Chiral 1,2,3,4-Tetrahydro-1-naphthylamine-Derived Phosphine-Phosphoramidite Ligand (THNAPhos): Application in Highly Enantioselective Hydrogenations of Functionalized CC Bonds

We have recently reported a new chiral 1,2,3,4‐tetrahydro‐1‐naphthylamine‐derived phosphine‐phosphoramidite ligand, (Rc,Ra)‐THNAPhos, that is highly efficient in the rhodium‐catalyzed asymmetric hydrogenation of a broad range of α‐enol ester phosphonates. To further demonstrate the utility of THNAPh...

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Veröffentlicht in:	Advanced synthesis & catalysis 2008-06, Vol.350 (9), p.1413-1418
Hauptverfasser:	Qiu, Min, Hu, Xiang-Ping, Wang, Dao-Yong, Deng, Jun, Huang, Jia-Di, Yu, Sai-Bo, Duan, Zheng-Chao, Zheng, Zhuo
Format:	Artikel
Sprache:	eng
Schlagworte:	asymmetric catalysis hydrogenation olefins phosphine-phosphoramidite ligand
Online-Zugang:	Volltext
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