Influence of ionic liquid content on properties of dense polymer membranes
Pervaporation was used for removal of butan-1-ol from its 5 wt.% of aqueous solution, at which the concentration of Clostridium acetobutylicum starts to decrease. The polydimethylsiloxane (PDMS) membrane containing 0, 10, 20 or 30 wt.% of benzyl-3-butylimidazolium tetrafluoroborate ([BBIM][BF 4]) io...
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| Veröffentlicht in: | European polymer journal 2009-03, Vol.45 (3), p.813-819 |
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| container_title | European polymer journal |
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| creator | Kohoutová, M. Sikora, A. Hovorka, Š. Randová, A. Schauer, J. Tišma, M. Setničková, K. Petričkovič, R. Guernik, S. Greenspoon, N. Izák, P. |
| description | Pervaporation was used for removal of butan-1-ol from its 5
wt.% of aqueous solution, at which the concentration of
Clostridium acetobutylicum starts to decrease. The polydimethylsiloxane (PDMS) membrane containing 0, 10, 20 or 30
wt.% of benzyl-3-butylimidazolium tetrafluoroborate ([BBIM][BF
4]) ionic liquid was used. Differential scanning calorimetry measurements showed that PDMS-[BBIM][BF
4] membranes (though optically homogeneous) contained PDMS and [BBIM][BF
4] phases. Pervaporation selectivity increased and total flux through membranes raised moderately with an increased content of [BBIM][BF
4] in PDMS-[BBIM][BF
4] membranes. Hence, immobilization of a proper ionic liquid in a membrane results in the creation of pervaporation membranes, effective in the removal of alcohol from fermentation broths. |
| doi_str_mv | 10.1016/j.eurpolymj.2008.11.043 |
| format | Article |
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wt.% of aqueous solution, at which the concentration of
Clostridium acetobutylicum starts to decrease. The polydimethylsiloxane (PDMS) membrane containing 0, 10, 20 or 30
wt.% of benzyl-3-butylimidazolium tetrafluoroborate ([BBIM][BF
4]) ionic liquid was used. Differential scanning calorimetry measurements showed that PDMS-[BBIM][BF
4] membranes (though optically homogeneous) contained PDMS and [BBIM][BF
4] phases. Pervaporation selectivity increased and total flux through membranes raised moderately with an increased content of [BBIM][BF
4] in PDMS-[BBIM][BF
4] membranes. Hence, immobilization of a proper ionic liquid in a membrane results in the creation of pervaporation membranes, effective in the removal of alcohol from fermentation broths.</description><identifier>ISSN: 0014-3057</identifier><identifier>EISSN: 1873-1945</identifier><identifier>DOI: 10.1016/j.eurpolymj.2008.11.043</identifier><identifier>CODEN: EUPJAG</identifier><language>eng</language><publisher>Kidlington: Elsevier Ltd</publisher><subject>Applied sciences ; Biofuel ; Clostridium acetobutylicum ; Dense polymer membranes ; Exact sciences and technology ; Exchange resins and membranes ; Fermentation ; Forms of application and semi-finished materials ; Ionic liquids ; Pervaporation ; Polymer industry, paints, wood ; Technology of polymers</subject><ispartof>European polymer journal, 2009-03, Vol.45 (3), p.813-819</ispartof><rights>2008 Elsevier Ltd</rights><rights>2009 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c448t-7963b08d64929d564802e5373ec44309ff1c34e85b06840b57eb4226504b1ecf3</citedby><cites>FETCH-LOGICAL-c448t-7963b08d64929d564802e5373ec44309ff1c34e85b06840b57eb4226504b1ecf3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.eurpolymj.2008.11.043$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,780,784,3541,27915,27916,45986</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=21285562$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Kohoutová, M.