Flash co-pyrolysis of biomass with polyhydroxybutyrate: Part 1. Influence on bio-oil yield, water content, heating value and the production of chemicals
Bio-oil obtained via flash pyrolysis shows potential to be applied as a renewable fuel. However, bio-oil often contains high amounts of water, which is a major drawback for its application. The influence of a biopolymer – polyhydroxybutyrate (PHB) on the pyrolysis of willow is investigated using a s...
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Veröffentlicht in: | Fuel (Guildford) 2008-09, Vol.87 (12), p.2523-2532 |
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creator | Cornelissen, T. Jans, M. Yperman, J. Reggers, G. Schreurs, S. Carleer, R. |
description | Bio-oil obtained via flash pyrolysis shows potential to be applied as a renewable fuel. However, bio-oil often contains high amounts of water, which is a major drawback for its application. The influence of a biopolymer – polyhydroxybutyrate (PHB) on the pyrolysis of willow is investigated using a semi-continuous home-built pyrolysis reactor. The flash co-pyrolysis of willow/PHB blends (w/w ratio 7:1, 3:1, 2:1 and 1:1) clearly shows particular merits: a synergetic increase in pyrolysis yield, a synergetic reduction of the water content in bio-oil, an increase in heating value, and a production of easily separable chemicals. The occurrence of synergetic interactions is observed based on a comparison between the actual pyrolysis results of the willow/PHB blends, the theoretical pyrolysis results calculated from the reference pyrolysis experiments (pure willow and pure PHB) and their respective w/w ratio. The co-pyrolysis of 1:1 willow/PHB shows the best overall results. |
doi_str_mv | 10.1016/j.fuel.2008.02.024 |
format | Article |
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The flash co-pyrolysis of willow/PHB blends (w/w ratio 7:1, 3:1, 2:1 and 1:1) clearly shows particular merits: a synergetic increase in pyrolysis yield, a synergetic reduction of the water content in bio-oil, an increase in heating value, and a production of easily separable chemicals. The occurrence of synergetic interactions is observed based on a comparison between the actual pyrolysis results of the willow/PHB blends, the theoretical pyrolysis results calculated from the reference pyrolysis experiments (pure willow and pure PHB) and their respective w/w ratio. 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The occurrence of synergetic interactions is observed based on a comparison between the actual pyrolysis results of the willow/PHB blends, the theoretical pyrolysis results calculated from the reference pyrolysis experiments (pure willow and pure PHB) and their respective w/w ratio. The co-pyrolysis of 1:1 willow/PHB shows the best overall results.</description><subject>Applied sciences</subject><subject>Bio-oil</subject><subject>Biomass</subject><subject>Energy</subject><subject>Exact sciences and technology</subject><subject>Flash co-pyrolysis</subject><subject>Natural energy</subject><subject>Polyhydroxybutyrate</subject><subject>Pyrolytic water</subject><subject>Willow</subject><issn>0016-2361</issn><issn>1873-7153</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2008</creationdate><recordtype>article</recordtype><recordid>eNp9kc1u1TAQhSNEJS6FF2DlDaya1H9JHMQGVfRHqkQXsLYcZ0x85WtfbKclb8Lj4uhWLCuNNJL1nTMzPlX1geCGYNJd7huzgGsoxqLBtBR_Ve2I6Fndk5a9rna4UDVlHXlTvU1pjzHuRct31d9rp9KMdKiPawxuTTahYNBow0GlhJ5sntGxvM_rFMOfdVzyGlWGz-hBxYxIg-68cQt4DSj4TVYH69BqwU0X6KmQsXj7DD5foBlUtv4XelRFgZSfUJ4BHWOYFp1tkZfBeoaD1cqld9WZKQ3eP_fz6uf1tx9Xt_X995u7q6_3teac5hpaGAfTj0IwhXVLyAScis6MvRooGYQgpnAtFYA1Y2LouOkxJZpS0U6jIuy8-nTyLXv8XiBlebBJg3PKQ1iSZIyKngtcQHoCdQwpRTDyGO1BxVUSLLcQ5F5uIcgtBIlpKV5EH5_dVSpXmai8tum_kmLe0m7oC_flxEE59dFClEnb7VcnG0FnOQX70ph_BIufVA</recordid><startdate>20080901</startdate><enddate>20080901</enddate><creator>Cornelissen, T.</creator><creator>Jans, M.</creator><creator>Yperman, J.</creator><creator>Reggers, G.</creator><creator>Schreurs, S.</creator><creator>Carleer, R.</creator><general>Elsevier Ltd</general><general>Elsevier</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7TB</scope><scope>8FD</scope><scope>F28</scope><scope>FR3</scope><scope>H8D</scope><scope>L7M</scope></search><sort><creationdate>20080901</creationdate><title>Flash co-pyrolysis of biomass with polyhydroxybutyrate: Part 1. 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subjects | Applied sciences Bio-oil Biomass Energy Exact sciences and technology Flash co-pyrolysis Natural energy Polyhydroxybutyrate Pyrolytic water Willow |
title | Flash co-pyrolysis of biomass with polyhydroxybutyrate: Part 1. Influence on bio-oil yield, water content, heating value and the production of chemicals |
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