4899ec586ccac340f315e8e8ce8d03afadb0e3fb0c7115dcff6cd08eff4a3</citedby><cites>FETCH-LOGICAL-c349t-45cd4899ec586ccac340f315e8e8ce8d03afadb0e3fb0c7115dcff6cd08eff4a3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s00604-008-0076-4$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s00604-008-0076-4$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,778,782,27907,27908,41471,42540,51302</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=21399002$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Luo, Yun</creatorcontrib><creatorcontrib>Li, Yi</creatorcontrib><creatorcontrib>Lv, Baoqiang</creatorcontrib><creatorcontrib>Zhou, Zaide</creatorcontrib><creatorcontrib>Xiao, Dan</creatorcontrib><creatorcontrib>Choi, Martin M. F.</creatorcontrib><title>A new luminol derivative as a fluorescent probe for trace analysis of copper(II)</title><title>Mikrochimica acta (1966)</title><addtitle>Microchim Acta</addtitle><description>A new luminol derivative has been synthesized and its fluorescence has been studied. The luminol derivative emits at 460 nm in pH 10.0 phosphate buffer which is different from the original luminol that emits at 425 nm under the same conditions. Cu
2+
exhibits strong fluorescence quenching effect on the luminol derivative and the quenching mechanism is discussed in detail. This luminol derivative can be applied as a fluorescent probe for ultra-trace analysis of Cu
2+
. The effects of pH, interferents and the stability have also been investigated. The fluorescent probe shows good reproducibility, and the relative standard deviation of response to Cu
2+
is 0.7% (
n
= 6). The lower linear range and the limit of detection are 0–500 and 0.27 nmol L
−1
, respectively.</description><subject>Analytical Chemistry</subject><subject>Characterization and Evaluation of Materials</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Exact sciences and technology</subject><subject>Microengineering</subject><subject>Nanochemistry</subject><subject>Nanotechnology</subject><subject>Original Paper</subject><subject>Spectrometric and optical methods</subject><issn>0026-3672</issn><issn>1436-5073</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2009</creationdate><recordtype>article</recordtype><recordid>eNp9kE1LAzEQhoMoWKs_wFsuih5WJ5vsbvZYih-Fgh70HNLsRLakmzXZrfTfm9Li0cMwMPPMy_AQcs3ggQFUjxGgBJEByFRVmYkTMmGCl1kBFT8lE4C8zHhZ5efkIsY1AKvKXEzI-4x2-EPduGk772iDod3qod0i1ZFqat3oA0aD3UD74FdIrQ90CNokoNNuF9tIvaXG9z2Gu8Xi_pKcWe0iXh37lHw-P33MX7Pl28tiPltmhot6yERhGiHrGk0hS2N0moLlrECJ0qBsgGurmxUgtyswFWNFY6wtTQMSrRWaT8ntITe99T1iHNSmTX86pzv0Y1SccwmyqBPIDqAJPsaAVvWh3eiwUwzU3p06uFPJndq7UyLd3BzDdTTa2aA708a_w5zxuk5GE5cfuJhW3RcGtfZjSF7iP-G_39R_cg</recordid><startdate>20090301</startdate><enddate>20090301</enddate><creator>Luo, Yun</creator><creator>Li, Yi</creator><creator>Lv, Baoqiang</creator><creator>Zhou, Zaide</creator><creator>Xiao, Dan</creator><creator>Choi, Martin M. F.</creator><general>Springer Vienna</general><general>Springer</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>H8G</scope><scope>JG9</scope><scope>L7M</scope></search><sort><creationdate>20090301</creationdate><title>A new luminol derivative as a fluorescent probe for trace analysis of copper(II)</title><author>Luo, Yun ; Li, Yi ; Lv, Baoqiang ; Zhou, Zaide ; Xiao, Dan ; Choi, Martin M. F.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c349t-45cd4899ec586ccac340f315e8e8ce8d03afadb0e3fb0c7115dcff6cd08eff4a3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2009</creationdate><topic>Analytical Chemistry</topic><topic>Characterization and Evaluation of Materials</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Exact sciences and technology</topic><topic>Microengineering</topic><topic>Nanochemistry</topic><topic>Nanotechnology</topic><topic>Original Paper</topic><topic>Spectrometric and optical methods</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Luo, Yun</creatorcontrib><creatorcontrib>Li, Yi</creatorcontrib><creatorcontrib>Lv, Baoqiang</creatorcontrib><creatorcontrib>Zhou, Zaide</creatorcontrib><creatorcontrib>Xiao, Dan</creatorcontrib><creatorcontrib>Choi, Martin M. F.</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Copper Technical Reference Library</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Mikrochimica acta (1966)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Luo, Yun</au><au>Li, Yi</au><au>Lv, Baoqiang</au><au>Zhou, Zaide</au><au>Xiao, Dan</au><au>Choi, Martin M. F.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>A new luminol derivative as a fluorescent probe for trace analysis of copper(II)</atitle><jtitle>Mikrochimica acta (1966)</jtitle><stitle>Microchim Acta</stitle><date>2009-03-01</date><risdate>2009</risdate><volume>164</volume><issue>3-4</issue><spage>411</spage><epage>417</epage><pages>411-417</pages><issn>0026-3672</issn><eissn>1436-5073</eissn><coden>MIACAQ</coden><abstract>A new luminol derivative has been synthesized and its fluorescence has been studied. The luminol derivative emits at 460 nm in pH 10.0 phosphate buffer which is different from the original luminol that emits at 425 nm under the same conditions. Cu
2+
exhibits strong fluorescence quenching effect on the luminol derivative and the quenching mechanism is discussed in detail. This luminol derivative can be applied as a fluorescent probe for ultra-trace analysis of Cu
2+
. The effects of pH, interferents and the stability have also been investigated. The fluorescent probe shows good reproducibility, and the relative standard deviation of response to Cu
2+
is 0.7% (
n
= 6). The lower linear range and the limit of detection are 0–500 and 0.27 nmol L
−1
, respectively.</abstract><cop>Vienna</cop><pub>Springer Vienna</pub><doi>10.1007/s00604-008-0076-4</doi><tpages>7</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0026-3672 |
| ispartof | Mikrochimica acta (1966), 2009-03, Vol.164 (3-4), p.411-417 |
| issn | 0026-3672 1436-5073 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_33380859 |
| source | SpringerLink Journals |
| subjects | Analytical Chemistry Characterization and Evaluation of Materials Chemistry Chemistry and Materials Science Exact sciences and technology Microengineering Nanochemistry Nanotechnology Original Paper Spectrometric and optical methods |
| title | A new luminol derivative as a fluorescent probe for trace analysis of copper(II) |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-16T20%3A31%3A54IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=A%20new%20luminol%20derivative%20as%20a%20fluorescent%20probe%20for%20trace%20analysis%20of%20copper(II)&rft.jtitle=Mikrochimica%20acta%20(1966)&rft.au=Luo,%20Yun&rft.date=2009-03-01&rft.volume=164&rft.issue=3-4&rft.spage=411&rft.epage=417&rft.pages=411-417&rft.issn=0026-3672&rft.eissn=1436-5073&rft.coden=MIACAQ&rft_id=info:doi/10.1007/s00604-008-0076-4&rft_dat=%3Cproquest_cross%3E33380859%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=33380859&rft_id=info:pmid/&rfr_iscdi=true |