</creatorcontrib><creatorcontrib>Sikora, A.</creatorcontrib><creatorcontrib>Hovorka, Š.</creatorcontrib><creatorcontrib>Randová, A.</creatorcontrib><creatorcontrib>Schauer, J.</creatorcontrib><creatorcontrib>Tišma, M.</creatorcontrib><creatorcontrib>Setničková, K.</creatorcontrib><creatorcontrib>Petričkovič, R.</creatorcontrib><creatorcontrib>Guernik, S.</creatorcontrib><creatorcontrib>Greenspoon, N.</creatorcontrib><creatorcontrib>Izák, P.</creatorcontrib><title>Influence of ionic liquid content on properties of dense polymer membranes</title><title>European polymer journal</title><description>Pervaporation was used for removal of butan-1-ol from its 5
wt.% of aqueous solution, at which the concentration of
Clostridium acetobutylicum starts to decrease. The polydimethylsiloxane (PDMS) membrane containing 0, 10, 20 or 30
wt.% of benzyl-3-butylimidazolium tetrafluoroborate ([BBIM][BF
4]) ionic liquid was used. Differential scanning calorimetry measurements showed that PDMS-[BBIM][BF
4] membranes (though optically homogeneous) contained PDMS and [BBIM][BF
4] phases. Pervaporation selectivity increased and total flux through membranes raised moderately with an increased content of [BBIM][BF
4] in PDMS-[BBIM][BF
4] membranes. Hence, immobilization of a proper ionic liquid in a membrane results in the creation of pervaporation membranes, effective in the removal of alcohol from fermentation broths.</description><subject>Applied sciences</subject><subject>Biofuel</subject><subject>Clostridium acetobutylicum</subject><subject>Dense polymer membranes</subject><subject>Exact sciences and technology</subject><subject>Exchange resins and membranes</subject><subject>Fermentation</subject><subject>Forms of application and semi-finished materials</subject><subject>Ionic liquids</subject><subject>Pervaporation</subject><subject>Polymer industry, paints, wood</subject><subject>Technology of polymers</subject><issn>0014-3057</issn><issn>1873-1945</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2009</creationdate><recordtype>article</recordtype><recordid>eNqFkMtOwzAQRS0EEqXwDWQDu4TxM86yqniqEhtYW4kzkVwlcWsnSP17XIrYsprFnDt3dAi5pVBQoOphW-Acdr4_DNuCAeiC0gIEPyMLqkue00rIc7IAoCLnIMtLchXjFgBKrviCvL2OXT_jaDHzXeb86GzWu_3s2sz6ccJxyvyY7YLfYZgcxiPV4hgx-6nEkA04NKEeMV6Ti67uI978ziX5fHr8WL_km_fn1_Vqk1sh9JSXleIN6FaJilWtVEIDQ8lLjmnPoeo6arlALRtQWkAjS2wEY0qCaCjaji_J_elu-mo_Y5zM4KLFvk9P-DkazrmQVUX_BRlwKbhWCSxPoA0-xoCd2QU31OFgKJijZLM1f5LNUbKh1CTJKXn3W1FHW_ddEmFd_IszyrSUiiVudeIwiflyGEy07mi9dQHtZFrv_u36BqhXloY</recordid><startdate>20090301</startdate><enddate>20090301</enddate><creator>Kohoutová, M.</creator><creator>Sikora, A.</creator><creator>Hovorka, Š.</creator><creator>Randová, A.</creator><creator>Schauer, J.</creator><creator>Tišma, M.</creator><creator>Setničková, K.</creator><creator>Petričkovič, R.</creator><creator>Guernik, S.</creator><creator>Greenspoon, N.</creator><creator>Izák, P.</creator><general>Elsevier Ltd</general><general>Elsevier</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7QL</scope><scope>7QO</scope><scope>8FD</scope><scope>C1K</scope><scope>FR3</scope><scope>P64</scope><scope>7SR</scope><scope>JG9</scope></search><sort><creationdate>20090301</creationdate><title>Influence of ionic liquid content on properties of dense polymer membranes</title><author>Kohoutová, M. ; Sikora, A. ; Hovorka, Š. ; Randová, A. ; Schauer, J. ; Tišma, M. ; Setničková, K. ; Petričkovič, R. ; Guernik, S. ; Greenspoon, N. ; Izák, P.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c448t-7963b08d64929d564802e5373ec44309ff1c34e85b06840b57eb4226504b1ecf3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2009</creationdate><topic>Applied sciences</topic><topic>Biofuel</topic><topic>Clostridium acetobutylicum</topic><topic>Dense polymer membranes</topic><topic>Exact sciences and technology</topic><topic>Exchange resins and membranes</topic><topic>Fermentation</topic><topic>Forms of application and semi-finished materials</topic><topic>Ionic liquids</topic><topic>Pervaporation</topic><topic>Polymer industry, paints, wood</topic><topic>Technology of polymers</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Kohoutová, M.</creatorcontrib><creatorcontrib>Sikora, A.</creatorcontrib><creatorcontrib>Hovorka, Š.</creatorcontrib><creatorcontrib>Randová, A.</creatorcontrib><creatorcontrib>Schauer, J.</creatorcontrib><creatorcontrib>Tišma, M.</creatorcontrib><creatorcontrib>Setničková, K.</creatorcontrib><creatorcontrib>Petričkovič, R.</creatorcontrib><creatorcontrib>Guernik, S.</creatorcontrib><creatorcontrib>Greenspoon, N.</creatorcontrib><creatorcontrib>Izák, P.</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Bacteriology Abstracts (Microbiology B)</collection><collection>Biotechnology Research Abstracts</collection><collection>Technology Research Database</collection><collection>Environmental Sciences and Pollution Management</collection><collection>Engineering Research Database</collection><collection>Biotechnology and BioEngineering Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>Materials Research Database</collection><jtitle>European polymer journal</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Kohoutová, M.</au><au>Sikora, A.</au><au>Hovorka, Š.</au><au>Randová, A.</au><au>Schauer, J.</au><au>Tišma, M.</au><au>Setničková, K.</au><au>Petričkovič, R.</au><au>Guernik, S.</au><au>Greenspoon, N.</au><au>Izák, P.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Influence of ionic liquid content on properties of dense polymer membranes</atitle><jtitle>European polymer journal</jtitle><date>2009-03-01</date><risdate>2009</risdate><volume>45</volume><issue>3</issue><spage>813</spage><epage>819</epage><pages>813-819</pages><issn>0014-3057</issn><eissn>1873-1945</eissn><coden>EUPJAG</coden><abstract>Pervaporation was used for removal of butan-1-ol from its 5
wt.% of aqueous solution, at which the concentration of
Clostridium acetobutylicum starts to decrease. The polydimethylsiloxane (PDMS) membrane containing 0, 10, 20 or 30
wt.% of benzyl-3-butylimidazolium tetrafluoroborate ([BBIM][BF
4]) ionic liquid was used. Differential scanning calorimetry measurements showed that PDMS-[BBIM][BF
4] membranes (though optically homogeneous) contained PDMS and [BBIM][BF
4] phases. Pervaporation selectivity increased and total flux through membranes raised moderately with an increased content of [BBIM][BF
4] in PDMS-[BBIM][BF
4] membranes. Hence, immobilization of a proper ionic liquid in a membrane results in the creation of pervaporation membranes, effective in the removal of alcohol from fermentation broths.</abstract><cop>Kidlington</cop><pub>Elsevier Ltd</pub><doi>10.1016/j.eurpolymj.2008.11.043</doi><tpages>7</tpages></addata></record> |
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| ispartof | European polymer journal, 2009-03, Vol.45 (3), p.813-819 |
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| language | eng |
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| source | ScienceDirect Journals (5 years ago - present) |
| subjects | Applied sciences Biofuel Clostridium acetobutylicum Dense polymer membranes Exact sciences and technology Exchange resins and membranes Fermentation Forms of application and semi-finished materials Ionic liquids Pervaporation Polymer industry, paints, wood Technology of polymers |
| title | Influence of ionic liquid content on properties of dense polymer membranes |
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